Abstract: Disclosed is a heat transfer system with a module that includes a peripheral frame (10) and an electrocaloric element (46) disposed in an opening in the peripheral frame. The electrocaloric element includes an electrocaloric film (46), a first electrode (48) on a first side of the electrocaloric film, and a second electrode (50) on a second side of the electrocaloric film. First and second electrically conductive elements (24, 25) are disposed adjacent to first and second surfaces of the peripheral frame, and provide an electrical connection to the first and second electrodes.

Abstract: A method of making an electrocaloric is disclosed. The method includes: (a) providing a roll of a film comprising an electrocaloric material or a supply of multiple sheets of a film comprising an electrocaloric material; (b) delivering film from the roll or the supply of multiple sheets to a conductive material application station; (c) forming electrodes comprising a patterned disposition of conductive material on the film at the application station to form an electrocaloric article (d) delivering film from the application station to a take-up roll or an inventory of electrocaloric sheets; and (e) repeating (b), (c), and (d) to form multiple electrocaloric articles.

Abstract: A method of realizing a ferroic response is provided. The method includes applying a positive or negative conjugate field, which is of a first polarity, to a ferroic material to obtain a substantially minimized entropy of the ferroic material (301) and applying a slightly negative or a slightly positive conjugate field, which is of a second polarity opposite the first polarity, to the ferroic material to obtain a substantially maximized entropy of the ferroic material (302).

Abstract: A method of realizing a ferroic response is provided. The method includes applying a first conjugate field to a ferroic material in a non-singular-stepwise manner and applying a second conjugate field to the ferroic material in a non-singular-stepwise manner.

Abstract: An electrocaloric module includes an electrocaloric element that includes an electrocaloric film, a first electrode on a first surface of the electrocaloric film, and a second electrode on a second surface of the electrocaloric film. A support is attached along an edge portion of the electrocaloric film, leaving a central portion of the electrocaloric film unsupported film. At least one of the first and second electrodes includes a patterned disposition of conductive material on the film surface. The electrocaloric module also includes a first thermal connection configured to connect to a first thermal flow path between the electrocaloric element and a heat sink, a second thermal connection configured to connect to a second thermal flow path between the electrocaloric element and a heat source, and a power connection connected to the first and second electrodes and configured to connect to a power source.

Abstract: In one aspect, a heat exchanger layer for an adsorption bed heat exchanger assembly is provided. The heat exchanger layer includes at least one fluid tube configured to supply a heat transfer fluid, a sorbent containment structure having a plurality of compartments, and a sorbent disposed within the plurality of compartments.

Abstract: A heat transfer system cycles between a first mode where a heat transfer fluid is directed to a first electrocaloric module and from the first electrocaloric module to a heat exchanger to a second electrocaloric module while one of the first and second electrocaloric modules is energized, and a second mode where the heat transfer fluid is directed to the second electrocaloric module and from the second electrocaloric module to the heat exchanger to the first electrocaloric module, while the other of the first and second electrocaloric modules is energized. The modes are repeatedly cycled in alternating order directing the heat transfer fluid to cause a temperature gradient in each of the first and second electrocaloric modules, and heat is rejected to the fluid from the heat exchanger or is absorbed by the heat exchanger from the fluid.

Abstract: An electrocaloric element for a heat transfer system includes an electrocaloric material of a copolymer of (i) vinylidene fluoride, (ii) an addition polymerization monomer selected from tetrafluoroethylene, trifluoroethylene, vinyl fluoride, or combinations thereof, and (iii) a halogenated addition polymerization monomer larger than vinylidene fluoride. It is also provided that: (a) the monomer (ii) includes an addition polymerization monomer smaller than trifluoroethylene, (b) at least one of the addition polymerization monomers (ii) or (iii) is a chiral monomer, and the copolymer includes syndiotactic ordered segments of chiral monomer units, and/or (c) at least one of the addition polymerization monomers (ii) or (iii) comprises chlorine, and the copolymer includes an ordered distribution of monomer units comprising chlorine along the copolymer polymer backbone.

Abstract: A heat transfer system is disclosed in which, an electrocaloric material includes a copolymer of a monomer mixture including (i) vinylidene fluoride, (ii) an addition polymerization monomer selected from tetrafluoroethylene, trifluoroethylene, or a monomer smaller than trifluoroethylene, and (iii) a halogenated addition polymerization monomer different than (ii) that is larger than vinylidene fluoride. The electrocaloric material also includes an additive selected from a nucleating agent having a polar surface charge, electrocalorically active solid particles, or a combination thereof. Electrodes are disposed on opposite surfaces of the electrocaloric material, and an electric power source is configured to provide voltage to the electrodes. The system also includes a first thermal flow path between the electrocaloric material and a heat sink, and a second thermal flow path between the electrocaloric material and a heat source.

Abstract: A heat transfer system cycles between a first mode where a heat transfer fluid is directed to a first electrocaloric module and from the first electrocaloric module to a heat exchanger to a second electrocaloric module while one of the first and second electrocaloric modules is energized, and a second mode where the heat transfer fluid is directed to the second electrocaloric module and from the second electrocaloric module to the heat exchanger to the first electrocaloric module, while the other of the first and second electrocaloric modules is energized. The modes are repeatedly cycled in alternating order directing the heat transfer fluid to cause a temperature gradient in each of the first and second electrocaloric modules, and heat is rejected to the fluid from the heat exchanger or is absorbed by the heat exchanger from the fluid.

Abstract: A heat transfer system is disclosed that includes a plurality of electrocaloric elements (12) including an electrocaloric film (14), a first electrode (16) on a first side of the electrocaloric film, and a second electrode (18) on a second side of the electrocaloric film. A fluid flow path (20) is disposed along the plurality of electrocaloric elements, formed by corrugated fluid flow guide elements (19).

Abstract: A method of making an electrocaloric element includes dissolving or dispersing an electrocaloric polymer in an organic solvent having a boiling point of less than 100° C. at 1 atmosphere to form a liquid composition comprising the electrocaloric polymer. A film of the liquid composition is cast on a substrate, and the organic solvent is evaporated to form a film of the electrocaloric polymer. The film is removed from the substrate and disposed between electrical conductors to form an electrocaloric element.

Abstract: A heat transfer system is disclosed including a plurality of modules arranged in a stack. The stack modules include electrocaloric element and electrodes on each side of the film. A fluid flow path is disposed between two or more electrocaloric elements. A first electrical bus element (18) in electrical contact with the first electrode (14), and a second electrical bus element (20) in electrical contact with second electrode (16). The first electrical bus element is electrically connected to at least one other electrical bus of another electrocaloric element in the stack at the same polarity as said first electrical bus, or the second electrical bus element is electrically connected to at least one other electrical bus of another electrocaloric element in the stack at the same polarity as said second electrical bus.

Abstract: A method of making an electrocaloric element includes forming conductive layers on opposing surfaces of a film comprising an electrocaloric material to form an electrocaloric element, wherein the forming of the conductive layers includes one or more of: vapor deposition of the conductive layers under reduced pressure for a duration of time, wherein the duration of time under reduced pressure is less than 240 minutes; vapor deposition of the conductive layers under reduced pressure for a duration of time, wherein the duration of time of exposure to conductive material deposition is less than 240 minutes; vapor deposition of the conductive layers under reduced pressure, wherein the reduced pressure is 10 torr to 500 torr; or maintaining the film at a temperature of less than or equal to 200° C. during forming of the conductive layers.

Abstract: A heat transfer system includes an electrocaloric element comprising an electrocaloric film (12). A first electrical conductor is disposed on a first side of the electrocaloric film, and a second electrical conductor is disposed on a second side of the electrocaloric film. At least one of the first and second electrical conductors is an electrically conductive liquid. An electric power source (20) is in electrical contact with the first and second electrical conductors, and is configured to provide an electrical field across the electrocaloric film. A liquid flow path (28) is disposed along the plurality of electrocaloric elements for the electrically conductive liquid.

Abstract: Embodiments are directed to a heat pump element comprising: a thin-film polymer or ceramic material within a range of 0.1 microns-100 microns thickness, and electrodes coupled to both sides of the thin-film material to form an electroded active thin-film material, wherein the thin-film material is separated by, and in intimate contact with, a heat transfer fluid in channels within a range of 10 microns-10 millimeters thickness, in which the fluid is capable of being translated back and forth through the element by an imposed pressure field.

Abstract: A method and apparatus for cooling a heat source is disclosed. The apparatus includes a fin-diffuser including a blower integrated with fins of a diffuser. A heat spreader is coupled to the fin-diffuser. The heat spreader is configured to spread heat from a location proximate the blower to location of the fins. The apparatus spreads heat from a heat source proximate a blower of the fin-diffuser to a location away from the blower to cool the heat source.

Abstract: A cooling system for electrical and optical devices includes an electrocaloric cooler (EEC). A fluid circuit is in thermal communication with the EEC to dump heat from a working fluid of the fluid circuit into the EEC. The system can include a second EEC, a second fluid circuit in thermal communication with the second EEC to dump heat from a working fluid of the second fluid circuit into the EEC, and a second heat sink in thermal communication with the second fluid circuit to dump heat into the working fluid of the second fluid circuit. The second EEC, second fluid circuit, and second heat sink can be cascaded with the first EEC, first heat sink, and first fluid circuit wherein the second heat sink is in thermal communication with the first EEC to accept heat therefrom.

Abstract: A heat transfer system cycles between a first mode where a heat transfer fluid is directed to a first electrocaloric module and from the first electrocaloric module to a heat exchanger to a second electrocaloric module while one of the first and second electrocaloric modules is energized, and a second mode where the heat transfer fluid is directed to the second electrocaloric module and from the second electrocaloric module to the heat exchanger to the first electrocaloric module, while the other of the first and second electrocaloric modules is energized. The modes are repeatedly cycled in alternating order directing the heat transfer fluid to cause a temperature gradient in each of the first and second electrocaloric modules, and fluid from a flow path between the electrocaloric modules is mixed with circulating fluid from a conditioned space to cool or heat the conditioned space.

Abstract: A heat transfer system cycles between a first mode where a heat transfer fluid is directed to a first electrocaloric module and from the first electrocaloric module to a heat exchanger to a second electrocaloric module while one of the first and second electrocaloric modules is energized, and a second mode where the heat transfer fluid is directed to the second electrocaloric module and from the second electrocaloric module to the heat exchanger to the first electrocaloric module, while the other of the first and second electrocaloric modules is energized. The modes are repeatedly cycled in alternating order directing the heat transfer fluid to cause a temperature gradient in each of the first and second electrocaloric modules, and heat is rejected to the fluid from the heat exchanger or is absorbed by the heat exchanger from the fluid.