Abstract: Provided are reduced acylated graphene oxide as an electrode active material and a method for preparing the same. By the method for preparing reduced acylated graphene oxide according to the present invention, a negative electrode active material for a lithium secondary battery having stable activity and a high battery capacity may be prepared with a simple and low-cost process. In addition, the active material prepared by the preparation method has low resistance, a high battery capacity, and improved rate-limiting characteristics while having stable cycle characteristics.

Abstract: Disclosed is a flow-type energy storage device having an improved flow of fluid. The flow-type energy storage device stores electricity using a fluidic material, and includes a reaction region in which charge-discharge reaction of electricity is performed by the fluidic material, wherein the reaction region has an octagonal cross-section. The shape of the reaction region is controlled to thus improve the flowability of the fluidic material, thereby providing a flow-type energy storage device that has almost constant electrical properties even when a charging and discharging cycle is repeatedly performed. Further, the structures of an inlet and an outlet are not complicated and a separate part for controlling the flow of fluid is not used in the device, and accordingly, additional costs are not incurred during a process of manufacturing the flow-type energy storage device.

Abstract: This invention relates to an electrolyte solution for a redox flow battery containing an organic active material, in which an organic compound useful as a single active material for a cathode and an anode is dissolved in a water-soluble solvent, and to a redox flow battery using the same. The electrolyte solution of the invention is an aqueous electrolyte solution obtained by dissolving an active material in an aqueous solvent, and is thus very stable due to the low risk of fire or explosion. Furthermore, the organic compound is applied as a single active material to the cathode and the anode, and thus, when the capacity of the battery is decreased due to the permeation of the active material through the separator, the battery capacity can be restored through rebalancing.

Abstract: This invention relates to an electrode structure including a porous electrode that simultaneously performs the functions both of a bipolar plate and of a felt electrode and has a pattern layer or a mesh layer serving as a flow path on the surface thereof, a method of manufacturing the same, and a redox flow battery stack configuration for decreasing shunt current.

Abstract: A method of manufacturing a graphene composite including an ultrasonic-wave pulverization post-treatment process. The method includes radiating a microwave on a mixture of graphite oxide and a conducting agent, dispersing a resultant material, obtained during the radiating the microwave, in a liquid and performing ultrasonic-wave pulverization, and freeze-drying particles subjected to the ultrasonic-wave pulverization. The post-treatment process is added to the method of manufacturing the graphene composite including the reduced graphene oxide using the graphite oxide, thereby manufacturing a graphene composite having improved bindability with spherical activated carbon used to manufacture an active material. Further, the post-treated graphene composite is used to manufacture the active material and the supercapacitor, and accordingly, the active material can be thinly and densely applied to provide a supercapacitor having improved performance.

Abstract: The present invention relates to a cathode for a metal-air battery, a method for manufacturing the same, and a metal-air battery including the same. The cathode comprises a needle-shaped core including two or more species of metals selected from the group consisting of nickel, cobalt, manganese, zinc, iron, copper, and chrome, or a cobalt oxide; and a flake-shaped shell including an oxide containing two or more species of metals selected from the group consisting of nickel, cobalt, manganese, zinc, iron, copper, and chrome or a cobalt oxide. As such, the core-shell structure may lead to a reduction in the charge voltage of the metal-air battery as well as the taking of the good capacity characteristics of the transition metal oxide. Further, according to the present invention, the cathode for a metal-air battery may be produced without adding carbon or binder.

Abstract: This invention relates to an electrolyte solution for a redox flow battery containing an organic active material, in which an organic compound useful as a single active material for a cathode and an anode is dissolved in a water-soluble solvent, and to a redox flow battery using the same. The electrolyte solution of the invention is an aqueous electrolyte solution obtained by dissolving an active material in an aqueous solvent, and is thus very stable due to the low risk of fire or explosion. Furthermore, the organic compound is applied as a single active material to the cathode and the anode, and thus, when the capacity of the battery is decreased due to the permeation of the active material through the separator, the battery capacity can be restored through rebalancing.

Abstract: This invention relates to an electrode structure including a porous electrode that simultaneously performs the functions both of a bipolar plate and of a felt electrode and has a pattern layer or a mesh layer serving as a flow path on the surface thereof, a method of manufacturing the same, and a redox flow battery stack configuration for decreasing shunt current.

Abstract: The present invention relates to a cathode for a metal-air battery, a method for manufacturing the same, and a metal-air battery including the same. The cathode comprises a needle-shaped core including two or more species of metals selected from the group consisting of nickel, cobalt, manganese, zinc, iron, copper, and chrome, or a cobalt oxide; and a flake-shaped shell including an oxide containing two or more species of metals selected from the group consisting of nickel, cobalt, manganese, zinc, iron, copper, and chrome or a cobalt oxide. As such, the core-shell structure may lead to a reduction in the charge voltage of the metal-air battery as well as the taking of the good capacity characteristics of the transition metal oxide. Further, according to the present invention, the cathode for a metal-air battery may be produced without adding carbon or binder.

Abstract: Disclosed herein is stack-type flow energy storage system. More particularly, the system includes a stack-type electrode cell composed of fluidic electrode material mixed with an electrolyte and storage tank for the electrode material, thereby remarkably improving stability, output and energy density. The stack-type flow energy storage system is advantageous in that unit cells, each consisting of a cathode, a separation membrane and an anode, are connected in parallel or in series to each other to make a stack cell, thus remarkably increasing output power. Further, the stack-type flow energy storage system is advantageous in that the sizes of slurry storage tanks connected to an electrode cell are adjusted, thus determining the required specification of energy density.

Abstract: Disclosed is a method of preparing a carbide-derived carbon having high ion mobility for use in a lithium battery anode material, a lithium air battery electrode, a supercapacitor electrode, and a flow capacitor electrode, including thermally treating a carbide compound in a vacuum, thus obtaining a vacuum-treated carbide compound; and thermochemically reacting the vacuum-treated carbide compound with a halogen element-containing gas, thus extracting the element other than carbon from the vacuum-treated carbide compound, wherein annealing can be further performed after thermochemical reaction. This carbide-derived carbon has a small pore distribution, dense graphite fringe, and a large lattice spacing and thus high ion mobility, compared to conventional carbide-derived carbon obtained only by thermochemical reaction with a halogen element-containing gas.

Abstract: A manifold for a redox flow battery capable of effectively suppressing a shunt current has a supply flow pathway and an exhaust flow pathway respectively formed at a left side and a right side of an anode or cathode electrode electrolyte reaction unit so as to include a U-shaped curved portion, and the U-shaped curved portion is formed to be positioned on the upper part of the top or the lower part of the bottom of the first electrode electrolyte reaction unit. When the manifold is applied to a redox flow battery, the supply flow pathway and the exhaust flow pathway having the U-shaped curved portion are formed on the upper part of the top or the lower part of the bottom of the electrode electrolyte reaction unit to prevent an electrolyte existing in the inside of a stack and a pipe from passing through the U-shaped curved portion.

Abstract: Disclosed herein is a method of preparing porous graphene from porous graphite, including 1) thermochemically reacting a highly crystalline carbide compound with a halogen element-containing gas to give a porous carbide-derived carbon; 2) treating the carbide-derived carbon with an acid, thus preparing a carbide-derived carbon oxide; and 3) reducing the carbide-derived carbon oxide. An anode mixture for a secondary battery including the graphene and an anode for a secondary battery including the anode mixture are also provided.

Abstract: Disclosed is a method for preparing a metal catalyst having improved yield of alcohols. The method for preparing a metal catalyst for the production of alcohol from synthesis gas includes forming a metal catalyst; and irradiating the metal catalyst with gamma rays. The metal catalyst has improved yield of alcohols by stabilizing the metal catalyst through gamma ray irradiation to inhibit generation of hydrocarbons in catalytic reaction with synthesis gas.

Abstract: Disclosed is a method of manufacturing a graphene composite including an ultrasonic-wave pulverization post-treatment process. The method includes radiating a microwave on a mixture of graphite oxide and a conducting agent, dispersing a resultant material, obtained during the radiating the microwave, in a liquid and performing ultrasonic-wave pulverization, and freeze-drying particles subjected to the ultrasonic-wave pulverization. In the present invention, the post-treatment process is added to the method of manufacturing the graphene composite including the reduced graphene oxide using the graphite oxide, thereby manufacturing a graphene composite having improved bindability with spherical activated carbon used to manufacture an active material. Further, the post-treated graphene composite is used to manufacture the active material and the supercapacitor, and accordingly, the active material can be thinly and densely applied to provide a supercapacitor having improved performance.

Abstract: Disclosed are a method of preparing active carbon and active carbon prepared thereby, in which carbonization and activation can be carried out through a single process, thus simplifying the preparation process and increasing energy savings and preparation efficiency.

Abstract: Disclosed is a flow-type energy storage device having an improved flow of fluid. The flow-type energy storage device stores electricity using a fluidic material, and includes a reaction region in which charge-discharge reaction of electricity is performed by the fluidic material, wherein the reaction region has an octagonal cross-section. The shape of the reaction region is controlled to thus improve the flowability of the fluidic material, thereby providing a flow-type energy storage device that has almost constant electrical properties even when a charging and discharging cycle is repeatedly performed. Further, the structures of an inlet and an outlet are not complicated and a separate part for controlling the flow of fluid is not used in the device, and accordingly, additional costs are not incurred during a process of manufacturing the flow-type energy storage device.

Abstract: The present invention relates to a cathode catalyst for a metal-air battery, a method for manufacturing the same, and a metal-air battery comprising the same. More specifically, the present invention relates to a cathode catalyst for a metal-air battery, a method for manufacturing the same, and a metal-air battery comprising the same having an improved storage capacity for charging/discharging and an increased charge-discharge cycle lifetime. The cathode catalyst is characterized by having a layered perovskite structure, and including lanthanum and nickel oxides. The cathode catalyst including the layered perovskite is used for manufacturing a cathode for a metal-air battery, and a metal-air battery is provided using the same. As a result, the charge-discharge polarisation of the metal-air battery is decreased, the storage capacity is increased, and the charge-discharge cycle lifetime can be improved.

Abstract: Disclosed is a method of preparing a carbide-derived carbon having high ion mobility for use in a lithium battery anode material, a lithium air battery electrode, a supercapacitor electrode, and a flow capacitor electrode, including thermally treating a carbide compound in a vacuum, thus obtaining a vacuum-treated carbide compound; and thermochemically reacting the vacuum-treated carbide compound with a halogen element-containing gas, thus extracting the element other than carbon from the vacuum-treated carbide compound, wherein annealing can be further performed after thermochemical reaction. This carbide-derived carbon has a small pore distribution, dense graphite fringe, and a large lattice spacing and thus high ion mobility, compared to conventional carbide-derived carbon obtained only by thermochemical reaction with a halogen element-containing gas.

Abstract: Disclosed is a method for preparing a carbide-derived carbon-based anode active material. The method includes preparing carbide-derived carbon, and expanding pores of the carbide-derived carbon. Here, expanding of pores is performed as an activation process of heating the prepared carbide-derived carbon in the air. The pores formed inside the carbide-derived carbon can be expanded during the activation process in the preparation of the carbide-derived carbon-based anode active material. In addition, by applying the carbide-derived carbon to an anode active material, lithium secondary battery having improved charge-discharge efficiency can be prepared.