Abstract: A thermoelectric generator of a vehicle converts thermal energy of exhaust gas of an engine into electric energy by using a thermoelectric phenomenon, and may include: a high-temperature part heated by exchange heat and a plurality of pairs of heat transfer plates mounted on an outer peripheral surface of an exhaust pipe at a predetermined interval; pairs of thermoelectric modules acquired by bonding a P-type semiconductor and an N-type semiconductor, interposed between the pairs of heat transfer plates to generate electricity, and electrically connected to each other; and a low-temperature part interposed between the pairs of thermoelectric modules and cooling inner surfaces of the pairs of thermoelectric modules. The plurality of thermoelectric modules generates electricity by a difference in temperature between heated outer surfaces and cooled inner surfaces. Thermoelectric efficiency is improved and a small-sized thermoelectric generator of a vehicle may be implemented.