Patent number: 10388954
Abstract: An olivine-type positive active material for a lithium battery, a lithium battery having the olivine-type positive active material, and a method of manufacturing the olivine-type positive active material are provided. The olivine-type positive active material includes a plurality of particles represented by LixMyM?zXO4-wBw. M and M? are independently an element selected from the group consisting of Fe, Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Mo, Ti, Zn, Al, Ga, Mg, B, and the combination thereof, X is one element selected from the group consisting of P, As, Bi, Sb, and the combination thereof, B is one element selected from the group consisting of F, S, and the combination thereof, 0<x?1, 0<y?1, 0<z?1, 0<x+y+z?2, and 0?w?0.5. The particle is a secondary particle having a plurality of primary particles, a first carbon coating layer is on the surface of the primary particle and a second carbon coating layer is on the surface of the secondary particle, and carbon is dispersed inside the primary particle.
Type:
Grant
Filed:
December 27, 2016
Date of Patent:
August 20, 2019
Assignee:
IUCF-HYU (INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNVERSITY)
Inventors:
Yang-Kook Sun, Sung-Woo Oh, Hyun-Joo Bang, Seung Min Oh
Publication number: 20170110731
Abstract: The present invention provides an olivine-type positive active material precursor for a lithium battery that includes MXO4-zBz (wherein M is one element selected from the group consisting of Fe, Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Ti, Zn, Al, Ga, Mg, B, and a combination thereof, X is one element selected from the group consisting of P, As, Bi, Sb, and a combination thereof, B is one element selected from the group consisting of F, S, and a combination thereof, and 0?z?0.5) particles, and the precursor has a particle diameter of 1 to 20 ?m, a tap density of 0.8 to 2.1 g/cm3, and a specific surface area of 1 to 10 m2/g. The olivine-type positive active material prepared using the olivine-type positive active material precursor has excellent crystallinity of particles, a large particle diameter, and a high tap density, and therefore shows excellent electrochemical characteristics and capacity per unit volume.
Type:
Application
Filed:
December 27, 2016
Publication date:
April 20, 2017
Inventors:
Yang-Kook SUN, Sung-Woo OH, Hyun-Joo BANG, Seung Min OH
Patent number: 9570746
Abstract: The present invention provides an olivine-type positive active material precursor for a lithium battery that includes MXO4-zBz (wherein M is one element selected from the group consisting of Fe, Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Ti, Zn, Al, Ga, Mg, B, and a combination thereof, X is one element selected from the group consisting of P, As, Bi, Sb, and a combination thereof, B is one element selected from the group consisting of F, S, and a combination thereof, and 0?z?0.5) particles, and the precursor has a particle diameter of 1 to 20 ?m, a tap density of 0.8 to 2.1 g/cm3, and a specific surface area of 1 to 10 m2/g. The olivine-type positive active material prepared using the olivine-type positive active material precursor has excellent crystallinity of particles, a large particle diameter, and a high tap density, and therefore shows excellent electrochemical characteristics and capacity per unit volume.
Type:
Grant
Filed:
March 25, 2009
Date of Patent:
February 14, 2017
Assignee:
IUCF-HYU (INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY)
Inventors:
Yang-Kook Sun, Sung-Woo Oh, Hyun-Joo Bang, Seung Min Oh