Patents by Inventor Suojiang Zhang
Suojiang Zhang has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20220274944Abstract: Disclosed are a composite absorbent and a method for using same in the absorption and conversion of ethylene oxide for the coupling co-production of ethylene carbonate. The composite absorbent comprises an ionic liquid and ethylene carbonate, wherein the ionic liquid is an imidazole ionic liquid, a quaternary ammonium ionic liquid and a quaternary phosphonium ionic liquid. The composite absorbent is used for absorbing ethylene oxide and carbon dioxide, and is also used in the absorption and conversion of ethylene oxide for the coupling co-production of ethylene carbonate.Type: ApplicationFiled: March 23, 2020Publication date: September 1, 2022Applicant: Institute of Process Engineering, Chinese Academy of SciencesInventors: Weiguo Cheng, Li Dong, Junjie Chu, Zengliang Zhang, Qian Su, Songsong Chen, Yifan Liu, Xiangping Zhang, Suojiang ZHANG
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Patent number: 11299450Abstract: A system and a process for co-producing dimethyl carbonate and ethylene glycol. The system comprises an interconnected ethylene carbonate preparation unit and an ethylene carbonate alcoholysis unit. The ethylene carbonate preparation unit comprises a fixed bed reactor and a light-component stripping column connected to each other. The fixed bed reactor is filled with a supported ionic liquid catalyst. The process comprises the steps of: reacting carbon dioxide and ethylene oxide as raw materials in the fixed bed reactor to produce ethylene carbonate, purifying the ethylene carbonate and then mixing it with an alcoholysis reaction catalyst, and reacting the mixture with methanol in a reactive distillation tower, producing dimethyl carbonate and ethylene glycol. The process increases the conversion rate of ethylene oxide and avoids the need for a process of separating conventional homogeneous catalysts from ethylene carbonate, thereby reducing process energy consumption and simplifying process procedures.Type: GrantFiled: September 14, 2017Date of Patent: April 12, 2022Assignee: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCESInventors: Weiguo Cheng, Li Dong, Qian Su, Songsong Chen, Junping Zhang, Suojiang Zhang
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Publication number: 20210331999Abstract: A system and a process for co-producing dimethyl carbonate and ethylene glycol. The system comprises an interconnected ethylene carbonate preparation unit and an ethylene carbonate alcoholysis unit. The ethylene carbonate preparation unit comprises a fixed bed reactor and a light-component stripping column connected to each other. The fixed bed reactor is filled with a supported ionic liquid catalyst. The process comprises the steps of: reacting carbon dioxide and ethylene oxide as raw materials in the fixed bed reactor to produce ethylene carbonate, purifying the ethylene carbonate and then mixing it with an alcoholysis reaction catalyst, and reacting the mixture with methanol in a reactive distillation tower, producing dimethyl carbonate and ethylene glycol. The process increases the conversion rate of ethylene oxide and avoids the need for a process of separating conventional homogeneous catalysts from ethylene carbonate, thereby reducing process energy consumption and simplifying process procedures.Type: ApplicationFiled: September 14, 2017Publication date: October 28, 2021Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCESInventors: Weiguo Cheng, Li Dong, Qian Su, Songsong Chen, Junping Zhang, Suojiang Zhang
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Patent number: 11123718Abstract: Provided are an oxovanadium phosphate catalyst, and a preparation method and an application therefor. The method includes: 1) mixing and reacting a vanadium source, a choline chloride-organic carboxylic acid eutectic solvent, and alcohol; 2) mixing the obtained reaction product with a phosphorus source, raising the temperature to a temperature higher than the melting point of the eutectic solvent, and continuing the reaction to obtain an oxovanadium phosphate precursor; and 3) calcining to obtain the oxovanadium phosphate catalyst. The alcohol is: benzyl alcohol or a mixture of C3-C8 monohydric alcohol and benzyl alcohol. The present method uses a green and inexpensive eutectic solvent to strengthen the preparation of oxovanadium phosphate catalyst, avoids the disadvantages of the prior art, and overcoming the problems of low yield and poor selectivity when used in a reaction to prepare maleic anhydride by catalytic n-butane selective oxidisation.Type: GrantFiled: March 1, 2018Date of Patent: September 21, 2021Assignee: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCESInventors: Ruixia Liu, Bin He, Ruirui Zhang, Hongguo Tang, Suojiang Zhang
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Publication number: 20200368730Abstract: Provided are an oxovanadium phosphate catalyst, and a preparation method and an application therefor. The method includes: 1) mixing and reacting a vanadium source, a choline chloride-organic carboxylic acid eutectic solvent, and alcohol; 2) mixing the obtained reaction product with a phosphorus source, raising the temperature to a temperature higher than the melting point of the eutectic solvent, and continuing the reaction to obtain an oxovanadium phosphate precursor; and 3) calcining to obtain the oxovanadium phosphate catalyst. The alcohol is: benzyl alcohol or a mixture of C3-C8 monohydric alcohol and benzyl alcohol. The present method uses a green and inexpensive eutectic solvent to strengthen the preparation of oxovanadium phosphate catalyst, avoids the disadvantages of the prior art, and overcoming the problems of low yield and poor selectivity when used in a reaction to prepare maleic anhydride by catalytic n-butane selective oxidisation.Type: ApplicationFiled: March 1, 2018Publication date: November 26, 2020Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCESInventors: Ruixia Liu, Bin He, Ruirui Zhang, Hongguo Tang, Suojiang Zhang
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Patent number: 10604468Abstract: The present invention relates to the technical field of chemical engineering and catalysis. Provided are an application of an ionic liquid in propylene glycol ether synthesis and a method for synthesizing a propylene glycol ether. The ionic liquid is a methyl carbonate ionic liquid, and is used as a catalyst for catalyzing propylene glycol ether synthesis. The method for synthesizing the propylene glycol ether comprises the following steps: placing propylene oxide and an alcohol within a reactor to contact a catalyst, and heating the mixture in an enclosed environment to 50-200° C. to obtain the propylene glycol ether, wherein the catalyst is a methyl carbonate ionic liquid. The method for synthesizing propylene glycol ether provided in the present invention is a green synthesis technique, and does not require special production equipment. The method has simple and easily controllable processes, and can be used in industrial production and applications.Type: GrantFiled: November 14, 2016Date of Patent: March 31, 2020Assignee: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCESInventors: Ruixia Liu, Suojiang Zhang, Ruirui Zhang, Junping Zhang, Shengxin Chen, Fei Dai
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Publication number: 20180222833Abstract: The present invention relates to the technical field of chemical engineering and catalysis. Provided are an application of an ionic liquid in propylene glycol ether synthesis and a method for synthesizing a propylene glycol ether. The ionic liquid is a methyl carbonate ionic liquid, and is used as a catalyst for catalyzing propylene glycol ether synthesis. The method for synthesizing the propylene glycol ether comprises the following steps: placing propylene oxide and an alcohol within a reactor to contact a catalyst, and heating the mixture in an enclosed environment to 50-200° C. to obtain the propylene glycol ether, wherein the catalyst is a methyl carbonate ionic liquid. The method for synthesizing propylene glycol ether provided in the present invention is a green synthesis technique, and does not require special production equipment. The method has simple and easily controllable processes, and can be used in industrial production and applications.Type: ApplicationFiled: November 14, 2016Publication date: August 9, 2018Inventors: Ruixia LIU, Suojiang ZHANG, Ruirui ZHANG, Junping ZHANG, Shengxin CHEN, Fei (6) DAI
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Patent number: 9663589Abstract: Disclosed herein are processes for providing a biopolymer from a biomass or source of chitin using ionic liquids. The processes involve contacting a biomass or source of chitin with an ionic liquid to produce a biopolymer comprising solution and precipitating the biopolymer from the solution with supercritical CO2, gaseous CO2, or combinations thereof.Type: GrantFiled: February 13, 2014Date of Patent: May 30, 2017Assignees: The Board of Trustees of The University of Alabama, The Intellectual Property Office of Institute of Process Engineering, Chinese Academy of SciencesInventors: Robin D. Rogers, Patrick S. Barber, Chris S. Griggs, Gabriela Gurau, Xingmei Lu, Suojiang Zhang
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Patent number: 9358497Abstract: An ionic liquid solvent and gas purification method using the same are provided. The ionic liquid solvent consists of a main absorbent, a regulator for the main absorbent, an auxiliary absorbent, an activator, an antioxidant and water. The ionic liquid involves a low synthetic cost, low viscosity and high absorption capacity, and can be easily regenerated and recycled. The method, compared with traditional processes, has advantages such as a greater absorption capability and lower operation cost.Type: GrantFiled: September 26, 2010Date of Patent: June 7, 2016Assignee: Institute of Process Engineering, Chinese Academy of SciencesInventors: Xiangping Zhang, Yansong Zhao, Shaojuan Zeng, Suojiang Zhang, Haifeng Dong, Yingpeng Zhen, Lei Huang
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Publication number: 20150368371Abstract: Disclosed herein are processes for providing a biopolymer from a biomass or source of chitin using ionic liquids. The processes involve contacting a biomass or source of chitin with an ionic liquid to produce a biopolymer comprising solution and precipitating the biopolymer from the solution with supercritical CO2, gaseous CO2, or combinations thereof.Type: ApplicationFiled: February 13, 2014Publication date: December 24, 2015Applicant: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ALABAMAInventors: Robin D. Rogers, Patrick S. Barber, Chris S. Griggs, Gabriela Gurau, Xingmei Lu, Suojiang Zhang
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Patent number: 8658842Abstract: Disclosed is a process for producing ethylene glycol catalyzed by an ionic liquid, characterized in that the process includes the following three steps: (a) a carbonylation step of ethylene oxide and CO2 catalyzed by an ionic liquid composite catalyst comprising a hydroxyl functionalized ionic liquid and an alkali metal salt under an aqueous condition to produce ethylene carbonate and ethylene glycol; (b) a hydrolysis step of reacting the reaction solution containing ethylene carbonate and the ionic liquid composite catalyst obtained in step (a) with water to produce ethylene glycol; (c) a purification step of dehydrating and refining ethylene glycol from the aqueous solution containing ethylene glycol and the catalyst produced in step (b). The present process has the following advantages: the catalyst has high activity, high suitability, and good stability, the reaction condition is wild, the conversion of ethylene oxide is high, the selectivity of ethylene glycol is high, and the process is simple.Type: GrantFiled: June 7, 2010Date of Patent: February 25, 2014Assignee: Institute of Process Engineering, Chinese Academy of SciencesInventors: Suojiang Zhang, Jian Sun, Weiguo Cheng, Jinquan Wang, Jianxin Zhang, Zengzeng Fu, Xiangping Zhang
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Publication number: 20130255496Abstract: An ionic liquid solvent and gas purification method using the same are provided. The ionic liquid solvent consists of a main absorbent, a regulator for the main absorbent, an auxiliary absorbent, an activator, an antioxidant and water. The ionic liquid involves a low synthetic cost, low viscosity and high absorption capacity, and can be easily regenerated and recycled. The method, compared with traditional processes, has advantages such as a greater absorption capability and lower operation cost.Type: ApplicationFiled: September 26, 2010Publication date: October 3, 2013Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMYInventors: Xiangping Zhang, Yansong Zhao, Shaojuan Zeng, Suojiang Zhang, Haifeng Dong, Yingpeng Zhen, Lei Huang
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Publication number: 20130072727Abstract: Disclosed is a process for producing ethylene glycol catalyzed by an ionic liquid, characterized in that the process includes the following three steps: (a) a carbonylation step of ethylene oxide and CO2 catalyzed by an ionic liquid composite catalyst comprising a hydroxyl functionalized ionic liquid and an alkali metal salt under an aqueous condition to produce ethylene carbonate and ethylene glycol; (b) a hydrolysis step of reacting the reaction solution containing ethylene carbonate and the ionic liquid composite catalyst obtained in step (a) with water to produce ethylene glycol; (c) a purification step of dehydrating and refining ethylene glycol from the aqueous solution containing ethylene glycol and the catalyst produced in step (b). The present process has the following advantages: the catalyst has high activity, high suitability, and good stability, the reaction condition is wild, the conversion of ethylene oxide is high, the selectivity of ethylene glycol is high, and the process is simple.Type: ApplicationFiled: June 7, 2010Publication date: March 21, 2013Applicant: Institute of Process Engineering, Chinese Academy of SciencesInventors: Suojiang Zhang, Jian Sun, Weiguo Cheng, Jinquan Wang, Jianxin Zhang, Zengzeng Fu, Ziangping Zhang
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Patent number: 7964756Abstract: Disclosed is a process for absorbing methylacrolein, characterized in that it absorbs methylacrolein by an absorbent comprising an ionic liquid. The absorbent can absorb methylacrolein effectively, and it is easy to be separated from methylacrolein, regenerated and recycled. It is a green absorbent. The technique is a green methylacrolein absorbing and separating technique.Type: GrantFiled: March 10, 2008Date of Patent: June 21, 2011Assignee: Institute of Process Engineering, Chinese Academy of SciencesInventors: Suojiang Zhang, Qiong Chen, Ruiyi Yan, Lei Wang, Yuhuan Chen, Xiaoliang Yuan
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Publication number: 20110021846Abstract: Disclosed is a process for absorbing methylacrolein, characterized in that it absorbs methylacrolein by an absorbent comprising an ionic liquid. The absorbent can absorb methylacrolein effectively, and it is easy to be separated from methylacrolein, regenerated and recycled. It is a green absorbent. The technique is a green methylacrolein absorbing and separating technique.Type: ApplicationFiled: March 10, 2008Publication date: January 27, 2011Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCESInventors: Suojiang ZHANG, Qiong CHEN, Ruiyi YAN, Lei WANG, Yuhuan CHEN, Xiaoliang YUAN
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Publication number: 20090005392Abstract: The present invention provides crystals of 6-[4-(4-pyridylamino)phenyl]-4,5-dihydro-3(2H)-pyridazinone hydrochloride trihydrate useful as a medicament for therapeutic treatment of cardiac failure, and the like; and a pharmaceutical composition comprising said crystals as an active ingredient. The crystal of the present invention has characteristic absorption peaks (2? degrees) at 12.9 (±0.2°) and 19.0 (±0.2°), for example, in powder X-ray diffractometry.Type: ApplicationFiled: February 11, 2008Publication date: January 1, 2009Applicant: MITSUBISHI PHARMA CORPORATIONInventors: Haruki Asatani, Akio Tsuboi, Suojiang Zhang, Shinji Ohura
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Publication number: 20040224956Abstract: The present invention provides crystals of 6-[4-(4-pyridylamino)phenyl]-4,5-dihydro-3(2H)-pyridazinone hydrochloride trihydrate useful as a medicament for therapeutic treatment of cardiac failure, and the like; and a pharmaceutical composition comprising said crystals as an active ingredient.Type: ApplicationFiled: June 22, 2004Publication date: November 11, 2004Inventors: Haruki Asatani, Akio Tsuboi, Suojiang Zhang, Shinji Ohura