Abstract: A reaction product (A) which can be prepared by reaction, under free radical conditions, of at least one monomer (a) capable of free radical reaction, in the presence of at least one free radical initiator and of a radical of the formula (III) where R1 to R3, in each case independently of one another, are hydrogen, methyl or a radical-stabilizing and/or bulky group selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, cycloalkyl, alcohol, ether, polyether, amine, aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R5, —C(O)OR5, —CR5R6—O—R7, —O—C(O)R5, —CN, —O—CN, —S—CN, —O—C?NR5, —S—C?NR5, —O—CR5R6—CR7R8NR9R10, —N?C?O, —C?NR5, —CR5R6-Hal, —C(S)R5, —CR5R6—P(O)R7R8, —CR5R6—PR7R8, —CR5R6—NR7R8, —CR5R6(OR7)(OR8), —CR5R6(OR7)(NR8), —CR5R6(NR7)(NR8), an anhydride, acetal or ketal group, —SO2R5, an amidine group, —NR5C(S)NR6,

Abstract: A process for the preparation of a reaction product (A), which comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction in the presence of at least one free radical initiator and a compound of the formula (I)  where R1 to R4, independently of one another, are each hydrogen, an alkyl radical, cycloalkyl radical or aralkyl radical, each of which is unsubstituted or substituted, an unsubstituted or substituted aromatic hydrocarbon radical, with the proviso that at least two of the radicals R1 to R4 are an unsubstituted or substituted aromatic hydrocarbon radical, or R1 and R2 or R3 and R4, in each case in pairs, are a substituted or unsubstituted aromatic hydrocarbon having 6 to 18 carbon atoms and a functional group which, in conjugation with the C—C double bond in the formula I, has a multiple bond between a carbon atom and a heteroatom, 10% by weight or less of wate

Abstract: A process for the preparation of polymers is described, wherein at least one first ethylenically unsaturated monomer is subjected to a free radical polymerization in the presence of stable free radicals or sources of stable free radicals and of a compound having at least one free thiol group to give a polymer, and wherein the molar ratio of compound having a free thiol group to stable free radicals is from 0.05 to 1.1. The polymerization rate is substantially increased by the compound having a free thiol group.

Abstract: Disclosed are a detersive composition comprising a water-soluble or water-dispersible block copolymer preparable by controlled free-radical polymerization, a process for preparing such a detersive composition and the use of water-soluble or water-dispersible block copolymers preparable by controlled free-radical polymerization for preparing detersive compositions.

Abstract: A process for the preparation of a reaction product (A) comprises the following stage (i):

Abstract: The present invention provides a process for the free radical polymerization of one or more ethylenically unsaturated monomers, said process comprising polymerizing one or more ethylenically unsaturated monomers in the presence of one or more N-oxyl radicals of formula II, wherein X is S, NR5, O, SO or SO2, R5 is C1-C20-alkyl or C5-C8-cycloalkyl and R3 and R4 independently of one another, are C1-C4-alkyl, phenyl, naphthyl or an aromatic five-membered ring, or R3 and R4 together are —(CH2)o— and p and o, independently of one another, are an integer from 2 to 7.

Abstract: A reaction product (A) which can be prepared by reaction, under free radical conditions, of at least one monomer (a) capable of free radical reaction, in the presence of at least one free radical initiator and of a radical of the formula (III) 1

Abstract: A process for the preparation of a reaction product (A), which comprises the following stage (i):

Abstract: Polymers obtainable by a process for the living free radical polymerization of one or more ethylenically unsaturated monomers with the use of at least one free radical polymerization initiator and in the presence of one or more stable N-oxyl radicals, at least one stable N-oxyl radical having polymerizable double bonds, are used for processing to give moldings, films, fibers and foams.