Abstract: Disclosed herein is an apparatus comprising an active layer substantially free of binding agents, the active layer comprising a network of carbon nanotubes defining void spaces, the network of carbon nanotubes making up less than 10% by weight of the active layer; and a carbonaceous material located in the void spaces and bound by the network of carbon nanotubes; wherein the active layer is configured to provide energy storage.

Abstract: Disclosed herein is an anode, comprising an active layer comprising a network of high aspect ratio carbon elements defining void spaces within the network; a plurality of electrode active material particles disposed in the void spaces within the network, wherein the active material particles comprise silicon; and a polymeric additive, the polymeric additive being at least one of (i) selected from a family of polyamides, or (ii) a modified polyamide or derivative of a polyamide. Disclosed herein too is a cathode, comprising an active layer comprising a network of high aspect ratio carbon elements defining void spaces within the network; a plurality of electrode active material particles disposed in the void spaces within the network; and a polymeric additive, the polymeric additive being at least one of (i) selected from a family of polyamides, or (ii) a modified polyamide or derivative of a polyamide.