Patents by Inventor Suzhen Qiao

Suzhen Qiao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10239969
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Grant
    Filed: October 13, 2016
    Date of Patent: March 26, 2019
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Xinsheng Wang, Ping Gao, Suzhen Qiao, Maoping Yin, Weili Li, Tianyi Zhang, Renqi Peng, Ying Chen, Zhihui Zhang
  • Publication number: 20170101486
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Application
    Filed: October 13, 2016
    Publication date: April 13, 2017
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi XIA, Yuexiang LIU, Jigui ZHANG, Xinsheng WANG, Ping GAO, Suzhen QIAO, Maoping YIN, Weili LI, Tianyi ZHANG, Renqi PENG, Ying CHEN, Zhihui ZHANG
  • Patent number: 9499569
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: November 22, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Xinsheng Wang, Ping Gao, Suzhen Qiao, Maoping Yin, Weili Li, Tianyi Zhang, Renqi Peng, Ying Chen, Zhihui Zhang
  • Patent number: 9353197
    Abstract: A catalyst component for olefin polymerization is disclosed, which comprises at least one diol ester type electron donor compound (a) and at least one diether type electron donor compound (b) among others, wherein the molar ratio of a to b is 0.55-50. A preparation method of the catalyst component, a catalyst comprising the catalyst component, and an olefin polymerization method using the catalyst which can especially be used for preparation of polypropylenes of low ash contents are also disclosed.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: May 31, 2016
    Assignees: China Petroleum and Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum and Chemical Corporation
    Inventors: Xianzhi Xia, Jin Zhao, Yuexiang Liu, Jigui Zhang, Weili Li, Yang Tan, Suzhen Qiao, Renqi Peng, Ping Gao, Maoping Yin, Tianyi Zhang
  • Patent number: 9321857
    Abstract: A spheric magnesium compound comprises a reaction product of at least the following components: (a) a magnesium halide having a formula of MgX2-nRn, wherein X is independently chloride or bromide, R is a C1-C14 alkyl, a C6-C14 aryl, a C1-C14 alkoxy, or a C6-C14 aryloxy, and n is 0 or 1; (b) an alcohol compound; and (c) an epoxy compound having a general formula (I), wherein R2 and R3 are independently hydrogen, a C1-C5 linear or branched alkyl, or a C1-C5 linear or branched haloalkyl. The magnesium compound has characteristic DSC curve and X-ray diffraction pattern, and can be used as a carrier for olefin polymerization catalyst. stereoregularity of polymer having high melt index, and low content of polymer fines.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: April 26, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Weili Li, Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Suzhen Qiao, Jin Zhao, Ping Gao, Xinsheng Wang, Yang Tan, Zhihui Zhang, Linna Yang, Ruilin Duan, Renqi Peng
  • Patent number: 9243086
    Abstract: A catalyst component for olefin polymerization is disclosed, which comprises a reaction product of the following components: (1) a spheric carrier; (2) a titanium compound; and optionally, (3) an electron donor, wherein the spheric carrier comprises a reaction product of at least the following components: (a) a magnesium halide represented by a general formula of MgX2-nRn, wherein X is independently chloride or bromide, R is a C1-C14 alkyl, a C6-C14 aryl, a C1-C14 alkoxy, or a C6-C14 aryloxy, and n is 0 or 1; (b) an alcohol compound; and (c) an epoxy compound represented by a general formula (I), wherein R2 and R3 are independently hydrogen, a C1-C5 linear or branched alkyl, or a C1-C5 linear or branched haloalkyl.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: January 26, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Inst. of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Weili Li, Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Suzhen Qiao, Jin Zhao, Ping Gao, Xinsheng Wang, Yang Tan, Zhihui Zhang, Linna Yang, Ruilin Duan, Renqi Peng
  • Patent number: 9068026
    Abstract: A magnesium halide adduct is provided, comprising at least one compound of the formula MgXY, at least one compound of the formula ROH, methanol, at least one modifying agent chosen from DOE and o-hydroxy benzoates, and optionally water. Also provided herein are a catalyst component comprising the magnesium halide adduct, a catalyst for olefin polymerization comprising the catalyst component; the respective processes for preparing the magnesium halide adduct and the catalyst component; use of the magnesium halide adduct for preparing the catalyst component, use of the catalyst component in a catalyst for olefin polymerization and use of the catalyst in olefin polymerization; and a process of olefin polymerization.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: June 30, 2015
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Xianzhi Xia, Yuexiang Liu, Jin Zhao, Jigui Zhang, Yongtai Ling, Weili Li, Suzhen Qiao, Yang Tan, Renqi Peng, Ping Gao, Futang Gao, Zhihui Zhang
  • Publication number: 20120302708
    Abstract: A magnesium halide adduct is provided, comprising at least one compound of the formula MgXY, at least one compound of the formula ROH, methanol, at least one modifying agent chosen from DOE and o-hydroxy benzoates, and optionally water. Also provided herein are a catalyst component comprising the magnesium halide adduct, a catalyst for olefin polymerization comprising the catalyst component; the respective processes for preparing the magnesium halide adduct and the catalyst component; use of the magnesium halide adduct for preparing the catalyst component, use of the catalyst component in a catalyst for olefin polymerization and use of the catalyst in olefin polymerization; and a process of olefin polymerization.
    Type: Application
    Filed: May 25, 2012
    Publication date: November 29, 2012
    Inventors: Xianzhi XIA, Yuexiang LIU, Jin ZHAO, Jigui ZHANG, Yongtai LING, Weili LI, Suzhen QIAO, Yang TAN, Renqi PENG, Ping GAO, Futang GAO, Zhihui ZHANG
  • Publication number: 20120264590
    Abstract: A spheric magnesium compound comprises a reaction product of at least the following components: (a) a magnesium halide having a formula of MgX2-nRn, wherein X is independently chloride or bromide, R is a C1-C14 alkyl, a C6-C14 aryl, a C1-C14 alkoxy, or a C6-C14 aryloxy, and n is 0 or 1; (b) an alcohol compound; and (c) an epoxy compound having a general formula (1), wherein R2 and R3 are independently hydrogen, a C1-C5 linear or branched alkyl, or a C1-C5 linear or branched haloalkyl. The magnesium compound has characteristic DSC curve and X-ray diffraction pattern, and can be used as a carrier for olefin polymerization catalyst. stereoregularity of polymer having high melt index, and low content of polymer fines.
    Type: Application
    Filed: October 18, 2010
    Publication date: October 18, 2012
    Inventors: Weili Li, Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Suzhen Qiao, Jin Zhao, Ping Gao, Xinsheng Wang, Yang Tan, Zhihui Zhang, Linna Yang, Ruilin Duan, Renqi Peng
  • Publication number: 20120252992
    Abstract: A catalyst component for olefin polymerization is disclosed, which comprises a reaction product of the following components: (1) a spheric carrier; (2) a titanium compound; and optionally, (3) an electron donor, wherein the spheric carrier comprises a reaction product of at least the following components: (a) a magnesium halide represented by a general formula of MgX2-nRn, wherein X is independently chloride or bromide, R is a C1-C14 alkyl, a C6-C14 aryl, a C1-C14 alkoxy, or a C6-C14 aryloxy, and n is 0 or 1; (b) an alcohol compound; and (c) an epoxy compound represented by a general formula (I), wherein R2 and R3 are independently hydrogen, a C1-C5 linear or branched alkyl, or a C1-C5 linear or branched haloalkyl.
    Type: Application
    Filed: October 18, 2010
    Publication date: October 4, 2012
    Inventors: Weili Li, Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Suzhen Qiao, Jin Zhao, Ping Gao, Xinsheng Wang, Yang Tan, Zhihui Zhang, Linna Yang, Ruilin Duan, Renqi Peng
  • Publication number: 20120226004
    Abstract: A catalyst component for olefin polymerization is disclosed, which comprises at least one diol ester type electron donor compound (a) and at least one diether type electron donor compound (b) among others, wherein the molar ratio of a to b is 0.55-50. A preparation method of the catalyst component, a catalyst comprising the catalyst component, and an olefin polymerization method using the catalyst which can especially be used for preparation of polypropylenes of low ash contents are also disclosed.
    Type: Application
    Filed: April 19, 2010
    Publication date: September 6, 2012
    Inventors: Xianzhi Xia, Jin Zhao, Yuexiang Liu, Jigui Zhang, Weili Li, Yang Tan, Suzhen Qiao, Renqi Peng, Ping Gao, Maoping Yin, Tianyi Zhang
  • Publication number: 20120184694
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Application
    Filed: July 15, 2009
    Publication date: July 19, 2012
    Inventors: Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Xinsheng Wang, Ping Gao, Suzhen Qiao, Maoping Yin, Weili Li, Tianyi Zhang, Renqi Peng, Ying Chen, Zhihui Zhang
  • Publication number: 20100099833
    Abstract: The component of magnesium halide adduct is represented by MgX2 mROH nE pH2O, in which X is chlorine, bromine, C1-C14alkoxy or aryloxy; R is C1-C12 alkyl, C3-C10 cycloalkyl or C6-C10 aryl; E is represented by the general formula (II), wherein R1 and R2 which can be the same or different to each other, are hydrogen or linear or branched C1-C10 hydrocarbon groups, C3-C10 cycloalkyl, C6-C10 aryl, C7-C10 alkaryl or aralkyl, optionally, the said aryl or alkylaryl or arylalkyl is substituted by one or more halogen in the aromatic ring, R1 and R2 can form ring or fused ring. R3 and R4 have the same meaning of R1 and R2 except that they can't be hydrogen, m is 1-5, n is 0.005-1.0, and p is 0-0.8. Spherical catalyst component and catalyst made from the above spherical magnesium halide adduct and their use in polymerising the alpha-olefins CH2=CHR and their mixture are provided, in which R is hydrogen or C1-C12 alkyl or aryl.
    Type: Application
    Filed: April 6, 2007
    Publication date: April 22, 2010
    Inventors: Xianzhi Xia, Yuexiang Liu, Xinsheng Wang, Tianyi Zhang, Mingzhi Gao, Ping Gao, Suzhen Qiao, Maoping Yin, Ying Chen, Renqi Peng, Jing Ma