Abstract: A system for repositioning teeth a patient from an initial tooth arrangement to a final tooth arrangement includes a plurality of incremental position adjustment appliances, each having an arrangement of cavities shaped to receive and reposition teeth of the patient. The cavities in at least one appliance in the system have a different geometry than that of at least one other appliance in the system. At least some of the appliances in the system are successively worn by the patient to exert force on at least one tooth and move the teeth of the patient from a first arrangement to a successive arrangement different from the first arrangement. The system includes a first multilayer shell with a bending stiffness factor less than about 0.1 GPa*mm3 and an elastic modulus no greater than about 1.5 GPa; and a second shell with a bending stiffness factor greater than 0.1 GPa*mm3.

Abstract: The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article.

Abstract: A method for making a dental appliance configured to position at least one tooth of a patient includes printing a hard-enable liquid resin composition on a major surface of a polymeric material to form a pattern of discrete unhardened liquid regions thereon; at least partially hardening the unhardened liquid regions to form a corresponding array of structures on the major surface of the polymeric material, wherein the structures have a characteristic cross-sectional dimension of about 25 microns to about 1 mm, and a feature spacing of about 100 microns to about 2000 microns; forming an exterior layer comprising a ion-permeable polymeric material on the base polymeric material and the array of structures; and forming a plurality of cavities in the polymeric material to form the dental appliance including an arrangement of cavities configured to receive one or more teeth.

Abstract: An aqueous oral care one-part composition (e.g., solution), a kit that includes such composition (e.g., solution), and methods (e.g., a method of providing fluoride to a patient's tooth surface), wherein the oral care composition (e.g., solution) includes: silver cations; iodide anions; fluoride anions; and water.

Abstract: Presently described are methods of making an article comprising providing a structured film (1100) comprising a thermoformable planar base (212) layer and a structured surface (116, 216) layer disposed on a major surface (1200) of the planar base (212) layer wherein the structured surface (116, 216) layer comprises a different organic polymeric material than the thermoformable planar base (212) layer, and thermoforming the structured film (1100) into a thermoformed article (1000). Also described are thermoformed and thermoformable articles.

Abstract: A method of thermoforming is described. The method comprises providing a multilayer polymer film comprising at least one first thermoplastic polymer layer having a glass transition temperature (Tg) greater than 60° C. and at least one second polymer layer; and thermoforming the multilayer polymer film into a three-dimensional shape. The second polymer layer can be characterized by one or more properties selected from i) a Tg ranging from 20 to 70° C.; ii) a molecular weight between crosslinks of no greater than 20,000 g/mole; and iii) sufficient crosslinking such that the second polymer layer lacks a thermal melt or softening transition at a temperature up to the decomposition temperature of the second polymer layer. Also described are multilayer films and articles, such as orthodontic aligner and retainer trays.

Abstract: A dental appliance includes a polymeric shell with a plurality of cavities for receiving one or more teeth, including an interior region with a core layer of a first thermoplastic polymer A with a thermal transition temperature of about 70° C. to about 140° C. and a flexural modulus greater than about 1.3 GPa, and first and second interior layers of a second thermoplastic polymer B with a glass transition temperature of less than about 0° C., a flexural modulus less than about 1 GPa, and an elongation a break of greater than 150%; and first and second exterior layers of a third thermoplastic polymer C with a thermal transition temperature of about 70° C. to about 140° C. and a flexural modulus greater than about 1.3 GPa. The dental appliance demonstrates enhanced optical properties, with enhanced light transmission and low haze.

Abstract: An aqueous oral care one-part composition (e.g., solution), a kit that includes such composition (e.g., solution), and methods (e.g., a method of providing fluoride to a patient's tooth surface), wherein the oral care composition (e.g., solution) includes: silver cations; iodide anions; fluoride anions; and water.

Abstract: A multilayer film comprises first, second, and third layers. The first layer comprises at least one aromatic polyester, and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals. The second layer is thermoplastic and has a loss modulus at 1 hertz and 25° C. of less than or equal to 60 megapascals and comprises a thermoplastic elastomer and a polyamide. The third layer contacts the second layer opposite the first layer and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals. The second layer is sandwiched between the first and third layers. A method of making the multilayer film by coextrusion is also disclosed.

Abstract: A system for repositioning teeth a patient from an initial tooth arrangement to a final tooth arrangement includes a plurality of incremental position adjustment appliances, each having an arrangement of cavities shaped to receive and reposition teeth of the patient. The cavities in at least one appliance in the system have a different geometry than that of at least one other appliance in the system. At least some of the appliances in the system are successively worn by the patient to exert force on at least one tooth and move the teeth of the patient from a first arrangement to a successive arrangement different from the first arrangement. The system includes a first multilayer shell with a bending stiffness factor less than about 0.1 GPa*mm3 and an elastic modulus no greater than about 1.5 GPa; and a second shell with a bending stiffness factor greater than 0.1 GPa*mm3.

Abstract: An aqueous oral care one-part composition (e.g., solution), a kit that includes such composition (e.g., solution), and methods (e.g., a method of providing fluoride to a patients tooth surface), wherein the oral care composition (e.g., solution) includes: silver cations; thiocyanate anions; fluoride anions; and water.

Abstract: An article. The article includes a substrate, wherein the substrate having two opposing major surfaces; and particles coated with a metal oxide on the substrate: particles coated with a metal on the substrate; wherein the coated particles are randomly distributed on or in the substrate; and wherein at least some of coated particles are discrete particles.

Abstract: An article having anti-microbial effect is provided. The article includes an occlusive layer and a substrate having a nanostructured surface. The nanostructured surface is coated with a metal oxide layer and the metal oxide layer includes a metal oxide.

Abstract: A method for making a dental appliance configured to position at least one tooth of a patient includes printing a hardenable liquid resin composition on a major surface of a polymeric material to form a pattern of discrete unhardened liquid regions thereon; at least partially hardening the unhardened liquid regions to form a corresponding array of structures on the major surface of the polymeric material, wherein the structures have a characteristic cross-sectional dimension of about 25 microns to about 1 mm, and a feature spacing of about 100 microns to about 2000 microns; and forming a plurality of cavities in the polymeric material to form the dental appliance including an arrangement of cavities configured to receive one or more teeth.

Abstract: A multilayer film comprises first, second, and third layers. The first layer comprises at least one aromatic polyester, and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals. The second layer is thermoplastic and has a loss modulus at 1 hertz and 25° C. of less than or equal to 60 megapascals and comprises a thermoplastic elastomer and a polyamide. The third layer contacts the second layer opposite the first layer and has a loss modulus at 1 hertz and 25° C. of at least 70 megapascals. The second layer is sandwiched between the first and third layers. A method of making the multilayer film by coextrusion is also disclosed.

Abstract: A dental appliance includes a polymeric shell with a plurality of cavities for receiving one or more teeth, including an interior region with a core layer of a first thermoplastic polymer A with a thermal transition temperature of about 70° C. to about 140° C. in and a flexural modulus greater than about 1.3 GPa, and first and second interior layers of a second thermoplastic polymer B with a glass transition temperature of less than about 0° C. and a flexural modulus less than about 1 GPa; and first and second exterior layers of a third thermoplastic polymer C with a thermal transition temperature of about 70° C. to about 140° C. and a flexural modulus greater than about 1.3 GPa. Interfacial adhesion between any of the adjacent layers in the polymeric shell is greater than about 150 grams per inch.

Abstract: A method includes reactively extruding a polymeric composition to form a film. The polymeric composition includes a polyisocyanate and at least one dimer fatty diol.

Abstract: A dental appliance includes a polymeric shell with an arrangement of one or more cavities configured to receive one or more teeth, and the polymeric shell includes an antimicrobial lipid, such as monolaurin, and optionally an enhancer.

Abstract: A dental article includes at least one segment defining a complex three-dimensional shape configured to follow contours of an oral anatomy, in which the at least one segment includes a core component including a majority of parylene.

Abstract: A film including a resin layer comprising a structured major surface opposite a second major surface, the structured major surface including a plurality of features; a barrier layer on the structured major surface; and a first adhesive layer on the barrier layer.