Abstract: A fluorocarboxylic acid preparation process which includes hydrolyzing fluorocarboxylic acid fluoride in the presence of an aqueous sulfuric acid solution to form a reaction product containing a fluorocarboxylic acid and hydrogen fluoride (present as hydrofluoric acid); and removing at least some of the hydrogen fluoride from the reaction product by washing the reaction production with aqueous sulfuric acid solution. The hydrolyzing and washing are carried out at a temperature at which the fluorocarboxylic acid is a liquid.

Abstract: A fluorocarboxylic acid preparation process continuously carries out acidification reaction treatment and washing treatment, and includes subjecting a fluorocarboxylate-containing aqueous solution to acidification reaction treatment in the presence of sulfuric acid so as to form a sulfate-containing fluorocarboxylic acid phase; and subjecting the fluorocarboxylic acid phase to washing treatment using an aqueous sulfuric acid solution.

Abstract: A fluorocarboxylic acid preparation process continuously carries out acidification reaction treatment and washing treatment, and includes subjecting a fluorocarboxylate-containing aqueous solution to acidification reaction treatment in the presence of sulfuric acid so as to form a sulfate-containing fluorocarboxylic acid phase; and subjecting the fluorocarboxylic acid phase to washing treatment using an aqueous sulfuric acid solution.

Abstract: A fluorocarboxylic acid preparation process which includes hydrolyzing fluorocarboxylic acid fluoride in the presence of an aqueous sulfuric acid solution to form a reaction product containing a fluorocarboxylic acid and hydrogen fluoride (present as hydrofluoric acid); and removing at least some of the hydrogen fluoride from the reaction product by washing the reaction production with aqueous sulfuric acid solution. The hydrolyzing and washing are carried out at a temperature at which the fluorocarboxylic acid is a liquid.

Abstract: Fluorinated carboxylic acid, used as a surfactant in fluoropolymerization in aqueous media, can be recovered by scrubbing from the exhaust gas of the dryer during polymer drying and, after concentration and treatment with alumina, directly reused in fluoropolymerization in aqueous media.

Abstract: Fluorinated carboxylic acid, used as a surfactant in fluoropolymerization in aqueous media, can be recovered by scrubbing from the exhaust gas of the dryer during polymer drying and, after concentration and treatment with alumina, directly reused in fluoropolymerization in aqueous media.

Abstract: A process for preparing a hydrochlorofluorocarbon essentially free of olefinic impurities by selectively hydrogenating the olefinic impurities. The process may be controlled such that at least a portion of the hydrochlorofluorocarbon is converted into a fluorohydrocarbon.

Abstract: An improved process for producing an anisotropic pitch product suitable for carbon fiber manufacture. A carbonaceous feedstock is heated at elevated temperature while passing a reactive sparging gas through the feedstock. The sparging gas is an oxidative gas such as a gaseous mixture containing a major proportion of inert gas and from about 0.1 to 2% by volume of oxygen. The process produces an anisotropic pitch having from 50 to 100% by volume mesophase which is suitable for producing good quality carbon fibers.

Abstract: The present invention resides in improved graphite nipples which are suitable for connecting graphite electrodes. The graphite nipples are prepared by adding mesophase pitch-based carbon fibers into a typical nipple extrusion blend.

Abstract: Binder pitch is prepared by combining a petroleum aromatic mineral oil thermal tar and super finely subdivided calcined premium coke particles. The petroleum aromatic mineral oil thermal tar is obtained by hydrotreating, thermally cracking and vacuum distilling an aromatic mineral oil. Additionally, the aromatic mineral oil thermal tar may be subjected to heat soaking.

Abstract: An improved process for producing an anisotropic pitch product suitable for carbon fiber manufacture. A carbonaceous feedstock substantially free of mesophase pitch is heated at elevated temperature while passing an oxidatively reactive sparging gas such as air through the feedstock. The oxidatively treated feedstock, which remains substantially free of mesophase pitch, is then heated at a higher temperature in the presence of a non-oxidative sparging gas to produce an anisotropic pitch having from 50 to 100% by volume mesophase which is suitable for producing good quality carbon fibers.

Abstract: An improved process for producing an anisotropic pitch product suitable for carbon fiber manufacture. A carbonaceous feedstock substantially free of mesophase pitch is heated at elevated temperature while passing an oxidatively reactive sparging gas such as air through the feedstock. The oxidatively treated feedstock, which contains isotropic pitch, is solvent fractionated to recover a solid pitch which on fusion becomes an anisotropic pitch product having from 50 to 100 percent by volume mesophase. In one aspect of the invention the carbonaceous feedstock is oxidatively treated in a melt phase at a lower temperature and the resulting isotropic pitch is then heated at a higher temperature in a melt phase in the presence or absence of a non-oxidative sparging gas prior to solvent fractionation.

Abstract: Properties of premium coke are improved by coking the feed at a temperature lower than the normal coking temperature and thereafter subjecting the coke to a heat soak at substantially the same temperature as the temperature at which the coke was formed.

Abstract: In a delayed premium coking process utilizing as feedstock an aromatic mineral oil having a high aromatic content and a low molecular weight, coke CTE is reduced and coke particle size is increased by sparging with a gas during the coking cycle.

Abstract: A process for providing more uniform premium coke in a delayed coking operation by adding an aliphatic petroleum fraction to the premium coking feed during the latter part of the coking cycle. Preferably the aliphatic petroleum fraction is added gradually and is increased in quantity over the period of addition.