Abstract: The present application relates reinforced poly(arylene sulfide) compositions and processes of producing the reinforced poly(arylene sulfide) compositions. The reinforced poly(arylene sulfide compositions can be prepared by blending the reinforcing agent with the poly(arylene sulfide) or by including the reinforcing agent in the process to produce the poly(arylene sulfide). Reinforcing agents which can be utilized are graphenes (e.g., single-walled carbon nanotubes). The inclusion of the graphene reinforcing agent in the poly(arylene sulfide) composition affects the crystallization properties and/or the conductivity of the melt processed poly(arylene sulfide) compositions.

Abstract: A process for selectively making 2-alkenes from a NAO using a mesoporous catalyst that has been surface modified with a Brönsted acid compound. The Brönsted acid compound has a reactive silane connector, an organic linking group, and a Brönsted acid group. The mesoporous catalyst has an average pore diameter in a range of about 12 to about 100 Angstroms and a surface area of between about 400 to about 1400 m2/gram.

Abstract: Oxygen scavenging materials incorporated into or attached to a package such as a gable-top or rectangular carton, used to package foods, beverages or other oxygen sensitive materials, and thereby increase shelf-life by decreasing oxygen in the headspace of the package, and decreasing oxidation of the packaged product.

Abstract: A process for selectively making 2-alkenes from a NAO using a mesoporous catalyst that has been surface modified with a Brönsted acid compound. The Brönsted acid compound has a reactive silane connector, an organic linking group, and a Brönsted acid group. The mesoporous catalyst has an average pore diameter in a range of about 12 to about 100 Angstroms and a surface area of between about 400 to about 1400 m2/gram.

Abstract: A process for selectively making 2-alkenes from a NAO using a mesoporous catalyst that has been surface modified with a Brönsted acid compound. The Brönsted acid compound has a reactive silane connector, an organic linking group, and a Brönsted acid group. The mesoporous catalyst has an average pore diameter in a range of about 12 to about 100 Angstroms and a surface area of between about 400 to about 1400 m2/gram.

Abstract: A process for selectively making 2-alkenes from a NAO using a mesoporous catalyst that has been surface modified with a Brönsted acid compound. The Brönsted acid compound has a reactive silane connector, an organic linking group, and a Brönsted acid group. The mesoporous catalyst has an average pore diameter in a range of about 12 to about 100 Angstroms and a surface area of between about 400 to about 1400 m2/gram.

Abstract: Herein is disclosed a modified ethylene vinyl alcohol polymer (EVOH) comprising an oxygen scavenging functional group. Preferably, the modified EVOH comprises structures IV, V, and VI: wherein x is an integer greater than or equal to 1, y is an integer greater than or equal to 1, z is an integer greater than or equal to 1, and R comprises a cycloalkenyl group. The modified EVOH is useful in oxygen barrier applications, such as a forming an oxygen barrier layer of a packaging article. Also disclosed are methods of modifying ethylene vinyl alcohol polymers, and using the modified EVOH to make packaging articles with a superior barrier to entry by atmospheric oxygen.

Abstract: Herein is disclosed an oxygen barrier composition comprising an oxygen barrier polymer and an oxygen scavenging polymer. Preferably, the oxygen barrier polymer is selected from polymers or copolymers of vinyl alcohol, polyesters, polymers or copolymers of vinylidene dichloride, polymers or copolymers of epoxies, polysulfones, polymers or copolymers of acrylonitrile, polymers or copolymers of isocyanates, or polyamides other than MXD6; and the oxygen scavenging polymer either comprises an ethylenic backbone and a cyclic olefinic pendant group of structure I, or a polyester group of structure II or structure III: wherein q1, q2, q3, q4, and r are independently selected from hydrogen, methyl, or ethyl; m is —(CH2)n—, wherein n is an integer from 0 to 4, inclusive; X is null or a linking group; and, when r is hydrogen, at least one of q1, q2, q3, and q4 is also hydrogen. The oxygen barrier composition can be formed into an oxygen barrier layer of a packaging article.

Abstract: Herein is disclosed an oxygen barrier composition comprising an oxygen barrier polymer and an oxygen scavenging polymer. The composition can be in the form of a physical blend or a cross-linked blend, and can further comprise a compatibilizer, a transesterification catalyst, or both. Preferably, the oxygen barrier polymer is poly(ethylene/vinyl alcohol) (EVOH), polyethylene terephthalate (PET), or polyamide other than MXD6. Preferably, the oxygen scavenging polymer comprises an ethylenic backbone and a pendant cyclic olefinic group, or the oxygen scavenging polymer is a polyamide derived at least in part from a xylene diamine-based monomer. The oxygen barrier composition can be formed into an oxygen barrier layer of a packaging article. Such layers and articles, and methods for making same, are also disclosed.

Abstract: A family of polymers containing selected cyclic allylic pendent groups for oxygen scavenging packaging which has minimal organoleptic by-products after oxidation.

Abstract: Herein is disclosed a modified ethylene vinyl alcohol polymer (EVOH) comprising an oxygen scavenging functional group. Preferably, the modified EVOH comprises structures IV, V, and VI: wherein x is an integer greater than or equal to 1, y is an integer greater than or equal to 1, z is an integer greater than or equal to 1, and R comprises a cycloalkenyl group. The modified EVOH is useful in oxygen barrier applications, such as a forming an oxygen barrier layer of a packaging article. Also disclosed are methods of modifying ethylene vinyl alcohol polymers, and using the modified EVOH to make packaging articles with a superior barrier to entry by atmospheric oxygen.

Abstract: Rigid containers are provided comprising oxygen scavenger compositions that produce only low levels of volatiles or by-products as a consequence of oxygen scavenging. In particular, a family of polymers containing selected cyclic olefinic pendent groups are used in the rigid containers to achieve oxygen scavenging that is associated with minimal or no organoleptic by-products after oxidation.

Abstract: Disclosed herein are oxygen scavenging compositions and packaging articles that comprise (a) a metal catalyzed oxidizable compound and (b) at least one of a transition metal carboxylate, wherein the transition metal carboxylate comprises at least one carboxylate group and wherein each carboxylate group comprises between 20 and 30 carbon atoms, inclusive, such as cobalt behenate or cobalt arachidate.

Abstract: Herein are disclosed modified vinyl alcohol polymers (mPVOH), wherein the mPVOH can comprise structure VII: and at least one structure comprising structure IX: or structure X: wherein —R can independently comprise an unsubstituted hydrocarbon moiety comprising at least one alpha hydrogen or a substituted hydrocarbon moiety comprising at least one alpha hydrogen. The mPVOH can be useful in oxygen barrier applications, such as a forming an oxygen barrier layer of a packaging article. Also disclosed are methods of forming mPVOH and methods of using mPVOH to make packaging articles with a superior barrier to entry by atmospheric oxygen.

Abstract: Herein is disclosed an oxygen scavenging composition, comprising (i) an oxygen scavenging polymer comprising structure I: X—R—X—O—CH2—Ar—CH2—O,??(I) wherein —R— is selected from the group consisting of C1–C24 alkyl, C1–C24 substituted alkyl, C6–C24 aryl, and C6–C24 substituted aryl; —Ar— is selected from the group consisting of C6–C24 aryl and C6–C24 substituted aryl; and —X— is selected from the group consisting of null and —C(?O)—; (ii) a transition metal oxidation catalyst; and (iii) an energy-absorbing compound selected from the group consisting of microwave reactive materials and photoinitiators having a wavelength of maximum absorption of electromagnetic radiation from about 200 nm to about 750 nm. The oxygen scavenging composition can be used to form an oxygen barrier packaging article.

Abstract: Herein is disclosed multilayer packaging articles comprising an oxygen barrier layer comprising ethylene/vinyl alcohol copolymer (EVOH) (an “EVOH oxygen barrier layer”); an oxygen scavenging layer adjacent thereto, wherein the oxygen scavenging layer comprises a polymer comprising an ethylenic backbone and a cycloalkenyl group having structure I: wherein q1, q2, q3, q4, and r are independently selected from hydrogen, methyl, or ethyl; m is —(CH2)n—, wherein n is an integer from 0 to 4, inclusive, and, when r is hydrogen, at least one of q1, q2, q3, and q4 is also hydrogen; and a third layer adjacent to the oxygen scavenging layer. In addition to the oxygen scavenging function, the oxygen scavenging layer functions as a tie layer to substantially inhibit delamination of the EVOH oxygen barrier layer from the third layer of the packaging article.

Abstract: Disclosed is a process for esterifying and/or transesterifying a polymer having a polyethylenic backbone and pendant acid and/or ester moieties comprising contacting a melt of the polymer with a transesterifying compound so that the polymer undergoes esterification and/or transesterification but not alcoholysis. The esterified or transesterified polymer also has pendant ester moieties which differ in kind and/or number from the unreacted polymer. In one embodiment, the process also comprises adding an amount of a transition metal salt that is effective to promote oxygen scavenging. Also in a further embodiment, the process comprises irradiating the transesterified polymer with actinic radiation to reduce the induction period before oxygen scavenging commences. Also disclosed are compositions comprising a component which comprises an ethylenic or polyethylenic backbone and a pendant or terminal moiety comprising a benzylic, allylic, or ether-containing radical.

Abstract: We disclose a packaging article, defining a package interior and a package exterior, and comprising (i) a first layer, containing an oxygen scavenging polymer the oxygen scavenging polymer comprises (a) an ethylenic backbone or a polyester backbone and (b) at least one cyclic olefinic group; (ii) a second layer, containing a functional barrier polymer; and (iii) a transition metal organic salt in at least one of the first layer or a layer adjacent to the first layer; wherein the second layer is located between the first layer and the package interior. The packaging article can further comprise a functional absorber. Such a packaging article is capable of both scavenging oxygen present in the package interior and inhibiting the migration of off-taste- or off-odor-imparting scavenging byproducts from the first layer to the package interior.

Abstract: An oxygen scavenging composition or system is provided comprising an oxygen scavenging material, a photoinitiator, and at least one catalyst effective in catalyzing an oxygen scavenging reaction, wherein the photoinitiator comprises a benzophenone derivative containing at least two benzophenone moieties. A film, a multi-phase composition, a multi-layer composition, a multi-layer film, an article comprising the oxygen scavenging composition, a method for preparing the oxygen scavenging composition, and a method for scavenging oxygen are also provided. Non-extractable benzophenone derivative photoinitiators and methods for preparing same are also provided.

Abstract: Multilayer packaging articles contain (i) an oxygen scavenging tie layer which includes polypropylene-graft-acrylic acid (PP-g-AA), polypropylene-graft-maleic anhydride (PP-g-MA), or a mixture thereof; (ii) a second layer; and (iii) a third layer, wherein the oxygen scavenging-tie layer is located between the second layer and the third layer. In addition to the oxygen scavenging function, the oxygen scavenging tie layer functions as a tie layer to inhibit delamination of the second layer from the third layer, or vice versa.