Patents by Inventor Tadao Natsuume

Tadao Natsuume has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5885505
    Abstract: A molding frame made by molding a thermoplastic norbornene resin which hardly deforms even after repeated use is used for production of electronic part sealed bodies by sealing the electronic devices of integrated circuits such as light emitting diodes, diodes, transistors, LSI devices, IC devices and CCD devices and capacitors, resistors, coils, microswitches and dipswitches with thermosetting resins such as epoxy resins as sealants.
    Type: Grant
    Filed: August 25, 1997
    Date of Patent: March 23, 1999
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yuji Koushima, Teiji Kohara, Tadao Natsuume
  • Patent number: 5725960
    Abstract: A molded article having an adhesion of at least 50 squares per 100 squares in crosscut adhesion test and at least 40 squares per 100 squares even after kept in a warm water of 70.degree. C. for 1 hour, a haze value of 1.0% or less in Taber abrasion test and a pencil hardness of 2H or higher, said molded article being obtained by modifying the surface of a substrate formed of a thermoplastic norbornene resin to have a surface tension of 50 dynes/cm or greater by a treatment such as corona discharge treatment or the like or forming a preliminary primer layer of a modified product obtained by introducing a polar group into a copolymer of a vinyl aromatic compound and a conjugated diene, or the like; forming a primer layer for silicone hard coating agent on the modified surface or the preliminary primer layer, and then forming thereon a silicone hard coat layer, and a method for producing the molded article.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 10, 1998
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yuichiro Konishi, Tohru Hosaka, Mitsushi Tada, Tadao Natsuume, Nobukazu Takahashi, Teiji Kohara
  • Patent number: 5686156
    Abstract: A press-through package obtained by placing objects to be packed, in the accommodating pockets formed by vacuum forming or the like of a sheet made of a thermoplastic norbornene type resin, particularly preferably a hydrogenated product of ring-opening polymerization product of a dicyclopentadiene type monomer, and then closing the openings of pockets of the sheet with another sheet such as metal foil to pack the objects to be packed, which package makes the packed objects clearly visible in the pocket portions, prevents the deterioration of the packed objects by moisture bacause of its excellent water vapor barrier properties, and is good in production efficiency.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: November 11, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshiyasu Matsui, Tsutomu Hani, Teiji Kohara, Tadao Natsuume
  • Patent number: 5681900
    Abstract: A resin obtained by subjecting a norbornene type monomer having an aromatic ring structure (e.g. 5-phenyl-2-norbornene) to ring-opening polymerization and hydrogenating 95% or more of the unsaturated bonds in the backbone structure of the resulting polymer by the use of a catalyst composed of a combination of a transition metal compound and an alkyl metal compound, while leaving 80% or more of the aromatic ring structures, which resin has not only a high refractive index but also characteristics of a hydrogenated norbornene ring-opening polymerization product, i.e., excellent heat resistance, transparency, low birefringent properties, weather resistance, light resistance, low water absorption properties, moisture resistance, small dielectric constant, small dielectric loss, chemical resistance, etc., said resin being usable in optical materials, medical tools and materials, tools and materials for treating electronic parts, etc.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: October 28, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshihide Murakami, Teiji Kohara, Tadao Natsuume
  • Patent number: 5665795
    Abstract: A resin composition comprising 30-95 parts by weight of a thermoplastic norbornene resin and 5-70 parts by weight of a spherical inorganic filler having an average particle diameter of 0.05-50 .mu.m; and a precision molding produced therefrom.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: September 9, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yuji Koushima, Teiji Kohara, Tadao Natsuume
  • Patent number: 5599882
    Abstract: The present invention discloses a polycyclic norbornene-based ring-opening polymer which comprises(A) 90-5% by mol of a repeating unit represented by the following formula [I] or the alkyl-substituted derivative thereof, and(B) 10-95% by mol of at least one repeating unit selected from a repeating unit represented by the following formula [II], the alkyl-substituted derivative thereof, a repeating unit represented by the following formula [III], the alkyl-substituted derivative thereof, or the alkylidene-substituted derivative thereof, and which has an intrinsic viscosity [.eta.] of 0.01-20 dl/g as determined in toluene at 25.degree. C., the hydrogenation products thereof, and a process for production thereof ##STR1## wherein ------ denotes a single bond or a double bond.
    Type: Grant
    Filed: February 13, 1990
    Date of Patent: February 4, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yoshikatsu Nishi, Masayoshi Ohshima, Teiji Kohara, Toshiyasu Matsui, Tadao Natsuume
  • Patent number: 5580934
    Abstract: There are disclosed a polycyclic norbornene or its derivative hydrogenated copolymer which containsa repeating unit represented by the following formula [I] or the alkyl-substituted derivative thereof (A),a repeating unit represented by the following formula [II] or the alkyl-substituted derivative thereof (B) and, as desired,5-85% by mole of at least one repeating unit (C) selected from a repeating unit represented by the following formula [III], the alkyl-substituted derivative thereof, a repeating unit represented by the following formula [IV], the alkyl-substituted derivative and the alkylidene-substituted derivative thereof, and a process for producing the polycyclic norbornene or its derivative ring-opening hydrogenated copolymer ##STR1## wherein ------ represents either a single bond or a double bond.
    Type: Grant
    Filed: June 7, 1990
    Date of Patent: December 3, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yoshikatsu Nishi, Masayoshi Oshima, Teiji Kohara, Tadao Natsuume
  • Patent number: 5561208
    Abstract: A polymer composition comprising a thermoplastic norbornene polymer which preferably has a number average molecular weight of 10,00-200,000 as determined by gel permeation chromatography in toluene solvent and calculated as styrene and a content of norbornene polymer components having a number average molecular weight of 2,000 or less of 1% by weight or less, and a compounding ingredient, such as a rubber-like polymer, wherein the compounding ingredient is preferably dispersed in the form of microdomains in the norbornene polymer; and medical implements and optical naturals formed essentially of the composition.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: October 1, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Nobukazu Takahashi, Tohru Hosaka, Koji Minami, Yuichiro Konishi, Teiji Kohara, Tadao Natsuume
  • Patent number: 5543948
    Abstract: A phase plate comprises, as a birefringent layer, a film obtained by stretching and orienting a sheet of a thermoplastic saturated norbornene resin, which has been formed by melt forming. The phase plate of the invention is such that the birefringent layer is optically even at the whole surface, and such optical evenness remains constant even by changes of temperature, humidity and/or the like. The phase plate of the invention can be used in parts for polarization microscopes, parts for liquid crystal displays, etc., and is particularly suitable for use in a phase plate for liquid crystal displays.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: August 6, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Nobukazu Takahashi, Tsutomu Hani, Teiji Kohara, Tadao Natsuume
  • Patent number: 5539060
    Abstract: The present invention provides a method for hydrogenating a metathesis polymer solution obtained by polymerization in the presence of a metathesis polymerization catalyst comprising (a) the catalyst component of a transition metal compound and (b) the co-catalyst component of a metal compound by bringing the above solution into contact with hydrogen, without adding an inactivating agent for the metathesis polymerization catalyst, that is, with the solution left to contain the catalyst, in the presence of a hydrogenation catalyst comprising a transition metal compound (c) and a reductive metal compound (d) and if necessary by adding an acid-binding compound.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: July 23, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yasuo Tsunogae, Hideharu Mizuno, Teiji Kohara, Tadao Natsuume
  • Patent number: 5468803
    Abstract: A polymer composition including a thermoplastic norbornene polymer which preferably has a number average molecular weight of 10,00-200,000 as determined by gel permeation chromatography in toluene solvent and calculated as styrene and a content of norbornene polymer components having a number average molecular weight of 2,000 or less of 1% by weight or less, and a compounding ingredient, such as a rubber-like polymer, wherein the compounding ingredient is preferably dispersed in the form of microdomains in the norbornene polymer; and medical implements and optical naturals formed essentially of the composition.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: November 21, 1995
    Assignee: Nippon Zeon Co. Ltd.
    Inventors: Nobukazu Takahashi, Tohru Hosaka, Koji Minami, Yuichiro Konishi, Teiji Kohara, Tadao Natsuume
  • Patent number: 5462995
    Abstract: The present invention provides the hydrogenated product of a thermoplastic norbornene polymer excellent in characteristics as optical materials by reducing the residual amounts of the transition metal atoms originating from the polymerization catalyst used at the polymerization to 1 ppm or less of the hydrogenated product.Reduction of the residual amounts to below the desired level is attained by treating the reaction solution with the adsorbent during or after production of the hydrogenated product from the thermoplastic norbornene polymer.The hydrogenated product of the thermoplastic norbornene polymer thus obtained in which the residual amounts of the transition metal atoms are 1 ppm or less, has a wide utilization field, including a material for optical articles having excellent utilization characteristics such as substrates for optical elements, lenses and the like.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: October 31, 1995
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Tohru Hosaka, Hideharu Mizuno, Yuji Koushima, Teiji Kohara, Tadao Natsuume
  • Patent number: 5437926
    Abstract: A process for the production of a molded or formed article provided with a hard coat layer, which comprises coating a surface of a thermoplastic saturated norbornene polymer molded or formed article with a UV curable hard coating layer containing a solvent of an aromatic hydrocarbon series and/or solvent of an alicyclic hydrocarbon series, drying the resultant coating, and irradiating the dried coating with UV ray, and a molded or formed article provided with a hard coat layer having high hardness and excellent bond strength.
    Type: Grant
    Filed: July 20, 1992
    Date of Patent: August 1, 1995
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Nobukazu Takahashi, Teiji Kohara, Tadao Natsuume
  • Patent number: 5399646
    Abstract: The present invention discloses an alkylidenenorbornene polymer comprising as the essential constituent at least one kind of the structural unit represented by the formula ##STR1## wherein R.sub.1 denotes an alkyl group of 1-4 carbon atoms and R.sub.2 denotes a hydrogen atom or an alkyl group of 1-5 carbon atoms, and a process for producing the same.According to the present invention, an alkylidenenorbornene polymer is obtained which is excellent in light resistance, transparency, heat resistance and moisture resistance and is useful as an optical polymeric material.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: March 21, 1995
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Teiji Kohara, Shin-ichiro Tahara, Yoshitsugu Hirokawa, Tadao Natsuume
  • Patent number: 5366812
    Abstract: The present invention provides a thermoplastic composition excellent in heat resistance and water resistance which comprises a thermoplastic saturated norbornene polymer which has a number-average molecular weight (Mn) of 50,000-500,000 and a weight-average molecular weight (Mw) of 100,000-2,000,000 which are measured by high performance liquid chromatography, and a molecular weight distribution (Mw/Mn) of 2.2 or more, and a volatile content of at most 0.3% by weight. The composition is suitable for optical materials, electroconductive composite materials and optical recording media.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: November 22, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Nobukazu Takahashi, Teiji Kohara, Tadao Natsuume
  • Patent number: 5334424
    Abstract: A thermoplastic norbornene based molded article which can be used as a substrate for liquid crystal display having an excellent performance; said substrate having a specified surface roughness of 0.05 .mu.m or less, and a liquid crystal display produced therefrom.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: August 2, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Tsutomu Hani, Nobukazu Takahashi, Teiji Kohara, Tadao Natsuume
  • Patent number: 5310439
    Abstract: The present invention relates to a process for bonding a molded article of a thermoplastic saturated norbornene resin in which when the molded article is bonded to an adherend widely different from the molded article in coefficient of linear expansion, the adhesion surface of the molded article and that of the adherend are stuck together with an adhesive composed mainly of an epoxy resin which has an elasticity (Shore hardness D: about 40 or less) imparted by modification with a polymer having reactive silyl groups, and then the adhesive is cured. Thus, there is provided such an excellent bonding process that the adhesive strength is hardly deteriorated by a temperature change.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: May 10, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshiyasu Matsui, Hidenori Yukishige, Tadao Natsuume
  • Patent number: 5302656
    Abstract: A molded article, particularly for optical use, formed of a thermoplastic saturated norbornene-based polymer composition including a thermoplastic saturated norbornene-based polymer excellent in heat resistance, etc., and a filler, the composition being capable of preventing cracks even when an insertion part having a linear expansion coefficient greatly different from that of the polymer is present and a thermal change occurs. The filler is selected from a fibrous filler and a combination of a fibrous filler with a powdery filler.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: April 12, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Teiji Kohara, Tadao Natsuume
  • Patent number: 5276098
    Abstract: A composition including a thermoplastic saturated norbornene group polymer and a partially etherified product of a polyhydric alcohol having at least 3 hydroxyl groups incorporated thereinto. The composition exhibits excellent adhesion to the recording film of an optical disk and adhesion to a hard coating film or a protective film formed by coating an acrylic ultraviolet curing coating material or like films without deteriorating the excellent heat resistance and transparency inherent to thermoplastic saturated norbornene group polymers. An optical disk substrate formed of this composition and an optical disk including the optical disk substrate and an information recording film and/or a light reflecting film and a protective film laminated thereon are also disclaimed.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: January 4, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Teiji Kohara, Tadao Natsuume
  • Patent number: 5252190
    Abstract: A harmful substance remover, which is used to remove any of ethylene, mercaptans, amines and aldehydes, is a solid product having a specific surface area of 100 m.sup.2 /g or more obtained by hydrolyzing a metal alkoxide in the presence or absence of a noble metal. The harmful substance remover is utilized by contacting a harmful substance therewith. Such contacting may take place under irradiation of ultraviolet rays.
    Type: Grant
    Filed: March 1, 1991
    Date of Patent: October 12, 1993
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Kenichi Sekiguchi, Tsunehisa Ueda, Tadao Natsuume