Patents by Inventor Tadao Shimomura
Tadao Shimomura has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6335406Abstract: A method for the production of (D) an absorbent resin excelling in durability, which method comprises polymerizing (A) 30% by weight to saturated concentration of (A) an aqueous water-soluble ethylenically unsaturated monomer solution containing (B) 0.005 to 5 mol % of a cross-linking agent and (C) 0.001 to 1 mol % of a water-soluble chain transfer agent, both based on the amount of said monomer (A), and if necessary, the surface region of the resultant absorbent resin (D) is cross-linked with (E) a hydrophilic cross-linking agent capable of reacting with the functional group of the absorbent resin and an absorbent resin obtained by such method.Type: GrantFiled: March 1, 1993Date of Patent: January 1, 2002Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Kinya Nagasuna, Kenji Kadonaga, Kazumasa Kimura, Tadao Shimomura
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Patent number: 6150469Abstract: A hydrophilic polymer is denatured with a gaseous denaturant or a powdery denaturant substance made from a liquid denaturant substance. The liquid denaturant substance is made into powders by, for example, a method of mixing the liquid denaturant substance with a water-insoluble compound, a method of cooling the liquid denaturant substance to or below its melting point to turn the same into a solid state. Consequently, the hydrophilic polymer can be denatured uniformly. In case that the hydrophilic polymer is denatured with a gaseous denaturant, the hydrophilic polymer and denaturant react with each other efficiently in a safe manner regardless of the size or shape of the hydrophilic polymer. In case that the hydrophilic polymer is denatured with the powdery denaturant substance, not only the liquid denaturant substance which is substantially in the solid state can be mixed with the hydrophilic polymer, but also the denaturation timing can be readily controlled.Type: GrantFiled: September 29, 1997Date of Patent: November 21, 2000Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuyuki Harada, Shigeru Sakamoto, Yoshihiro Motono, Tadao Shimomura
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Patent number: 6087002Abstract: A process for producing water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the polymer so obtained, and crosslinking the surface of the polymer powder.Type: GrantFiled: October 29, 1997Date of Patent: July 11, 2000Assignee: Nippon Shokubai Kagaku Kogyo Co. Ltd.Inventors: Kazumasa Kimura, Kinya Nagasuna, Takashi Namba, Kenji Kadonaga, Koji Miyake, Tadao Shimomura
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Patent number: 6083417Abstract: A thermal storage agent used, for example, for air-conditioning systems of buildings, exhibiting excellent thermal storage, thermal conduction and safety, and a manufacturing method thereof. The thermal storage agent contains particulate oil gel bodies prepared by letting an oil absorbent resin absorb, and thus swell with, a thermal storage oil-soluble substance, wherein the oily gel bodies have a unitary volume of not less than 0.01 cm.sup.3 and are in contact with one another. A manufacturing method in accordance with the present invention can produce the thermal storage agent by letting an oil absorbent resin that is prepared by suspension polymerization in a solution containing the oil-soluble substance absorb, and thus swell with, the oil-soluble substance.Type: GrantFiled: November 18, 1997Date of Patent: July 4, 2000Assignee: Nippon Shokubai Co., Ltd.Inventors: Tomoki Gomi, Yoshio Irie, Tadao Shimomura
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Patent number: 5624967Abstract: A process for producing a water-absorbing resin, which comprises polymerizing (D) an aqueous solution comprising (A) at least one monomer component selected from the group consisting of an unsaturated carboxylic acid and salts thereof; (B) a compound having two or more unsaturated groups in a molecule; and (C) a compound having two or more functional groups which are capable of reacting with carboxyl groups in a molecule, the polymerization being conducted in such a manner that the following conditions (a) to (c) are simultaneously satisfied: (a) the molar ratio (B)/(C) being in the range of from 2.times.10.sup.-3 to 300, (b) the polymerization being initiated by a redox polymerization initiator, and (c) the maximum reaction temperature being in the range of from 60.degree. to 100.degree. C, and a water-absorbing resin having a degree of reduction in absorption magnification of from 1 to 16, and n absorption magnification under pressure of from 20 to 40.Type: GrantFiled: June 7, 1995Date of Patent: April 29, 1997Assignee: Nippon Shokubai Co., Ltd.Inventors: Kazuhisa Hitomi, Takumi Hatsuda, Tadao Shimomura
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Patent number: 5599763Abstract: An absorbent material produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, an absorbent body produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, dry mixing the resultant mixture with 10 to 1,000 parts by weight hydrophilic fibers based on 100 parts by weight of said absorbent polymer, pneumatically molding the resultant mixture in the form of web, and thermally compressing the resultant web to a density in the range of from 0.1 to 1.0 g/cm.sup.3, and a method for production thereof.Type: GrantFiled: August 3, 1994Date of Patent: February 4, 1997Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuyuki Harada, Kazumasa Kimura, Tadao Shimomura
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Patent number: 5382610Abstract: The present invention provides a water absorbent matter which is physically and chemically stable, difficult in shifting and falling-off of a water-absorbent resin particle and from a cellulose fiber, and thereby, has superior water-absorbent properties. A water absorbent matter like this is made by containing a water-absorbent resin particle having an acidic group such as a carboxyl group on the surface, a cellulose fiber, and a cationic high-molecular compound having a weight-average molecular weight of 2,000 or more, so that the water-absorbent resin particle is firmly set on the cellulose fiber by a cationic high-molecular compound in the presence of water.Type: GrantFiled: October 27, 1993Date of Patent: January 17, 1995Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuyuki Harada, Katsuyuki Wada, Hisanori Obara, Tadao Shimomura, Yoshinori Sano
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Patent number: 5368918Abstract: An absorbent material produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, an absorbent body produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, dry mixing the resultant mixture with 10 to 1,000 parts by weight hydrophilic fibers based on 100 parts by weight of the absorbent polymer, pneumatically molding the resultant mixture in the form of web, and thermally compressing the resultant web to a density in the range of from 0.1 to 1.0 g/cm.sup.3, and a method for production thereof.Type: GrantFiled: August 29, 1991Date of Patent: November 29, 1994Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuyuki Harada, Kazumasa Kimura, Tadao Shimomura
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Patent number: 5338810Abstract: A method for the production of an acrylate by the neutralization reaction of acrylic acid and a basic substance, comprising sequentially (A) a step of supplying acrylic acid and said basic substance to water thereby subjecting them to a neutralization reaction while constantly retaining the neutralization ratio of acrylic acid within the neutralization reaction system in the range of 75 to 100 mol %, (B) a step of adjusting the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.1 to 110 mol % by supplying said basic substance to said neutralization reaction system, (C) a step of retaining the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.Type: GrantFiled: March 8, 1993Date of Patent: August 16, 1994Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Tadao Shimomura, Yoshio Irie, Hitoshi Takahashi, Katsuhiro Kajikawa, Jyunichi Saga, Teruaki Fujiwara, Takumi Hatsuda
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Patent number: 5296650Abstract: A waterproofing agent for an optical or electric cable, formed of a cross-linked macromolecular compound containing a sulfonic acid group or a salt thereof in an amount of not less than 0.5 mg. equivalent/g and a dissociating group in an amount of not less than 1.0 mg. equivalent/g, and a method for waterproofing said cable by packing said waterproofing agent in the sheath of said cables.Type: GrantFiled: December 2, 1992Date of Patent: March 22, 1994Assignee: Nippon Shokubai Kagaku Kogyko Co., Ltd.Inventors: Hiroya Kobayashi, Tadao Shimomura, Kazuhiro Okamura, Yoshinori Sano
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Patent number: 5244735Abstract: Water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less are prepared by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the gel-like polymer so obtained, and crosslinking the surface of the polymer powder. In an alternative process, an aqueous solution of the monomer having a viscosity greater than 15 cps is dispersed in a hydrophobic organic solvent and polymerized to obtain a polymer powder, and the surface of the polymer powder is crosslinked.Type: GrantFiled: December 11, 1992Date of Patent: September 14, 1993Assignee: Nippon Shokubai Kagaku Kabushiki KaishaInventors: Kazumasa Kimura, Kinya Nagasuna, Takashi Namba, Kenji Kadonaga, Koji Miyake, Tadao Shimomura
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Patent number: 5213893Abstract: A cable grade water proofing agent made of a cross-linked polymer produced by polymerizing a monomer mixture comprising at least one (meth)acrylic compound selected from the group consisting of (meth)acrylic acids and (meth)acrylic salts and a (meth)acrylamide in a molar ratio of said (meth)acrylic compound to said (meth)acrylamide in the range of from 1:9 to 5:5, said cross-linked polymer exhibiting a speed of absorption of not more than 8 minutes as expressed by the time required for the absorption of artificial seawater to reach 90% of the maximum, a capacity for absorption of said artificial seawater of not less than 8 times the own weight, and a gel viscosity in the range of from 0.6.times.10.sup.5 to 2.5.times.10.sup.5 dynes.multidot.s/cm.sup.3, and a composite waterproofing material carried on a substrate such as yarns and tape.Type: GrantFiled: September 11, 1991Date of Patent: May 25, 1993Assignee: Nippon Shokubai Co., Ltd.Inventors: Hiroya Kobayashi, Kazuhiro Okamura, Yoshiyuki Takahashi, Tadao Shimomura
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Patent number: 5210298Abstract: A method for the production of an acrylate by the neutralization reaction of acrylic acid and a basic substance, comprising sequentially (A) a step of supplying acrylic acid and said basic substance to water thereby subjecting them to a neutralization reaction while constantly retaining the neutralization ratio of acrylic acid within the neutralization reaction system in the range of 75 to 100 mol %, (B) a step of adjusting the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.1 to 110 mol % by supplying said basic substance to said neutralization reaction system, (C) a step of retaining the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.Type: GrantFiled: October 27, 1989Date of Patent: May 11, 1993Assignee: Nippon Shokubai Kagaku Kogyo, Co., Ltd.Inventors: Tadao Shimomura, Yoshio Irie, Hitoshi Takahashi, Katsuhiro Kajikawa, Jyunichi Saga, Teruaki Fujiwara, Takumi Hatsuda
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Patent number: 5195999Abstract: An absorbent body having an absorbent polymer and hydrophilic fibers as main components thereof, characterized by the fact that the density of said absorbent body is in the range of from 0.1 to 0.5 g/cm.sup.3 or a ratio of wet swelling is not less than 200%, a capacity of said absorbent body for absorption of physiological saline solution under pressure is in the range of from 11 to 25 g/g, and the ratio of exfoliation of said absorbent polymer is not more than 45%, and an absorbent article comprising a liquid-pervious surface material, a liquid-impervious lining material, and the absorbent body layer interposed therebetween.Type: GrantFiled: August 29, 1991Date of Patent: March 23, 1993Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuyuki Harada, Kazumasa Kimura, Tadao Shimomura
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Patent number: 5190815Abstract: A waterproofing agent for an optical or electric cable, formed of a cross-linked macromolecular compound containing a sulfonic acid group or a salt thereof in an amount of not less than 0.5 mg. equivalent/g and a dissociating group in an amount of not less than 1.0 mg. equivalent/g, and a method for waterproofing said cable by packing said waterproofing agent in the sheath of said cables.Type: GrantFiled: June 17, 1991Date of Patent: March 2, 1993Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Hiroya Kobayashi, Tadao Shimomura, Kazuhiro Okamura, Yoshinori Sano
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Patent number: 5115011Abstract: This invention relates to a process for producing a quality-improved water-absorbent polymer in which the aqueous liquid (I), which is obtained by mixing in an aqueous medium at least one kind of a water-soluble salt (A) selected from a group of halogenated compounds, sulfates, acetates, and nitrates, which are derived from at least one kind of a polyvalent metal selected from a group of aluminum, calcium, and magnesium, with at least one kind of a water-soluble salt (B) selected from a group of monovalent metal salts and ammonium salts, which are derived from at least one kind of an oxyacid selected from a group of sulfurous acid and thiosulfuric acid, is mixed with a water-absorbent polymer (II) in a proportion of that the water-soluble salt of the polyvalent metal (A) is in a range of 0.1.about.10 parts by weight against 100 parts by weight of the water-absorbent polymer (II) and the water-soluble salt of the oxyacid (B) is in a range of 0. 1.about.Type: GrantFiled: February 20, 1990Date of Patent: May 19, 1992Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Nobuyuki Harada, Toshihiro Okuno, Tadao Shimomura
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Patent number: 5098775Abstract: In a body fluid-absorbing article composed of a liquid-permeable front-surface member, a liquid-impermeable rear-surface member, and a fibrous absorbent member nipped therebetween and adapted to be used with the front-surface member held in contact with the human body, by the improvement having disposed in half of the thickness of the absorbent member on the front-surface member side an absorbent composite (A) obtained by applying an ethylenically unsaturated monomer capable of forming an absorbent polymer by polymerization or an aqueous solution of the monomer to a fibrous web and thereafter polymerizing the monomer.Type: GrantFiled: March 26, 1990Date of Patent: March 24, 1992Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Nobuyuki Harada, Yoshihiro Motono, Kazumasa Kimura, Tadao Shimomura
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Patent number: 5078992Abstract: Disclosed herein are a water-absorbing resin composition composed of a water-absorbing resin and a metallophthalocyanine, and a method for utilizing the water-absorbing resin composition as a deodorant in the presence of water.Type: GrantFiled: March 6, 1990Date of Patent: January 7, 1992Assignees: Ahsu Kurin Kabushiki Kaisha, Nisshin Seifun Kabushiki Kaisha, Nippon Shokubai Co., Ltd.Inventors: Yoshiyuki Takahashi, Tadao Shimomura, Naoyuki Shirane
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Patent number: 5079034Abstract: A method of preparation of an absorbent composite in which an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization is applied to a substrate, and the monomer is polymerized while the substrate to which the aqueous solution is applied is, on both the sides, held in contact with polymerization-inert surfaces facing each other. A continuous manufacturing method includes the sequential steps of continuously passing a substrate through (1) a region applying to the substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization, and (2) a region of polymerizing the monomer while maintaining the substrate, on both the sides, in contact with polymerization-inert surfaces facing each other.Type: GrantFiled: November 17, 1989Date of Patent: January 7, 1992Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Koji Miyake, Nobuyuki Harada, Kazumasa Kimura, Tadao Shimomura
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Patent number: 5026800Abstract: Water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less are prepared by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the gel-like polymer so obtained, and crosslinking the surface of the polymer powder. In an alternative process, an aqueous solution of the monomer having a viscosity greater than 15 cps is dispersed in a hydrophobic organic solvent and polymerized to obtain a polymer powder, and the surface of the polymer powder is crosslinked.Type: GrantFiled: June 26, 1989Date of Patent: June 25, 1991Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Kazumasa Kimura, Kinya Nagasuna, Takashi Namba, Kenji Kadonaga, Koji Miyake, Tadao Shimomura