Abstract: A platinum-phosphite ester complex-containing hydrosilylation catalyst has good storage stability and comprises: a platinum-phosphite ester complex composed of platinum and a phosphite ester compound having a specific structure; and a liquid alkenyl group-containing siloxane compound containing an organopolysiloxane compound having two or more adjacent alkenyl groups, the catalyst being free of a hydrocarbon-based organic solvent and being liquid at 23° C. By using the catalyst, a one-component (one-part) curable organopolysiloxane composition free of a hydrocarbon-based organic solvent can be easily obtained, and the resulting one-component curable organopolysiloxane composition has stable characteristics and physical properties even when exposed to ambient temperature for a long period of time.

Abstract: This addition reaction curing-type self-adhesive silicone gel composition has a predetermined amount of a specific non-functional organopolysiloxane added thereto, has predetermined amounts of a specific carboxylic acid metal salt and a partial hydrolysis-condensation product of a specific hydrolysable silane added thereto, and can be used to provide a silicone gel cured product that has sufficient adhesiveness to a metal substrate made of copper, aluminum, or the like, that can prevent generation of voids or detachment after adhesion even under high temperature conditions, and that has a high dielectric strength.

Abstract: A curable silicone gel composition including: (A) 100 parts by mass of a branched-chain organosiloxane that has a specific structure; (B) 0.1-50 parts by mass of a diorganopolysiloxane in which both molecular chain terminals are blocked with a diorganohydrogensiloxy group; (C) a platinum-based catalyst; (D) a phosphorous acid triester compound in an amount that is 3-15 molecules per one platinum atom in the (C) component, said phosphorous acid triester compound having a structure in which a chain alkyl group is bonded to an oxygen atom of phosphorous acid; (E) an organic peroxide for which the 10-hour half-life temperature is 120° C. or greater, in an amount that is 5-50 times the amount of the (D) component; and (F) an oxidation inhibitor. This curable silicone gel composition demonstrates superior high-temperature storability and deep section curability.

Abstract: A one-pack type curable silicone gel composition which contains: 100 parts by mass of (A) a branched chain organopolysiloxane having a specific structure from 0.1 part by mass to 50 parts by mass of (B) a diorganopolysiloxane having both molecular chain ends blocked with diorganohydrogensiloxy groups; (C) a platinum-based catalyst; and (D) a phosphite compound represented by formula (3) (wherein R2 represents a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms; and X represents a hydrogen atom or a methyl group) in such an amount that more than 3 molecules hut not more than 15 molecules of the phosphite compound represented by formula (3) are present per one platinum atom in component (C). This one-pack type curable silicone gel composition is stable in terms of characteristics and physical properties even if exposed to a temperature more than 50° C. for a long period of time.

Abstract: Provided is a room temperature moisture-curable silicone gel composition containing: (A) diorganopolysiloxane, both terminals of which are blocked by silanol groups; (B) hydrolysable organosilicon compound represented by Formula (2) and/or a partial hydrolysate thereof (where R2 is a monovalent hydrocarbon group, R3 is an alkyl group or a cycloalkyl group, and a is 2 or 3.); (C) a curing catalyst; and (D) a heat-resistant aid containing a homogeneous mixture of (D-a), (D-b), and (D-c) (where (D-a) is organopolysiloxane having a viscosity of 10-10,000 mPa·s at 25° C., (D-b) is carboxylate of cerium, and (D-c) is a titanium compound and/or a partial hydrolytic condensate thereof). This room temperature moisture-curable silicone gel composition can be a silicone gel cured product which has a small variation rate of low-stress properties evaluated by the index such as penetration even under heat-resistant conditions exceeding 230° C. and which has excellent heat-resistance.

Abstract: A one-pack type curable silicone gel composition which contains: 100 parts by mass of (A) a branched chain organopolysiloxane having a specific structure from 0.1 part by mass to 50 parts by mass of (B) a diorganopolysiloxane having both molecular chain ends blocked with diorganohydrogensiloxy groups; (C) a platinum-based catalyst; and (D) a phosphite compound represented by formula (3) (wherein R2 represents a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms; and X represents a hydrogen atom or a methyl group) in such an amount that more than 3 molecules hut not more than 15 molecules of the phosphite compound represented by formula (3) are present per one platinum atom in component (C). This one-pack type curable silicone gel composition is stable in terms of characteristics and physical properties even if exposed to a temperature more than 50° C. for a long period of time.

Abstract: This addition reaction curing-type self-adhesive silicone gel composition has a predetermined amount of a specific non-functional organopolysiloxane added thereto, has predetermined amounts of a specific carboxylic acid metal salt and a partial hydrolysis-condensation product of a specific hydrolysable silane added thereto, and can be used to provide a silicone gel cured product that has sufficient adhesiveness to a metal substrate made of copper, aluminum, or the like, that can prevent generation of voids or detachment after adhesion even under high temperature conditions, and that has a high dielectric strength.

Abstract: Provided is a room temperature moisture-curable silicone gel composition containing: (A) diorganopolysiloxane, both terminals of which are blocked by silanol groups; (B) hydrolysable organosilicon compound represented by Formula (2) and/or a partial hydrolysate thereof (where R2 is a monovalent hydrocarbon group, R3 is an alkyl group or a cycloalkyl group, and a is 2 or 3.); (C) a curing catalyst; and (D) a heat-resistant aid containing a homogeneous mixture of (D-a), (D-b), and (D-c) (where (D-a) is organopolysiloxane having a viscosity of 10-10,000 mPa·s at 25° C., (D-b) is carboxylate of cerium, and (D-c) is a titanium compound and/or a partial hydrolytic condensate thereof). This room temperature moisture-curable silicone gel composition can be a silicone gel cured product which has a small variation rate of low-stress properties evaluated by the index such as penetration even under heat-resistant conditions exceeding 230° C. and which has excellent heat-resistance.

Abstract: Provided is a curable organopolysiloxane composition from which highly heat-resistant cured products can be obtained, the curable organopolysiloxane composition comprising: (A) 100 parts by mass of a novel organopolysiloxane represented by formula (1) (R1 is an alkyl group or an alkoxy substituted alkyl group having 1 to 6 carbon atoms, R2 is a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a group in which a portion of the hydrogen atoms of those groups is substituted with a halogen atom, Ar is an arylene group having 6 carbon atoms or more, a is 1 to 1,000, b is 1 to 5,000, and n is 1 to 3, the total of n in an unsubstituted or substituted alkoxysilyl group on both ends of the molecular chain being 3 or more); and (B) 0.01 to 10 parts by mass of a curing catalyst. Also provided are electrical and electronic components, a vehicle oil seal, a building sealant, etc. which use the cured product of the composition.

Abstract: Provided are: a silicone gel composition providing a silicone gel cured product having excellent heat resistance at high temperatures; and a cured product (silicone gel) thereof. This silicone gel composition is an addition reaction-curable silicone gel composition containing, with respect to the total (mass) of the composition, 1-1,000 ppm of a niobium carboxylate and/or nickel carboxylate represented by the following formula (3). (R3COO)fM??(3) (In the formula, R3 is a homogeneous or heterogeneous monovalent hydrocarbon group, M is at least one metal selected from among nickel and niobium, and f is 2 when M is nickel and 4 or 5 when M is niobium).

Abstract: Provided are a recombinant microorganism comprising: a gene encoding a pyridoxine oxidase; and a gene encoding a pyridoxamine synthetase having an enzymatic activity of synthesizing pyridoxamine from pyridoxal, in which each of the gene encoding a pyridoxine oxidase and the gene encoding a pyridoxamine synthetase is introduced from outside of a bacterial cell, or is endogenous to the bacterial cell and has an enhanced expression, and a method of producing pyridoxamine or a salt thereof from pyridoxine or a salt thereof using the recombinant microorganism.

Abstract: A recombinant microorganism includes a gene encoding a pyridoxine dehydrogenase, a gene encoding a pyridoxamine synthetase having an enzymatic activity of synthesizing pyridoxamine from pyridoxal, and a gene encoding an amino acid regeneration enzyme having an enzymatic activity of regenerating an amino acid consumed by the pyridoxamine synthetase, in which at least two of the gene encoding the pyridoxine dehydrogenase, the gene encoding the pyridoxamine synthetase, or the gene encoding the amino acid regeneration enzyme, are introduced from outside of a bacterial cell, or are endogenous to the bacterial cell and have an enhanced expression. In addition, a recombinant microorganism into which a gene encoding a pyridoxine dehydrogenase is introduced is provided.

Abstract: Provided is a curable organopolysiloxane composition from which highly heat-resistant cured products can be obtained, the curable organopolysiloxane composition comprising: (A) 100 parts by mass of a novel organopolysiloxane represented by formula (1) (R1 is an alkyl group or an alkoxy substituted alkyl group having 1 to 6 carbon atoms, R2 is a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a group in which a portion of the hydrogen atoms of those groups is substituted with a halogen atom, Ar is an arylene group having 6 carbon atoms or more, a is 1 to 1,000, b is 1 to 5,000, and n is 1 to 3, the total of n in an unsubstituted or substituted alkoxysilyl group on both ends of the molecular chain being 3 or more); and (B) 0.01 to 10 parts by mass of a curing catalyst. Also provided are electrical and electronic components, a vehicle oil seal, a building sealant, etc. which use the cured product of the composition.

Abstract: This invention relates to DNA encoding a novel enzyme having activity of synthesizing D-serine from formaldehyde and glycine, recombinant DNA constructed by integrating such DNA into a vector, a transformant transformed with the recombinant DNA, and a method for producing D-serine from formaldehyde and glycine with the use of the enzyme.

Abstract: Provided are: a silicone gel composition providing a silicone gel cured product having excellent heat resistance at high temperatures; and a cured product (silicone gel) thereof. This silicone gel composition is an addition reaction-curable silicone gel composition containing, with respect to the total (mass) of the composition, 1-1,000 ppm of a niobium carboxylate and/or nickel carboxylate represented by the following formula (3). (R3COO)fM??(3) (In the formula, R3 is a homogeneous or heterogeneous monovalent hydrocarbon group, M is at least one metal selected from among nickel and niobium, and f is 2 when M is nickel and 4 or 5 when M is niobium.

Abstract: An acetyl-CoA-producing microorganism, which is capable of efficiently synthesizing acetyl-CoA using carbon dioxide, and a substance production method using the same are provided. An acetyl-CoA-producing microorganism including an acetyl-CoA production cycle obtained by imparting at least one type of enzymatic activity selected from the group consisting of malate thiokinase, malyl-CoA lyase, glyoxylate carboligase, 2-hydroxy-3-oxopropionate reductase, and hydroxypyruvate reductase, to a microorganism.

Abstract: This invention relates to DNA encoding a novel enzyme having activity of synthesizing D-serine from formaldehyde and glycine, recombinant DNA constructed by integrating such DNA into a vector, a transformant transformed with the recombinant DNA, and a method for producing D-serine from formaldehyde and glycine with the use of the enzyme.

Abstract: A mutant lysine decarboxylase produced by replacing at least one of the amino acids in SEQ ID NO:4 with another amino acid.

Abstract: A room-temperature-curable organopolysiloxane composition contains as essential components (A) an organopolysiloxane shown by the following general formula (1), (B) an alkoxysilane shown by the following general formula (2) or a partial hydrolysate thereof, (C) a silazane compound shown by the following general formula (3), (D) a bismuth compound shown by the following general formula (4) which is in a liquid state at 20° C., a partial hydrolysate thereof, or both of them, (E) one or more fillers, and (F) a silane coupling agent having amine structure or imine structure, in which the composition satisfies [component (C)/component (B)?1.0]. As a result, a room-temperature-curable organopolysiloxane composition has good curability and storage stability even without containing an organotin compound or an organotitanium compound, has safety in view of toxicity to the human body and environment, and exhibits good rubber physical properties and adhesion after curing.

Abstract: This invention relates to DNA encoding a novel enzyme having activity of synthesizing D-serine from formaldehyde and glycine, recombinant DNA constructed by integrating such DNA into a vector, a transformant transformed with the recombinant DNA, and a method for producing D-serine from formaldehyde and glycine with the use of the enzyme.