Abstract: A negative electrode active material comprising: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6), and wherein the particles of silicon compound have, as chemical shift values obtained from a 29Si-MAS-NMR spectrum, an intensity A of a peak derived from amorphous silicon obtained in ?40 to ?60 ppm, an intensity B of a peak derived from silicon dioxide obtained in the vicinity of ?110 ppm, and an intensity C of a peak derived from Si obtained in the vicinity of ?83 ppm, which satisfy the following formula 1 and formula 2. B?1.

Abstract: A negative electrode active material for a non-aqueous electrolyte secondary battery containing a negative electrode active material particle which includes a silicon compound particle containing a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle contains a Li compound, at least a part of the silicon compound particle is coated with a carbon material, and at least a part of a surface of the silicon compound particle, a surface of the carbon material, or both of them is coated with a layer containing a compound having a silyl group.

Abstract: A negative electrode active material containing negative electrode active material particles. The negative electrode active material particles include silicon compound particles each containing an oxygen-containing silicon compound. The silicon compound particle contains at least one of Li2SiO3 and Li2Si2O5. The silicon compound particle has, in a Si K-edge spectrum obtained from a XANES spectrum: a peak P derived from the Li silicate and located near 1847 eV; and a peak Q gentler than the peak P and located near 1851 to 1852 eV. This provides a negative electrode active material that is capable of stabilizing a slurry when the negative electrode active material is used for a secondary battery, and capable of increasing the battery capacity by improving the initial efficiency.

Abstract: The inventive negative electrode active material for a non-aqueous electrolyte secondary battery contains negative electrode active material particles which include silicon compound (SiOx: 0.5?x?1.6) particles. The negative electrode active material particles are at least partially coated with a carbon material, contain one or more selected from Li2SiO3 and Li2Si2O5, and satisfy Ib/Ia?4.8 and Ic/Ia?6.0 in an X-ray diffraction measurement using a Cu-K? line. Ia represents an intensity of a peak around 2?=28.4° attributable to Si obtained by the X-ray diffraction. Ib represents a peak intensity of a peak attributable to Li2SiO3 obtained by the X-ray diffraction. Ic represents a peak intensity of a peak attributable to Li2Si2O5 obtained by the X-ray diffraction.

Abstract: A negative electrode material containing a negative electrode active material particle which includes a silicon compound particle containing a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle contains at least one or more of Li2SiO3 and Li4SiO4, and the negative electrode material further contains at least one of a metal compound particle containing a metal compound and an aggregate of the metal compound particle. The negative electrode material is capable of stabilizing a slurry prepared in production of a negative electrode for a secondary battery, and improving initial charge-discharge characteristics and cycle characteristics when it is used as a negative electrode active material for a secondary battery.

Abstract: A negative electrode material containing a negative electrode active material particle which includes a silicon compound particle containing a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle contains at least one or more of Li2SiO3 and Li4SiO4, and the negative electrode material further contains at least one of a metal compound particle containing a metal compound and an aggregate of the metal compound particle. The negative electrode material is capable of stabilizing a slurry prepared in production of a negative electrode for a secondary battery, and improving initial charge-discharge characteristics and cycle characteristics when it is used as a negative electrode active material for a secondary battery.

Abstract: A negative electrode active material for a non-aqueous electrolyte secondary battery, containing negative electrode active material particles, including silicon compound particles each containing a silicon compound (SiOx: 0.5?x?1.6) and at least one or more of Li2SiO3 and Li2Si2O5, the material includes a phosphate, the negative electrode active material particles each have a surface containing lithium element, and a ratio mp/ml satisfies 0.02?mp/ml?3, where ml represents a molar quantity of the lithium element and contained per unit mass of the particles, and mp represents a molar quantity of phosphorus element contained per unit mass of the particles. Thereby, a negative electrode active material is capable of stabilizing an aqueous negative electrode slurry prepared in producing a negative electrode of a secondary battery, and capable of improving initial charge-discharge characteristics when the negative electrode active material is used for a secondary battery.

Abstract: A negative electrode active material containing a negative electrode active material particle; the negative electrode active material particle including a silicon compound shown by SiOx (0.5?x?1.6), and having a peak in a range of 539 to 541 eV in a XANES spectrum obtained by XANES measurement of the negative electrode active material particle. This provides a negative electrode active material that is capable of increasing battery capacity and improving cycle performance when it is used as a negative electrode active material for a secondary battery.

Abstract: Methods for producing a negative electrode active material particle which includes a silicon compound particle containing a silicon compound that contains oxygen. The methods including preparing a silicon compound particle containing a silicon compound that contains oxygen; inserting Li into the silicon compound particle; and heating, while stirring, the Li-inserted silicon compound particle in a furnace to produce a negative electrode active material particle, wherein at least part of Si constituting the silicon compound particle is present in at least one state selected from oxide of Si2+ to Si3+ containing no Li, and compound containing Li and Si2+ to Si3+.

Abstract: A negative electrode including a negative electrode active material layer including a negative electrode active material including a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle includes crystalline Li2SiO3 in at least part of the silicon compound particle. Among a peak intensity A derived from Li2SiO3, a peak intensity B derived from Si, a peak intensity C derived from Li2Si2O5, and a peak intensity D derived from SiO2 which are obtained from a 29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity A is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the following formula 1: Formula 1: 3C<A.

Abstract: A negative electrode active material containing a negative electrode active material particle which includes a silicon compound particle containing a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle has three or more peaks in a chemical shift value ranging from ?40 ppm to ?120 ppm but has no peak in a chemical shift value within a range of ?65±3 ppm in a spectrum obtained from 29Si-MAS-NMR of the silicon compound particle. This provides a negative electrode active material capable of improving cycle characteristics when it is used as a negative electrode active material for a secondary battery.

Abstract: A negative electrode active material comprising: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6), and wherein the particles of silicon compound have, as chemical shift values obtained from a 29Si-MAS-NMR spectrum, an intensity A of a peak derived from amorphous silicon obtained in ?40 to ?60 ppm, an intensity B of a peak derived from silicon dioxide obtained in the vicinity of ?110 ppm, and an intensity C of a peak derived from Si obtained in the vicinity of ?83 ppm, which satisfy the following formula 1 and formula 2. B?1.

Abstract: A negative electrode active material particle including: a silicon compound particle containing a silicon compound that contains oxygen, wherein the silicon compound particle contains a Li compound; and the negative electrode active material particle including aluminum phosphorous composite oxide attached to at least part of the surface, wherein the aluminum phosphorous composite oxide is a composite of P2O5 and Al2O3, and the P2O5 and the Al2O3 are in a mass ratio in a range of 1.2<mass of the P2O5/mass of the Al2O3<3.0, wherein the negative electrode active material particle including aluminum phosphorous composite oxide has at least one peak in a region of a binding energy of more than 135 eV and 144 eV or less in a P 2p peak shape given in an X-ray photoelectron spectroscopy.

Abstract: A negative electrode active material includes: particles of negative electrode active material, the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6); the particles of silicon compound contain at least one kind or more of Li2SiO3 and Li4SiO4; the particles of negative electrode active material contain Li2CO3 and LiOH on a surface thereof; and a content of the Li2CO3 is 0.01% by mass or more and 5.00% by mass or less relative to a mass of the particles of negative electrode active material and a content of the LiOH is 0.01% by mass or more and 5.00% by mass or less relative to the mass of the particles of negative electrode active material. Thus a negative electrode active material is capable of improving initial charge/discharge characteristics and the cycle characteristics when used as a negative electrode active material of the secondary battery.

Abstract: A negative electrode active material for a non-aqueous electrolyte secondary battery, containing a negative electrode active material particle, wherein the negative electrode active material particle includes a silicon compound particle containing a silicon compound (SiOx: 0.5?x?1.6), the silicon compound particle contains a Li compound, at least a part of the silicon compound particle is coated with a carbon material, and an O-component fragment and a CH-component fragment are detected from the negative electrode active material particle in a measurement by TOF-SIMS, and a ratio of a peak intensity A of the O-component fragment to a peak intensity B of the CH-component fragment is 0.5?A/B?100. This provides a negative electrode active material for a non-aqueous electrolyte secondary battery capable of increasing battery capacity and improving the cycle characteristics and battery initial efficiency.

Abstract: A negative electrode active material contains a negative electrode active material particle which includes a silicon compound particle containing a silicon compound that contains oxygen. The silicon compound particle contains a Li compound, and at least part of Si constituting the silicon compound particle is present in at least one state selected from oxide of Si2+ to Si3+ containing no Li, and compound containing Li and Si2+ to Si3+. A negative electrode active material is capable of increasing battery capacity and improving cycle characteristics and initial charge-discharge characteristics when the negative electrode active material is used for a secondary battery. A mixed negative electrode active material contains the negative electrode active material. A method produces a negative electrode active material particle which enables production of the negative electrode active material particle to be contained in the negative electrode active material as described above.

Abstract: A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing a silicon compound (SiOx: 0.5?x?1.6) that contains Li, includes: making a silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof (here, the solution B contains one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent); and making the silicon compound contact with a solution C (here, the solution C contains one or more kinds selected from an alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent). Thereby, a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing a battery capacity and improving the cycle characteristics.

Abstract: A negative electrode active material contains a negative electrode active material particle; the negative electrode active material particle including a silicon compound particle containing a silicon compound (SiOx: 0.5?x?1.6), wherein the silicon compound particle contains a Li compound, and the negative electrode active material particle contains at least one kind of salt selected from salts of polyacrylic acid and salts of carboxymethyl cellulose, together with a metal salt containing at least one kind of metal selected from Mg and Al. This provides a negative electrode active material that is capable of stabilizing slurry that is produced in production of a negative electrode for a secondary battery, and improving initial charge-discharge characteristics and cycle performance when it is used as a negative electrode active material for a secondary battery.

Abstract: A negative electrode active material including a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle includes crystalline Li2SiO3 in at least part of the silicon compound particle. Among a peak intensity A derived from Li2SiO3, a peak intensity B derived from Si, a peak intensity C derived from Li2Si2O5, and a peak intensity D derived from SiO2 which are obtained from a 29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity A is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the following formula 1.

Abstract: A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing particles of lithium-containing silicon compound includes: preparing particles of silicon compound containing a silicon compound (SiOx: 0.5?x?1.6); obtaining particles of lithium-containing silicon compound by making the particle of silicon compound contact with a solution A that contains lithium and has an ether-based solvent as a solvent; and heating the particles of the lithium-containing silicon compound. A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing battery capacity of the negative electrode active material and capable of improving the first time efficiency and cycle characteristics.