Patents by Inventor Takashi Chikumoto
Takashi Chikumoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11699809Abstract: Provided is a sulfide-based solid electrolyte which is capable of suppressing the generation of hydrogen sulfide caused by reaction with moisture even when in contact with dry air in a dry room or the like, and capable of maintaining lithium ion conductivity. Proposed is a sulfide-based solid electrolyte for a lithium secondary battery, wherein the surface of a compound containing lithium, phosphorus, sulfur, and halogen, and having a cubic argyrodite-type crystal structure is coated with a compound containing lithium, phosphorus, and sulfur, and having a non-argyrodite-type crystal structure.Type: GrantFiled: May 16, 2017Date of Patent: July 11, 2023Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Hideo Uesugi, Norihiko Miyashita, Hitohiko Ide, Takahiro Ito, Takashi Chikumoto, Takashi Muranaka
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Patent number: 11688879Abstract: A sulfide-based solid electrolyte particle having a crystal phase of a cubic argyrodite-type crystal structure composed of Li, P, S and a halogen (Ha. The proposed sulfide-based solid electrolyte particle has a feature such that the ratio (ZHa2/ZHa1) of an element ratio ZHa2 of the halogen (Ha) at the position of 5 nm in depth from the particle surface to an element ratio ZHa1 of the halogen (Ha) at the position of 100 nm in depth from the particle surface is 0.5 or lower, as measured by XPS; and the ratio (ZO2/ZA2) of an element ratio ZO2 of oxygen to the total ZA2 of element ratios of phosphorus (P), sulfur (S), oxygen (O) and the halogen (Ha) at the position of 5 nm in depth from the particle surface is 0.5 or higher, as measured by XPS.Type: GrantFiled: March 12, 2019Date of Patent: June 27, 2023Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Tsukasa Takahashi, Takashi Chikumoto, Takahiro Ito
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Publication number: 20230096142Abstract: A sulfide solid electrolyte is provided having peak A at 2?=20.7°±0.5° in an X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuK?1 radiation. It is preferable that the sulfide solid electrolyte has peak B at 2?=25.4°±1.0° in the X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuK?1 radiation. It is also preferable that the value of the ratio of IA to IB, IA/IB, is more than 0 and 0.7 or less, where IA is the intensity of peak A and IB is the intensity of peak B. It is also preferable that the sulfide solid electrolyte has peak C at 2?=22.0°±0.5° in the X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuK?1 radiation.Type: ApplicationFiled: December 6, 2022Publication date: March 30, 2023Inventors: Tsukasa TAKAHASHI, Takashi CHIKUMOTO
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Publication number: 20220131183Abstract: A sulfide solid electrolyte is provided having peak A at 2?=20.7°±0.5° in an X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuK?1 radiation. It is preferable that the sulfide solid electrolyte has peak B at 2?=25.4°±1.0° in the X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuK?1 radiation. It is also preferable that the value of the ratio of IA to IB, IA/IB, is more than 0 and 0.7 or less, where IA is the intensity of peak A and IB is the intensity of peak B. It is also preferable that the sulfide solid electrolyte has peak C at 2?=22.0°±0.5° in the X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuK?1 radiation.Type: ApplicationFiled: September 3, 2020Publication date: April 28, 2022Inventors: Tsukasa TAKAHASHI, Takashi CHIKUMOTO
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Publication number: 20220109183Abstract: A sulfide solid electrolyte is provided having: diffraction peak A observed within a range of 2?=20.0° to 24.0°; and diffraction peak B observed within a range of 2?=24.4° to 26.4°, diffraction peak A and diffraction peak B being observed by performing X-ray diffraction measurement using CuK?1 radiation, and the ratio of IA to IB, IA/IB, being 2.0 or less, wherein IA is an intensity of diffraction peak A and IB is an intensity of diffraction peak B. Preferably, the sulfide solid electrolyte contains elemental lithium, elemental phosphorus, elemental sulfur, and an elemental halogen. It is also preferable that the sulfide solid electrolyte has an argyrodite-type crystal structure. It is also preferable that the sulfide solid electrolyte contains a lithium halide hydrate.Type: ApplicationFiled: September 3, 2020Publication date: April 7, 2022Inventors: Tsukasa TAKAHASHI, Takashi CHIKUMOTO, Yoichiro OGATA
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Publication number: 20220109182Abstract: A sulfide solid electrolyte is provided that can reduce the reaction resistance between an active material and the sulfide solid electrolyte. The sulfide solid electrolyte has a weight loss rate of 2.6% or more and 9.6% or less, the percentage of weight loss rate being measured by heating the sulfide solid from 25° C. to 400° C. at a heating rate of 10° C./min in thermogravimetry. It is preferable that this sulfide solid electrolyte contains elemental lithium (Li), elemental phosphorus (P), elemental sulfur (S), an elemental halogen (X), and elemental oxygen (O). Also, this sulfide solid electrolyte is favorably produced by mixing a sulfide solid electrolyte with a compound that contains water of crystallization.Type: ApplicationFiled: September 3, 2020Publication date: April 7, 2022Inventors: Tsukasa TAKAHASHI, Takashi CHIKUMOTO, Yoichiro OGATA
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Publication number: 20220059870Abstract: A sulfide-based solid electrolyte particle having a crystal phase of a cubic argyrodite-type crystal structure composed of Li, P, S and a halogen (Ha), wherein good contact between the sulfide-based solid electrolyte particles and positive or negative electrode active material particles is secured and improvements in the rate characteristic and the cycle characteristic are attained. The ratio (ZHa2/ZHa1) of an element ratio ZHa2 of the halogen (Ha) at the position of 5 nm in depth from the particle surface to an element ratio ZHa1 of the halogen (Ha) at the position of 100 nm in depth from the particle surface is 0.5 or lower and the ratio (ZO2/ZA2) of an element ratio ZO2 of oxygen to the total ZA2 of element ratios of P, S, O, and the halogen (Ha) at the position of 5 nm in depth from the particle surface is 0.5 or higher, as measured by XPS.Type: ApplicationFiled: November 8, 2021Publication date: February 24, 2022Inventors: Tsukasa Takahashi, Takashi Chikumoto, Takahiro Ito
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Publication number: 20220029196Abstract: As a novel sulfide compound having a low elastic modulus while retaining high ion conductivity, a sulfide compound for a solid electrolyte of a lithium secondary battery that includes a crystal phase of a cubic argyrodite type crystal structure, and is represented by the compositional formula: Li7?xPS6?xClyBrz, wherein x in the compositional formula satisfies x=y+z and 1.0<x?1.8, and a ratio, z/y, of the molar ratio of Br to the molar ratio of Cl is from 0.1 to 10.0.Type: ApplicationFiled: October 6, 2021Publication date: January 27, 2022Inventors: Tsukasa Takahashi, Takashi Chikumoto, Takahiro Ito, Hideo Uesugi
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Patent number: 11196083Abstract: As a novel sulfide compound having a low elastic modulus while retaining the high ion conductivity, a sulfide compound for a solid electrolyte of a lithium secondary battery that includes a crystal phase of a cubic argyrodite type crystal structure, and is represented by the compositional formula: Li7?xPS6?xClyBrz, wherein x in the compositional formula satisfies x=y+z and 1.0<x?1.8, and a ratio (z/y) of the molar ratio of Br to the molar ratio of Cl is from 0.1 to 10.0 is proposed.Type: GrantFiled: July 2, 2018Date of Patent: December 7, 2021Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Tsukasa Takahashi, Takashi Chikumoto, Takahiro Ito, Hideo Uesugi
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Patent number: 11108084Abstract: A novel sulfide solid electrolyte containing Li, P, S, and a halogen, which can be used as a solid electrolyte for a lithium secondary battery or the like, and is able to suppress the generation of a hydrogen sulfide gas even when exposed to moisture in the atmosphere. The sulfide solid electrolyte comprises a crystal phase or a compound having an argyrodite-type structure and containing Li, P, S, and a halogen; and a compound composed of Li, Cl, and Br and having a peak at each position of 2?=29.1°±0.5° and 33.7°±0.5° in an X-ray diffraction pattern.Type: GrantFiled: November 6, 2019Date of Patent: August 31, 2021Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Tsukasa Takahashi, Takahiro Ito, Takashi Chikumoto, Teruaki Yagi
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Publication number: 20210028486Abstract: A novel sulfide solid electrolyte containing Li, P, S, and a halogen, which can be used as a solid electrolyte for a lithium secondary battery or the like, and is able to suppress the generation of a hydrogen sulfide gas even when exposed to moisture in the atmosphere. The sulfide solid electrolyte comprises a crystal phase or a compound having an argyrodite-type structure and containing Li, P, S, and a halogen; and a compound composed of Li, Cl, and Br and having a peak at each position of 2?=29.1°±0.5° and 33.7°±0.5° in an X-ray diffraction pattern.Type: ApplicationFiled: November 6, 2019Publication date: January 28, 2021Inventors: Tsukasa Takahashi, Takahiro Ito, Takashi Chikumoto, Teruaki Yagi
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Publication number: 20210013542Abstract: A sulfide-based solid electrolyte particle having a crystal phase of a cubic argyrodite-type crystal structure composed of Li, P, S and a halogen (Ha. The proposed sulfide-based solid electrolyte particle has a feature such that the ratio (ZHa2/ZHa1) of an element ratio ZHa2 of the halogen (Ha) at the position of 5 nm in depth from the particle surface to an element ratio ZHa1 of the halogen (Ha) at the position of 100 nm in depth from the particle surface is 0.5 or lower, as measured by XPS; and the ratio (ZO2/ZA2) of an element ratio ZO2 of oxygen to the total ZA2 of element ratios of phosphorus (P), sulfur (S), oxygen (O) and the halogen (Ha) at the position of 5 nm in depth from the particle surface is 0.5 or higher, as measured by XPS.Type: ApplicationFiled: March 12, 2019Publication date: January 14, 2021Inventors: Tsukasa Takahashi, Takashi Chikumoto, Takahiro Ito
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Publication number: 20200127325Abstract: As a novel sulfide compound having a low elastic modulus while retaining the high ion conductivity, a sulfide compound for a solid electrolyte of a lithium secondary battery that includes a crystal phase of a cubic argyrodite type crystal structure, and is represented by the compositional formula: Li7?xPS6?xClyBrz, wherein x in the compositional formula satisfies x=y+z and 1.0<x?1.8, and a ratio (z/y) of the molar ratio of Br to the molar ratio of Cl is from 0.1 to 10.0 is proposed.Type: ApplicationFiled: July 2, 2018Publication date: April 23, 2020Inventors: Tsukasa Takahashi, Takashi Chikumoto, Takahiro Ito, Hideo Uesugi
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Publication number: 20190312304Abstract: Provided is a sulfide-based solid electrolyte which is capable of suppressing the generation of hydrogen sulfide caused by reaction with moisture even when in contact with dry air in a dry room or the like, and capable of maintaining lithium ion conductivity. Proposed is a sulfide-based solid electrolyte for a lithium secondary battery, wherein the surface of a compound containing lithium, phosphorus, sulfur, and halogen, and having a cubic argyrodite-type crystal structure is coated with a compound containing lithium, phosphorus, and sulfur, and having a non-argyrodite-type crystal structure.Type: ApplicationFiled: May 16, 2017Publication date: October 10, 2019Inventors: Hideo Uesugi, Norihiko Miyashita, Hitohiko Ide, Takahiro Ito, Takashi Chikumoto, Takashi Muranaka
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Patent number: 9899701Abstract: Proposed is a new sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte relating to a compound that has a cubic argyrodite type crystal structure and is represented by Li7-x-2yPS6-x-yClx, and having excellent water resistance and oxidation resistance. Proposed is a sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte containing a compound that has a cubic argyrodite type crystal structure and is represented by compositional formula (1): Li7-x-2yPS6-x-yClx, in which compositional formula, conditions: 0.8?x?1.7 and 0<y??0.25x+0.5 are satisfied.Type: GrantFiled: June 15, 2015Date of Patent: February 20, 2018Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Norihiko Miyashita, Takashi Chikumoto, Hideaki Matsushima, Kenji Matsuzaki
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Patent number: 9899702Abstract: Relating to a sulfide-based solid electrolyte compound for lithium ion batteries which has a cubic argyrodite-type crystal structure, to provide a compound which can suppress a generation amount of hydrogen sulfide when being left to stand in the air and which can maintain high conductivity even when being left to stand in dry air. Proposed is a sulfide-based solid electrolyte compound for lithium ion batteries containing a crystal phase of the cubic argyrodite-type crystal structure and represented by a composition formula (1): Li7?x+yPS6?xClx+y, wherein x and y in the composition formula (1) satisfy 0.05?y?0.9 and ?3.0x+1.8?y??3.0x+5.7.Type: GrantFiled: December 25, 2015Date of Patent: February 20, 2018Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Norihiko Miyashita, Takashi Chikumoto, Tatsuya Aoki, Hitohiko Ide, Kenji Matsuzaki
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Publication number: 20170352916Abstract: Relating to a sulfide-based solid electrolyte compound for lithium ion batteries which has a cubic argyrodite-type crystal structure, to provide a compound which can suppress a generation amount of hydrogen sulfide when being left to stand in the air and which can maintain high conductivity even when being left to stand in dry air. Proposed is a sulfide-based solid electrolyte compound for lithium ion batteries containing a crystal phase of the cubic argyrodite-type crystal structure and represented by a composition formula (1): Li7-x+yPS6-xClx+y, wherein x and y in the composition formula (1) satisfy 0.05?y?0.9 and ?3.0x+1.8?y??3.0x+5.7.Type: ApplicationFiled: December 25, 2015Publication date: December 7, 2017Inventors: Norihiko Miyashita, Takashi Chikumoto, Tatsuya Aoki, Hitohiko Ide, Kenji Matsuzaki
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Patent number: 9812734Abstract: Provided is a solid electrolyte with which charge/discharge efficiency and cycle characteristics can be increased by reducing the electron conductivity of a compound which has a cubic crystal structure belonging to a space group F-43m, and is represented by Compositional Formula: Li7-xPS6-xHax (Ha is Cl or Br). Proposed is a sulfide-based solid electrolyte for a lithium ion battery, which includes a compound having a cubic crystal structure belonging to a space group F-43m, and being represented by Compositional Formula: Li7-xPS6-xHax (Ha is Cl or Br), in which x in the above Compositional Formula is 0.2 to 1.8, and the value of the lightness L* thereof in the L*a*b* color system is 60.0 or more.Type: GrantFiled: June 23, 2014Date of Patent: November 7, 2017Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Norihiko Miyashita, Takashi Chikumoto, Hideaki Matsushima, Kenji Matsuzaki
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Publication number: 20170222257Abstract: Proposed is a new sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte relating to a compound that has a cubic argyrodite type crystal structure and is represented by Li7-x-2yPS6-x-yClx, and having excellent water resistance and oxidation resistance. Proposed is a sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte containing a compound that has a cubic argyrodite type crystal structure and is represented by compositional formula (1) : Li7-x-2yPS6-x-yClx, in which compositional formula, conditions: 0.8 ?x?1.7 and 0<y??0.25x+0.5 are satisfied.Type: ApplicationFiled: June 15, 2015Publication date: August 3, 2017Inventors: Norihiko Miyashita, Takashi Chikumoto, Hideaki Matsushima, Kenji Matsuzaki
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Publication number: 20160156064Abstract: Provided is a solid electrolyte with which charge/discharge efficiency and cycle characteristics can be increased by reducing the electron conductivity of a compound which has a cubic crystal structure belonging to a space group F-43m, and is represented by Compositional Formula: Li7-xPS6-xHax (Ha is Cl or Br). Proposed is a sulfide-based solid electrolyte for a lithium ion battery, which includes a compound having a cubic crystal structure belonging to a space group F-43m, and being represented by Compositional Formula: Li7-xPS6-xHax (Ha is Cl or Br), in which x in the above Compositional Formula is 0.2 to 1.8, and the value of the lightness L* thereof in the L*a*b* color system is 60.0 or more.Type: ApplicationFiled: June 23, 2014Publication date: June 2, 2016Inventors: Norihiko Miyashita, Takashi Chikumoto, Hideaki Matsushima, Kenji Matsuzaki