Patents by Inventor Takashi Hakuta

Takashi Hakuta has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8993647
    Abstract: [Objects] It is an object to provide a foam having a low specific gravity and a small compression set, more preferably a foam having a low specific gravity, a small compression set and uniform quality, a foaming composition, and applications of the foam. [Means for Solution] The foam is obtained by foaming an olefin polymer, wherein the foam has a specific gravity (d) in the range of 0.03 to 0.30, and a compression set (CS, %) and the specific gravity (d) satisfy the formula of CS??279×(d)+95. The foam is preferably obtained from a foaming composition that includes an ethylene polymer (A) including a specific ethylene/?-olefin copolymer (A1) and an ethylene/polar monomer copolymer (A2) in a specific mass ratio, and a specific ethylene/C3-20 ?-olefin/non-conjugated polyene copolymer (B).
    Type: Grant
    Filed: May 10, 2007
    Date of Patent: March 31, 2015
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takayuki Kajihara, Kiminori Noda, Masayoshi Yamaguchi, Takashi Hakuta
  • Patent number: 8945701
    Abstract: An ethylene resin composition is provided which has excellent properties including adhesion properties, electrically insulating properties, transparency, moldability and process stability and can be produced without requiring any cross-linking procedure if necessary to improve productivity; and others. The ethylene resin composition contains a modified product produced by modifying an ethylene polymer (A) that meets all of the requirements a) to e) mentioned below with an ethylenically unsaturated silane compound (B). a) The density is 900 to 940 kg/m3. b) The melting peak temperature is 90 to 125 ° C. as determined by DSC. c) The melt flow rate (MFR2) is 0.1 to 100 g/10 minutes as measured at 190 ° C. and a load of 2.16 kg in accordance with JIS K-6721. d) The Mw/Mn ratio is 1.2 to 3.5. e) The content of metal residues is 0.1 to 50 ppm.
    Type: Grant
    Filed: May 31, 2010
    Date of Patent: February 3, 2015
    Assignee: Mitsui Chemicals Tohcello, Inc.
    Inventors: Shigenobu Ikenaga, Takashi Hakuta, Kazuhiro Yarimizu, Hiroshi Mori, Takanobu Murofushi, Hirofumi Zenkoh, Jun Tokuhiro, Fumito Takeuchi
  • Publication number: 20120073631
    Abstract: The purpose of the present invention is to provide an ethylene resin composition which has excellent properties including adhesion properties, electrically insulating properties, transparency, moldability and process stability and can be produced without requiring any cross-linking procedure if necessary to improve productivity; and others. The ethylene resin composition contains a modified product produced by modifying an ethylene polymer (A) that meets all of the requirements a) to e) mentioned below with an ethylenically unsaturated silane compound (B). a) The density is 900 to 940 kg/m3. b) The melting peak temperature is 90 to 125 DEG C as determined by DSC. c) The melt flow rate (MFR2) is 0.1 to 100 g/10 minutes as measured at 190° C. and a load of 2.16 kg in accordance with JIS K-6721. d) The Mw/Mn ratio is 1.2 to 3.5. e) The content of metal residues is 0.1 to 50 ppm.
    Type: Application
    Filed: May 31, 2010
    Publication date: March 29, 2012
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Shigenobu Ikenaga, Takashi Hakuta, Kazuhiro Yarimizu, Hiroshi Mori, Takanobu Murofushi, Hirofumi Zenkoh, Jun Tokuhiro, Fumito Takeuchi
  • Publication number: 20120073655
    Abstract: A package for storing or transporting a solar cell sealing film includes: the solar cell sealing film containing a silane compound and/or a silane-modified resin; and a package bag packaging the solar cell sealing film. The absolute humidity inside the package is 1 to 15 g/m3. The package can store or transport the solar cell sealing film while adhesive force thereof with a substrate, solar cells, etc. is kept at a practicable level or higher. Furthermore, the package can reduce the breakage of the solar cells caused by an external shock while a solar cell module operates and the corrosion of electrodes caused by water etc. from the atmosphere.
    Type: Application
    Filed: June 4, 2010
    Publication date: March 29, 2012
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Mori, Takanobu Murofushi, Shigenobu Ikenaga, Takashi Hakuta, Hirofumi Zenkoh
  • Patent number: 8101254
    Abstract: The present invention provides a molded product exhibiting excellent various properties by improving compatibility of an ethylene/?-olefin/non-conjugated polyene copolymer with a polyolefin resin and a rubber composition for forming the molded product. The present invention further provides a molded product which comprises a rubber composition, is inhibited from fogging and tackiness and is excellent in mechanical strength and heat aging resistance. The rubber composition of the invention comprises an ethylene/?-olefin/non-conjugated polyene copolymer (A), and a polyolefin resin (B) having Mn of not less than 10,000 and/or an ethylene/?-olefin copolymer (C) having Mn of 2500 to 5000, and satisfies the following requirements: (1) a maximum value and a minimum value of an ethylene distribution parameter P of the component (A) have a relationship of Pmax/Pmin?1.
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: January 24, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yuji Noguchi, Takashi Hakuta, Hiroki Ebata, Kotaro Ichino, Shuichi Nonaka, Satoshi Hase, Kazuyoshi Kaneko, Akinori Takehara
  • Patent number: 7977443
    Abstract: The invention provides a copolymer rubber excellent in processability in kneading and processability in extrusion; rubber compositions containing the rubber; and crosslinked moldings of the compositions excellent in sealing properties and shape retention. A random copolymer rubber of ethylene (A), a C3-20 ?-olefin (B) and a nonconjugated polyene (C) which satisfies the following requirements (1) to (5): (1) the structural units (A) and (B) are contained at an (A)/(B) molar ratio of 40/60 to 95/5, (2) the structural unit (C) content is 0.01 to 5% by mole, (3) the limiting viscosity [?] is 1.0 to 5.0 dl/g as determined in decahydronaphthalene at 135°., (4) the Mw/Mn is 1 to 8, and (5) the P value is 0.46 to 1.00 as defined by formula (1): P=Ln(limiting viscosity [?])?5.0×105×?*(10) (1) (wherein Ln is a natural logarithm; and ?*(10) is viscosity (Pa·sec) as determined at 190° C. and at 10 rad/sec.
    Type: Grant
    Filed: August 9, 2006
    Date of Patent: July 12, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kotaro Ichino, Masao Kunizane, Takashi Hakuta
  • Patent number: 7741394
    Abstract: It is an object of the present invention to provide a rubber composition which has been improved in mechanical properties with maintaining excellent various properties and is favorably used for a fuel cell sealing member, a hard disc drive top cover gasket member and an electric wire connector sealing member. It is another object of the present invention to provide main bodies mounted with the above respective members obtained by the use of the rubber composition. The rubber composition of the invention comprises a specific ethylene/?-olefin/non-conjugated polyene copolymer in which the non-conjugated polyene is a norbornene-based compound, a specific SiH group-containing compound, and if necessary, an organopolysiloxane. Such a rubber composition of the invention is excellent in mechanical properties and can be particularly favorably used for a fuel cell sealing member, a hard disc drive top cover gasket, an electric wire connector sealing member, etc.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: June 22, 2010
    Assignees: Mitsui Chemicals, Inc., NOK Corporation
    Inventors: Takashi Hakuta, Kuniyoshi Kawasaki
  • Publication number: 20100144997
    Abstract: The invention provides a copolymer rubber excellent in processability in kneading and processability in extrusion; rubber compositions containing the rubber; and crosslinked moldings of the compositions excellent in sealing properties and shape retention. A random copolymer rubber of ethylene (A), a C3-20 ?-olefin (B) and a nonconjugated polyene (C) which satisfies the following requirements (1) to (5): (1) the structural units (A) and (B) are contained at an (A)/(B) molar ratio of 40/60 to 95/5, (2) the structural unit (C) content is 0.01 to 5% by mole, (3) the limiting viscosity [?] is 1.0 to 5.0 dl/g as determined in decalin at 135° C., (4) the Mw/Mn is 1 to 8, and (5) the P value is 0.46 to 1.00 as defined by formula (1): P=Ln(limiting viscosity [?]?5.0×105×?*(10) (1) (wherein Ln is a natural logarithm; and ?*(10) is a viscosity (Pa·sec) as determined at 190° C. and at 10 rad/sec).
    Type: Application
    Filed: August 9, 2006
    Publication date: June 10, 2010
    Inventors: Kotaro Ichino, Masao Kunizane, Takashi Hakuta
  • Publication number: 20090239014
    Abstract: The present invention provides a molded product exhibiting excellent various properties by improving compatibility of an ethylene/?-olefin/non-conjugated polyene copolymer with a polyolefin resin and a rubber composition for forming the molded product. The present invention further provides a molded product which comprises a rubber composition, is inhibited from fogging and tackiness and is excellent in mechanical strength and heat aging resistance. The rubber composition of the invention comprises an ethylene/?-olefin/non-conjugated polyene copolymer (A), and a polyolefin resin (B) having Mn of not less than 10,000 and/or an ethylene/?-olefin copolymer (C) having Mn of 2500 to 5000, and satisfies the following requirements: (1) a maximum value and a minimum value of an ethylene distribution parameter P of the component (A) have a relationship of Pmax/Pmin?1.
    Type: Application
    Filed: December 4, 2008
    Publication date: September 24, 2009
    Inventors: Yuji Noguchi, Takashi Hakuta, Hiroki Ebata, Kotaro Ichino, Shuichi Nonaka, Satoshi Hase, Kazuyoshi Kaneko, Akinori Takehara
  • Publication number: 20090234073
    Abstract: An ?-olefin/non-conjugated cyclic polyene copolymer (A) includes structural units (I) derived from an ?-olefin and structural units (H) derived from a vinyl group-containing cyclic olefin. The copolymer has a molecular weight distribution (Mw/Mn) of not more than 2.7 and is amorphous or low crystalline with a crystalline heat of fusion (?H) of less than 90 kJ/kg. The copolymer is efficiently produced using a specific transition metal catalyst that has a ligand with a phenoxyimine skeleton. The copolymer of the invention has a narrower molecular weight distribution and a higher content of vinyl groups as compared with existing copolymers. The copolymer can then give crosslinked products having excellent tensile properties. The copolymer is also used as a plasticizer for polymers such as rubbers, and provides excellent processability and superior mechanical strength and rubber elasticity of crosslinked products.
    Type: Application
    Filed: May 10, 2006
    Publication date: September 17, 2009
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Shigekazu Matsui, Sadahiko Matsuura, Haruyuki Makio, Seiichi Ishii, Hiroshi Terao, Hidetatsu Murakami, Takashi Hakuta, Terunori Fujita
  • Publication number: 20090126234
    Abstract: [Objects] It is an object to provide a foam having a low specific gravity and a small compression set, more preferably a foam having a low specific gravity, a small compression set and uniform quality, a foaming composition, and applications of the foam. [Means for Solution] The foam is obtained by foaming an olefin polymer, wherein the foam has a specific gravity (d) in the range of 0.03 to 0.30, and a compression set (CS, %) and the specific gravity (d) satisfy the formula of CS??279×(d)+95. The foam is preferably obtained from a foaming composition that includes an ethylene polymer (A) including a specific ethylene/?-olefin copolymer (A1) and an ethylene/polar monomer copolymer (A2) in a specific mass ratio, and a specific ethylene/C3-20 ?-olefin/non-conjugated polyene copolymer (B).
    Type: Application
    Filed: May 10, 2007
    Publication date: May 21, 2009
    Inventors: Takayuki Kajihara, Kiminori Noda, Masayoshi Yamaguchi, Takashi Hakuta
  • Publication number: 20090118404
    Abstract: It is an object of the present invention to provide a rubber composition which has been improved in mechanical properties with maintaining excellent various properties and is favorably used for a fuel cell sealing member, a hard disc drive top cover gasket member and an electric wire connector sealing member. It is another object of the present invention to provide main bodies mounted with the above respective members obtained by the use of the rubber composition. The rubber composition of the invention comprises a specific ethylene/?-olefin/non-conjugated polyene copolymer in which the non-conjugated polyene is a norbornene-based compound, a specific SiH group-containing compound, and if necessary, an organopolysiloxane. Such a rubber composition of the invention is excellent in mechanical properties and can be particularly favorably used for a fuel cell sealing member, a hard disc drive top cover gasket, an electric wire connector sealing member, etc.
    Type: Application
    Filed: June 28, 2006
    Publication date: May 7, 2009
    Applicants: MITSUI CHEMICALS, INC., NOK CORPORATION
    Inventors: Takashi Hakuta, Kuniyoshi Kawasaki
  • Patent number: 7208548
    Abstract: The crosslinkable rubber composition of the invention is crosslinkable by hot air, and a hot-air crosslinked rubber sheet thereof has no scratch on the surface in a hardness test using a pencil of HB and has a compression set of not more than 70% after a heat treatment at 150° C. for 22 hours. The rubber composition comprises an ethylene/?-olefin/non-conjugated polyene random copolymer rubber comprising a specific vinyl end group-containing norbornene compound, a SiH group-containing compound having at least two SiH groups in one molecule, and if necessary, an addition reaction catalyst comprising a platinum group element and a reaction inhibitor.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: April 24, 2007
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takashi Hakuta, Masaaki Kawasaki, Yoshiharu Kikuchi, Tsutomu Nakamura, Satao Hirabayashi, Takeo Yoshida
  • Patent number: 7176269
    Abstract: The curable composition of the present invention contains (A1) a silyl-containing ethylene/?-olefin/non-conjugated polyene random copolymer rubber which has a structural unit derived from a norbornene compound as the non-conjugated polyene with at least one specific vinyl group at the terminal and contains a specific hydrolyzable silyl group, and (B) a compound, other than the rubber (A1), having a hydroxyl group and/or a hydrolyzable group, e.g., (B1) a compound having a silanol group and/or a compound which can react with moisture to form a compound having a silanol group in the molecule. This compound improves elongation of the cured product and residual surface tackiness, and, at the same time, is high in curing speed and capable of giving the cured product of high resistance to weather. It is suitable for, e.g., adhesives, tackifiers, paints, sealants, waterproof materials, spray materials, shaping materials and casting rubber materials.
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: February 13, 2007
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takashi Hakuta, Masaaki Kawasaki, Yoshiharu Kikuchi, Mitsunao Arino, Mitsuko Nagai, Hiroaki Sakaguchi, Masaki Sugawara, Masao Kishi, Kaoru Ueno, Takashi Abe, Michio Sekine
  • Publication number: 20070015893
    Abstract: The curable composition of the present invention contains (A1) a silyl-containing ethylene/?-olefin/non-conjugated polyene random copolymer rubber which has a structural unit derived from a norbornene compound as the non-conjugated polyene with at least one specific vinyl group at the terminal and contains a specific hydrolyzable silyl group, and (B) a compound, other than the rubber (A1), having a hydroxyl group and/or a hydrolyzable group, e.g., (B1) a compound having a silanol group and/or a compound which can react with moisture to form a compound having a silanol group in the molecule. This compound improves elongation of the cured product and residual surface tackiness, and, at the same time, is high in curing speed and capable of giving the cured product of high resistance to weather. It is suitable for, e.g., adhesives, tackifiers, paints, sealants, waterproof materials, spray materials, shaping materials and casting rubber materials.
    Type: Application
    Filed: September 5, 2006
    Publication date: January 18, 2007
    Inventors: Takashi Hakuta, Masaaki Kawasaki, Yoshiharu Kikuchi, Mitsunao Arino, Mitsuko Nagai, Hiroaki Sakaguchi, Masaki Sugawara, Masao Kishi, Kaoru Ueno, Takashi Abe, Michio Sekine
  • Publication number: 20060142437
    Abstract: A pellet comprising 100 parts by weight of an ethylene/?-olefin/non-conjugated polyene copolymer (A) containing a constitutional unit derived from non-conjugated polyene represented by a specific Formula, 1 to 150 parts by weight of a plasticizer (B) relative to 100 parts by weight of the above (A), and 0 to 30 parts by weight of a thermoplastic resin (C) relative to 100 parts by weight of the above (A), is obtained, and a vulcanized rubber or a thermoplastic elastomer which does not cause blocking and has excellent crosslinking reactivity and thus excellent properties can be prepared therefrom. According to a process for preparation of a thermoplastic elastomer using the above-mentioned pellet, a thermoplastic elastomer having excellent compression set or dispersibility can be economically and efficiently prepared. In particular, since it can be prepared continuously using a twin screw extruder, the process is excellent from an industrial viewpoint.
    Type: Application
    Filed: March 12, 2004
    Publication date: June 29, 2006
    Inventors: Takashi Hakuta, Yoshiharu Kikuchi, Masaaki Kawasaki
  • Patent number: 7015292
    Abstract: A silicon-containing olefin copolymer is provided which comprises (a) a constituent unit derived from —CH2—CH2— such as ethylene, (b) a constituent unit derived from —CH2—CHR— where R is a hydrocarbon group of 1 to 18 carbon atoms, and (c) a constituent unit containing a specific silicon-containing group. A silicon-containing olefin copolymer is also provided which is obtainable by co-polymerizing ethylene, an a-olefin of 3 to 20 carbon atoms and a specific silicon-containing ethylene monomer.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: March 21, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Keiji Okada, Hidetatsu Murakami, Takashi Hakuta, Masaaki Kawasaki
  • Publication number: 20050154132
    Abstract: The crosslinkable rubber composition of the invention is crosslinkable by hot air, and a hot-air crosslinked rubber sheet thereof has no scratch on the surface in a hardness test using a pencil of HB and has a compression set of not more than 70% after a heat treatment at 150° C. for 22 hours. The rubber composition comprises an ethylene/?-olefin/non-conjugated polyene random copolymer rubber comprising a specific vinyl end group-containing norbornene compound, a SiH group-containing compound having at least two SiH groups in one molecule, and if necessary, an addition reaction catalyst comprising a platinum group element and a reaction inhibitor. The automobile weatherstrip, hose, rubber vibration insulator, belt, sealing material, expanded product, covered electric wire, electric wire joint, electric insulating part and household rubber product according to the invention comprise the above-mentioned rubber composition.
    Type: Application
    Filed: December 3, 2004
    Publication date: July 14, 2005
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Takashi Hakuta, Masaaki Kawasaki, Yoshiharu Kikuchi, Tsutomu Nakamura, Satao Hirabayashi, Takeo Yoshida
  • Patent number: 6864315
    Abstract: The crosslinkable rubber composition of the invention is crosslinkable by hot air, and a hot-air crosslinked rubber sheet thereof has no scratch on the surface in a hardness test using a pencil of HB and has a compression set of not more than 70% after a heat treatment at 150° C. for 22 hours. The rubber composition comprises an ethylene/?-olefin/non-conjugated polyene random copolymer rubber comprising a specific vinyl end group-containing norbornene compound, a SiH group-containing compound having at least two SiH groups in one molecule, and if necessary, an addition reaction catalyst comprising a platinum group element and a reaction inhibitor. The automobile weatherstrip, hose, rubber vibration insulator, belt, sealing material, expanded product, covered electric wire, electric wire joint, electric insulating part and household rubber product according to the invention comprise the above-mentioned rubber composition.
    Type: Grant
    Filed: March 14, 2000
    Date of Patent: March 8, 2005
    Assignees: Mitsui Chemicals, Inc., Shin-Etsu Chemical Co., Ltd.
    Inventors: Takashi Hakuta, Masaaki Kawasaki, Yoshiharu Kikuchi, Hidenari Nakahama, Taku Koda, Hiroshi Kameda, Shuichi Nonaka, Mikio Hosoya, Yuji Ishii, Mitsunao Arino, Tsutomu Nakamura, Satao Hirabayashi, Takeo Yoshida
  • Publication number: 20050038214
    Abstract: The first silicon-containing olefin copolymer of the present invention comprises (a) a constituent unit derived from —CH2—CH2—, (b) a constituent unit derived from —CH2—CHR— [R is a hydrocarbon group of 1 to 18 carbon atoms], and (c) a constituent unit containing a specific silicon-containing group, and has a molar ratio [(a)/(b)] of the constituent units (a) to the constituent units (b) of from 99/1 to 30/70, a content of the constituent unit (c) of from 0.1 to 10 mol % based on 100 mol % of the total amounts of the constituent units (a), (b) and (c), and a branching index of not less than 0.70. The second silicon-containing olefin copolymer of the present invention is obtainable by copolymerizing ethylene, an ?-olefin of 3 to 20 carbon atoms and a specific silicon-containing ethylene monomer, and has a molar ratio of ethylene to ?-olefin of from 99/1 to 30/70, an intrinsic viscosity, as measured in decalin at 135° C., of from 0.1 to 10 dl/g, a content of the ethylene monomer of from 0.
    Type: Application
    Filed: December 26, 2002
    Publication date: February 17, 2005
    Inventors: Keiji Okada, Hidetatsu Murakami, Takashi Hakuta, Masaaki Kawasaki