Abstract: A method for separating and purifying 2-chloro-3-trifluoromethylpyridine useful as an intermediate for medicines, agrochemicals, and the like is provided. The method includes: 1) in the process of producing chloro ?-trifluoromethylpyridine compounds by allowing a ?-methylpyridine compound to react with chlorine and hydrogen fluoride in a reaction apparatus, allowing a ?-trifluoromethylpyridine compound to react with chlorine in a reaction apparatus, or allowing a chloro ?-trichloromethylpyridine compound to react with hydrogen fluoride in a reaction apparatus, 2) fractionating a liquid mixture containing chloro ?-trifluoromethylpyridine compounds from the reaction apparatus, and 3) separating and purifying 2-chloro-3-trifluoromethylpyridine from the liquid mixture.

Abstract: A method for separating and purifying 2-chloro-3-trifluoromethylpyridine useful as an intermediate for medicines, agrochemicals, and the like is provided. The method includes: 1) in the process of producing chloro ?-trifluoromethylpyridine compounds by allowing a ?-methylpyridine compound to react with chlorine and hydrogen fluoride in a reaction apparatus, allowing a ?-trifluoromethylpyridine compound to react with chlorine in a reaction apparatus, or allowing a chloro ?-trichloromethylpyridine compound to react with hydrogen fluoride in a reaction apparatus, 2) fractionating a liquid mixture containing chloro ?-trifluoromethylpyridine compounds from the reaction apparatus, and 3) separating and purifying 2-chloro-3-trifluoromethylpyridine from the liquid mixture.

Abstract: A webbing take-up device is obtained capable of securing sealing properties to gas generated by actuation of a gas generator. A switching mechanism of a webbing take-up device is equipped with a body, a gas generator, a piston that is actuated on receipt of pressure of gas generated by the gas generator, and a cylinder that internally houses the piston. A sheet and a support plate are attached to the body. Crushable ribs are provided to the sheet. The crushable ribs press the cylinder through a general portion of the sheet by attaching the sheet and the support plate to the body.

Abstract: In a webbing winding device, even when a piston moves toward the other side in a movement direction due to a reaction when the piston moves to a maximum movement position, an engagement surface of a hook portion comes into contact with a subject engagement surface of a subject engagement portion, so that the movement of the piston toward the other side in the movement direction is restricted. Accordingly, the piston is prevented from returning to a standby position, and a pawl is prevented from returning to a lock position. For this reason, a state where a rotation of a locking ring in the pull-out direction is maintained. Accordingly, after the piston moves from the standby position to the maximum movement position, the piston is prevented from returning to the standby position, and the force limiter load is prevented from being changed.

Abstract: A webbing take-up device is obtained capable of suppressing generating of extraordinary noise caused by vibration accompanying vehicle travelling. A switching mechanism of a webbing take-up device is equipped with a lock ring and a body that is formed with a recessed portion that houses the lock ring. The switching mechanism is also equipped with a sheet that is attached to the body so as to cover the recessed portion housing the lock ring. Protruding portions are formed at the sheet. The protruding portions make contact with the lock ring housed in the recessed portion of the body. As a result the lock ring is restricted from vibrating inside the recessed portion.

Abstract: To provide a method for producing pyrimidine compound useful as an intermediate for agricultural chemicals or pharmaceuticals, which is simple in operation, presents high yield and produces only a small amount of by-products. The method comprises reacting a compound represented by the formula (I) with a compound represented by the formula (II) in the presence of a pyridine compound to produce a compound represented by the formula (III), a compound represented by the formula (IV) or their mixture.

Abstract: A webbing take-up device enabling a reduction in size of an overload release mechanism and easy adjustment of an operation torque of the overload release mechanism is provided. In the overload release mechanism of this webbing take-up device, rotary force of a large diameter gear is transmitted to a small diameter gear via plural annular friction springs. The friction springs are disposed between an inner periphery face of a main body portion of the large diameter gear and a tubular portion of the small diameter gear, side by side along an axial direction of the two gears. Consequently, a radial direction enlargement of the large diameter gear and small diameter gear due to space for disposing the friction springs may be restrained. Moreover, the operation torque of the overload release mechanism may be adjusted stepwise by changing the number of the friction springs to be used, in accordance with requirements.

Abstract: A method for producing 3-methyl-2-thiophenecarboxylic acid is provided. A method for producing 3-methyl-2-thiophenecarboxylic acid, which comprises reacting a compound represented by the formula (I): (wherein X is a chlorine atom or a bromine atom) with magnesium in the presence of an alkyl halide to give a Grignard reagent represented by the formula (II): (wherein X is the same as defined above), reacting the Grignard reagent of the formula (II) with carbon dioxide, and acidifying the reaction product.

Abstract: Because fluazinam is excellent as an active ingredient of pesticides and highly useful, it is desired to produce it efficiently in a proper form with simple operations at low cost in an environmentally friendly manner. The desired product is obtained in good yields with simple operations by using industrially advantageous reaction systems by a process comprising (1) a step of reacting ACTF and DCDNBTF in the presence of an alkali component, a solvent selected from the group consisting of ketones, nitriles, ethers and esters and a sufficient amount of water to substantially dissolve the alkali component, (2) a step of neutralizing or acidifying the reaction mixture with an acid and (3) a step of removing the solvent by distillation from the mixture containing fluazinam as the reaction product and the reaction solvent to precipitate crystals the product.

Abstract: In a webbing winding device, even when a piston moves toward the other side in a movement direction due to a reaction when the piston moves to a maximum movement position, an engagement surface of a hook portion comes into contact with a subject engagement surface of a subject engagement portion, so that the movement of the piston toward the other side in the movement direction is restricted. Accordingly, the piston is prevented from returning to a standby position, and a pawl is prevented from returning to a lock position. For this reason, a state where a rotation of a locking ring in the pull-out direction is maintained. Accordingly, after the piston moves from the standby position to the maximum movement position, the piston is prevented from returning to the standby position, and the force limiter load is prevented from being changed.

Abstract: A webbing take-up device includes a speed-reduction mechanism that reduces rotation speed of a motor to transmit rotation force to a take-up shaft. An overload release mechanism is disposed at a middle position of the speed-reduction mechanism. The overload release mechanism includes a large-diameter gear rotating with the rotation speed of the motor being reduced and the rotation force being transmitted, a spring member mounted to the large-diameter gear, and a small-diameter gear provided to rotate relatively to the large-diameter gear, rotating the take-up shaft when the rotation speed thereof is reduced and the rotation force is transmitted to the take-up shaft, engaging with the spring member to become a state where relative rotation with respect to the large-diameter gear is stopped, and slides with the spring member when the rotation force acts between the large-diameter gear to become a state where relative rotation to the large-diameter gear is allowed.

Abstract: A method for producing 3-methyl-2-thiophenecarboxylic acid is provided. A method for producing 3-methyl-2-thiophenecarboxylic acid, which comprises reacting a compound represented by the formula (I): (wherein X is a chlorine atom or a bromine atom) with magnesium in the presence of an alkyl halide to give a Grignard reagent represented by the formula (II): (wherein X is the same as defined above), reacting the Grignard reagent of the formula (II) with carbon dioxide, and acidifying the reaction product.

Abstract: A webbing take-up device enabling a reduction in size of an overload release mechanism and easy adjustment of an operation torque of the overload release mechanism is provided. In the overload release mechanism of this webbing take-up device, rotary force of a large diameter gear is transmitted to a small diameter gear via plural annular friction springs. The friction springs are disposed between an inner periphery face of a main body portion of the large diameter gear and a tubular portion of the small diameter gear, side by side along an axial direction of the two gears. Consequently, a radial direction enlargement of the large diameter gear and small diameter gear due to space for disposing the friction springs may be restrained. Moreover, the operation torque of the overload release mechanism may be adjusted stepwise by changing the number of the friction springs to be used, in accordance with requirements.

Abstract: To provide a method for producing pyrimidine compound useful as an intermediate for agricultural chemicals or pharmaceuticals, which is simple in operation, presents high yield and produces only a small amount of by-products. The method comprises reacting a compound represented by the formula (I) with a compound represented by the formula (II) in the presence of a pyridine compound to produce a compound represented by the formula (III), a compound represented by the formula (IV) or their mixture.

Abstract: A webbing take-up device includes a speed-reduction mechanism that reduces rotation speed of a motor to transmit rotation force to a take-up shaft. An overload release mechanism is disposed at a middle position of the speed-reduction mechanism. The overload release mechanism includes a large-diameter gear rotating with the rotation speed of the motor being reduced and the rotation force being transmitted, a spring member mounted to the large-diameter gear, and a small-diameter gear provided to rotate relatively to the large-diameter gear, rotating the take-up shaft when the rotation speed thereof is reduced and the rotation force is transmitted to the take-up shaft, engaging with the spring member to become a state where relative rotation with respect to the large-diameter gear is stopped, and slides with the spring member when the rotation force acts between the large-diameter gear to become a state where relative rotation to the large-diameter gear is allowed.

Abstract: Because fluazinam is excellent as an active ingredient of pesticides and highly useful, it is desired to produce it efficiently in a proper form with simple operations at low cost in an environmentally friendly manner. The desired product is obtained in good yields with simple operations by using industrially advantageous reaction systems by a process comprising (1) a step of reacting ACTF and DCDNBTF in the presence of an alkali component, a solvent selected from the group consisting of ketones, nitriles, ethers and esters and a sufficient amount of water to substantially dissolve the alkali component, (2) a step of neutralizing or acidifying the reaction mixture with an acid and (3) a step of removing the solvent by distillation from the mixture containing fluazinam as the reaction product and the reaction solvent to precipitate crystals the product.

Abstract: A process for producing 2-phenylacetophenone derivatives represented by the formula (I): (wherein X is an alkyl group or a haloalkyl group, and Y is a hydrogen atom, a halogen atom or an alkyl group which may be substituted), which comprises reacting a compound represented by the formula (II): (wherein X and Y are as defined above, and R is a hydrogen atom or an alkyl group) with an acid.

Abstract: A process for producing 2-phenylacetophenone derivatives represented by the formula (I): 1

Abstract: A method for producing 2-methylspiro(1,3-oxathiolane-5,3')quinuclidine, which comprises reacting 3-hydroxy-3-mercaptomethylquinuclidine or a salt thereof and a carbonyl compound in the presence of a catalyst made of at least one member selected from the group consisting of tin halides, oxyacids of phosphorus, phosphorus oxyhalides and organic sulfonic acids, to produce cis-form 2-methylspiro(1,3-oxathiolane-5,3')quinuclidine or a salt thereof.