Abstract: Provided are a hydrogen storage material containing a TiFe-based alloy, a hydrogen storage container including the hydrogen storage material, and a hydrogen supply apparatus including the hydrogen storage container. The hydrogen storage material contains an alloy of an elemental composition represented by Formula (1), in which, in 1000× magnified COMP image of cross section of the alloy obtained by EPMA, 25 or more and 3000 or less pieces of a phase in which R is enriched and that have phase sizes of 0.1 ?m or more and 10 ?m or less are present in a field of view of 85 ?m×120 ?m of the COMP image, and an R-enriched phase area ratio of total area SR ?m2 of pieces of the phase present in the field of view to area S ?m2 of field of view is 0.3% or more and 6.0% or less: Ti(1?a?b)RaM1bFecMndM2eCf??(1).

Abstract: A low-cost hydrogen storage material has hydrogen absorption (storage) and desorption properties suitable for hydrogen storage. A hydrogen storage container including the hydrogen storage material and a hydrogen supply apparatus including the hydrogen storage container are disclosed. The hydrogen storage material includes an alloy having a specific elemental composition represented by Formula (1), in which, in a 1000×COMP image of a cross section of the alloy obtained by EPMA, a plurality of phases enriched with R are present, the phases having phase diameters of 0.1 ?m or more and 10 ?m or less, and 100 or more sets of combinations of two phases in the phases are present in a visual field of 85 ?m×120 ?m in the COMP image, the shortest separation distance between the two phases being 0.5 to 20 ?m. [Chem.

Abstract: Provided are hydrogen storage materials having hydrogen absorption (storage) desorption properties suitable for hydrogen storage in a temperature range of 0° C. or lower. Also provided are a hydrogen storage container containing the hydrogen storage materials, and a hydrogen supply apparatus including the hydrogen storage container. The hydrogen storage materials have an alloy with an elemental composition represented by Formula (1): in Formula (1), M is at least one kind selected from Mn, Co, and Al and essentially contains Mn, a satisfies 0.00?a?0.62, b satisfies 0.20?b?0.57, c satisfies 0.17?c?0.60, d satisfies 4.50?d?5.20, e satisfies 0.15?e?0.70, a+b+c=1, c+e satisfies 0.55?c+e?1.20, and d+e satisfies 5.13?d+e?5.40.

Abstract: Hydrogen storage materials being inexpensive and having hydrogen absorption (storage) and desorption properties suitable for hydrogen storage are provided. The hydrogen storage materials have alloys with an elemental composition of Formula (1), a hydrogen storage container containing the hydrogen storage material, and a hydrogen supply apparatus including the hydrogen storage container: LaaCebSmcNidMe ??(1) wherein M is Mn or both of Mn and Co, a satisfies 0.60?a?0.90, b satisfies 0?b?0.30, c satisfies 0.05?c?0.25, d satisfies 4.75?d?5.20, e satisfies 0.05?e?0.40, a+b+c=1, and d+e satisfies 5.10?d+e?5.35.

Abstract: A low-cost hydrogen storage material has hydrogen absorption (storage) and desorption properties suitable for hydrogen storage. A hydrogen storage container including the hydrogen storage material and a hydrogen supply apparatus including the hydrogen storage container are disclosed. The hydrogen storage material includes an alloy having a specific elemental composition represented by Formula (1), in which, in a 1000×COMP image of a cross section of the alloy obtained by EPMA, a plurality of phases enriched with R are present, the phases having phase diameters of 0.1 ?m or more and 10 ?m or less, and 100 or more sets of combinations of two phases in the phases are present in a visual field of 85 ?m×120 ?m in the COMP image, the shortest separation distance between the two phases being 0.5 to 20 ?m. [Chem.

Abstract: Hydrogen storage alloy powder, an anode, and a nickel-hydrogen rechargeable battery are provided, which are excellent in low-temperature characteristics and both in initial activity and cycle life at the same time, which properties are trading-off in conventional nickel-hydrogen rechargeable batteries. The alloy powder has a composition represented by formula (1) R1-aMgaNibAlcMd (R: rare earth elements including Sc and Y, or the like; 0.005?a?0.40, 3.00?b?4.50, 0?c?0.50, 0?d?1.00, 3.00?b+c+d?4.50), and has an arithmetical mean roughness (Ra) of the powder particle outer surface of not less than 2 ?m, or a crushing strength of not higher than 35,000 gf/mm2.

Abstract: Provided are hydrogen storage alloy powder capable of providing a nickel-hydrogen rechargeable battery with simultaneous excellence in initial activity, discharge capacity, and cycle characteristics, which are otherwise in a trade-off relationship, an anode for a nickel-hydrogen rechargeable battery as well as a nickel-hydrogen rechargeable battery employing the same. The hydrogen storage alloy has a particular composition represented by formula (1), R1-aMgaNibAlcMd, and has at its outermost surface a Mg-rich/Ni-poor region having a composition with a Mg molar ratio higher than that in formula (1) and a Ni molar ratio lower than that in formula (1), and has inside a Mg/Ni-containing region having a composition with a Mg molar ratio lower than and a Ni molar ratio higher than those in the Mg-rich/Ni-poor region.

Abstract: A safe and industrially advantageous production method is disclosed for producing a rare earth-Mg—Ni based hydrogen storage alloy which realizes production of a nickel-hydrogen rechargeable battery having excellent cycle characteristics and a large capacity. The method is for producing a rare earth-Mg—Ni based hydrogen storage alloy including element A, Mg, and element B, wherein element A is composed of at least one element R selected from rare earth elements including Sc and Y, and optionally at least one element selected from Zr, Hf, and Ca, and element B is composed of Ni and optionally at least one element selected from elements other than element A and Mg. The method includes first step of mixing an alloy consisting of elements A and B and Mg metal and/or a Mg-containing alloy having a melting point not higher than the melting point of Mg metal, and second step of heat-treating a mixture obtained from first step for 0.5 to 240 hours at a temperature 5 to 250° C.

Abstract: A hydrogen storage alloy wherein elution of Co, Mn, Al, and the like elements into an alkaline electrolyte is inhibited, an anode for a nickel-hydrogen rechargeable battery employing the alloy, and a nickel-hydrogen rechargeable battery having the anode.

Abstract: Hydrogen storage alloy powder, an anode, and a nickel-hydrogen rechargeable battery are provided, which are excellent in low-temperature characteristics and both in initial activity and cycle life at the same time, which properties are trading-off in conventional nickel-hydrogen rechargeable batteries. The alloy powder has a composition represented by formula (1) R1-aMgaNibAlcMd (R: rare earth elements including Sc and Y, or the like; 0.005?a?0.40, 3.00?b?4.50, 0?c?0.50, 0?d?1.00, 3.00?b+c+d?4.50), and has an arithmetical mean roughness (Ra) of the powder particle outer surface of not less than 2 ?m, or a crushing strength of not higher than 35,000 gf/mm2.

Abstract: Provided are hydrogen storage alloy powder capable of providing a nickel-hydrogen rechargeable battery with simultaneous excellence in initial activity, discharge capacity, and cycle characteristics, which are otherwise in a trade-off relationship, an anode for a nickel-hydrogen rechargeable battery as well as a nickel-hydrogen rechargeable battery employing the same. The hydrogen storage alloy has a particular composition represented by formula (1), R1-aMgaNibAlcMd, and has at its outermost surface a Mg-rich/Ni-poor region having a composition with a Mg molar ratio higher than that in formula (1) and a Ni molar ratio lower than that in formula (1), and has inside a Mg/Ni-containing region having a composition with a Mg molar ratio lower than and a Ni molar ratio higher than those in the Mg-rich/Ni-poor region.

Abstract: A hydrogen storage alloy wherein elution of Co, Mn, Al, and the like elements into an alkaline electrolyte is inhibited, an anode for a nickel-hydrogen rechargeable battery employing the alloy, and a nickel-hydrogen rechargeable battery having the anode.

Abstract: A safe and industrially advantageous production method is disclosed for producing a rare earth-Mg—Ni based hydrogen storage alloy which realizes production of a nickel-hydrogen rechargeable battery having excellent cycle characteristics and a large capacity. The method is for producing a rare earth-Mg—Ni based hydrogen storage alloy including element A, Mg, and element B, wherein element A is composed of at least one element R selected from rare earth elements including Sc and Y, and optionally at least one element selected from Zr, Hf, and Ca, and element B is composed of Ni and optionally at least one element selected from elements other than element A and Mg. The method includes first step of mixing an alloy consisting of elements A and B and Mg metal and/or a Mg-containing alloy having a melting point not higher than the melting point of Mg metal, and second step of heat-treating a mixture obtained from first step for 0.5 to 240 hours at a temperature 5 to 250° C.