Abstract: Process for making a partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1+1TM1?xO2, wherein TM comprises Ni and, optionally, at least one transition metal selected from Co and Mn, and, optionally, at least one element selected from Al, Mg, Ba and B, transition metals other than Ni, Co, and Mn, and x is in the range of from ?0.05 to 0.2, wherein at least 50 mole-% of the transition metal of TM is Ni, (b) treating said electrode active material with an aqueous formulation containing an inorganic aluminum compound dispersed or slurried in water, (c) separating off the water, (d) thermal treatment of the material obtained from step (c).

Abstract: A positive electrode active material comprises a Li-transition metal-layered oxide represented by the formula: Lia(NibCocAldMee)O2 (in which Me=Mn, Mg, Ti, Ru, Zr, Nb, Mo, W; 1.00?a?1.15; 0.25<b<1; 0<c?0.30; 0?d?0.05; 0?e?0.40), and is constituted of secondary particles formed by aggregation of primary particles. As to a compositional ratio of Li which is derived from unreacted substances or decomposed products in the secondary particles, a variation coefficient (Standard deviation value/Average value) of a Li-compositional ratio: Li/M (M=Ni+Co+Al+Me) is 30% or less. The positive electrode active material hardly deteriorates even if repeatedly charged/discharged, and enables stable charge/discharge, and then a non-aqueous electrolyte secondary battery is enabled to have an excellent output property and a long lifetime.

Abstract: The present invention relates to lithium composite oxide particles which can be produced by mixing nickel-cobalt-manganese-based compound particles, a zirconium raw material and a lithium raw material with each other and then calcining the resulting mixture, and comprise a Zr compound that is allowed to be present on a surface thereof, in which the Zr compound is represented by the chemical formula: Lix(Zr1-yAy)Oz wherein x, y and z are 2.0?x?8.0; 0?y?1.0; and 2.0?z?6.0, respectively, and a content of Zr in the lithium composite oxide particles is 0.05 to 1.0% by weight. By using the lithium composite oxide particles as a positive electrode active substance, it is possible to produce a lithium ion secondary battery that has a low electric resistance at a high temperature, and is excellent in cycle characteristic at a high temperature as well as high-temperature rate characteristic.

Abstract: A positive electrode active material comprises a Li-transition metal-layered oxide represented by the formula: Lia(NibCocAldMee)O2 (in which Me=Mn, Mg, Ti, Ru, Zr, Nb, Mo, W; 1.00?a?1.15; 0.25<b<1; 0<c?0.30; 0?d?0.05; 0?e?0.40), and is constituted of secondary particles formed by aggregation of primary particles. As to a compositional ratio of Li which is derived from unreacted substances or decomposed products in the secondary particles, a variation coefficient (Standard deviation value/Average value) of a Li-compositional ratio: Li/M (M=Ni+Co+Al+Me) is 30% or less. The positive electrode active material hardly deteriorates even if repeatedly charged/discharged, and enables stable charge/discharge, and then a non-aqueous electrolyte secondary battery is enabled to have an excellent output property and a long lifetime.

Abstract: An object of the present invention is to provide positive electrode active substance particles for non-aqueous electrolyte secondary batteries which are excellent in D.C. resistance characteristics under low-temperature conditions and a process for producing the provide positive electrode active substance particles, and a non-aqueous electrolyte secondary battery. The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries, comprising lithium composite oxide particles having a layered rock salt structure which are chemically reacted with at least Li and comprise at least one element selected from the group consisting of Ni, Co and Mn, and tungsten oxide particles, in which W is present in an amount of 0.1 to 4.0 mol % based on a total molar amount of Ni, Co and Mn in the lithium composite oxide particles, and the tungsten oxide particles have an average secondary particle diameter of 0.1 to 3.0 ?m.

Abstract: The present invention relates to lithium composite oxide particles which can be produced by mixing nickel-cobalt-manganese-based compound particles, a zirconium raw material and a lithium raw material with each other and then calcining the resulting mixture, and comprise a Zr compound that is allowed to be present on a surface thereof, in which the Zr compound is represented by the chemical formula: Lix(Zr1-yAy)Oz wherein x, y and z are 2.0?x?8.0; 0?y?1.0; and 2.0?z?6.0, respectively, and a content of Zr in the lithium composite oxide particles is 0.05 to 1.0% by weight. By using the lithium composite oxide particles as a positive electrode active substance, it is possible to produce a lithium ion secondary battery that has a low electric resistance at a high temperature, and is excellent in cycle characteristic at a high temperature as well as high-temperature rate characteristic.

Abstract: The present invention relates to nickel-cobalt-manganese-based compound particles which have a volume-based average secondary particle diameter (D50) of 3.0 to 25.0 ?m, wherein the volume-based average secondary particle diameter (D50) and a half value width (W) of the peak in volume-based particle size distribution of secondary particles thereof satisfy the relational formula: W?0.4×D50, and can be produced by dropping a metal salt-containing solution and an alkali solution to an alkali solution at the same time, followed by subjecting the obtained reaction solution to neutralization and precipitation reaction. The nickel-cobalt-manganese-based compound particles according to the present invention have a uniform particle size, a less content of very fine particles, a high crystallinity and a large primary particle diameter, and therefore are useful as a precursor of a positive electrode active substance used in a non-aqueous electrolyte secondary battery.

Abstract: The present invention relates to nickel-cobalt-manganese-based compound particles which have a volume-based average secondary particle diameter (D50) of 3.0 to 25.0 ?m, wherein the volume-based average secondary particle diameter (D50) and a half value width (W) of the peak in volume-based particle size distribution of secondary particles thereof satisfy the relational formula: W?0.4×D50, and can be produced by dropping a metal salt-containing solution and an alkali solution to an alkali solution at the same time, followed by subjecting the obtained reaction solution to neutralization and precipitation reaction. The nickel-cobalt-manganese-based compound particles according to the present invention have a uniform particle size, a less content of very fine particles, a high crystallinity and a large primary particle diameter, and therefore are useful as a precursor of a positive electrode active substance used in a non-aqueous electrolyte secondary battery.