Abstract: Disclosed herein is a high strength spring steel wire with excellent coiling properties and hydrogen embrittlement resistance. The steel wire comprises, by mass, 0.4 to 0.60% of C, 1.7 to 2.5% of Si, 0.1 to 0.4% of Mn, 0.5 to 2.0% of Cr, 0.015% or less of P (exceeding 0%), 0.015% or less of S (exceeding 0%), 0.006% or less of N (exceeding 0%), 0.001 to 0.07% of Al, and the remainder being Fe and unavoidable impurities. The steel wire has a structure wherein prior austenite has an average grain size of 12 ?m or less, and retained austenite exists in an amount of 1.0 to 8.0 vol. % with respect to a whole structure of the steel wire. The retained austenite has an average grain size of 300 nm or less and a maximum grain size of 800 nm or less. The steel has a tensile strength of 1,900 MPa or more.

Abstract: A steel for high-strength springs contains, on the mass basis, 0.35% to 0.65% of C, 1.4% to 2.5% of Si, 0.1% to 1.0% of Mn, 2.0% or less (exclusive of 0%) of Cr, 1.0% or less (exclusive of 0%) of Ni, 1.0% or less (exclusive of 0%) of Cu, 0.020% or less (exclusive of 0%) of P, 0.020% or less (exclusive of 0%) of S, 0.006% or less (exclusive of 0%) of N:, and 0.1% or less (exclusive of 0%) of Al, with the remainder being iron and inevitable impurities, in which Wp(Fe) and W(C) satisfy the following condition: Wp(Fe)>5×W(C), wherein Wp(Fe) is the content of Fe (percent by mass) constituting Fe-containing precipitates in the steel; and W(C) is the carbon content (percent by mass) of the steel. The steel is excellent in cold workability and quality stability.

Abstract: A high carbon steel wire material which is made of high carbon steel as a raw material for wire products such as steel cords, bead wires, PC steel wires and spring steel, allows for these wire products to be manufactured efficiently at a high wire drawing rate and has excellent wire drawability and a manufacturing process thereof. This high carbon steel wire material is made of a steel material having specific contents of C, Si, Mn, P, S, N, Al and O, and the Bcc-Fe crystal grains of its metal structure have an average crystal grain diameter (Dave) of 20 ?m or less and a maximum crystal grain diameter (Dmax) of 120 ?m or less, preferably an area ratio of crystal grains having a diameter of 80 ?m or more of 40% or less, an average sub grain diameter (dave) of 10 ?m or less, a maximum sub grain diameter (dmax) of 50 ?m or less and a (Dave/dave) ratio of the average crystal grain diameter (Dave) to the average sub grain diameter (dave) of 4.5 or less.

Abstract: The present invention provides a steel wire rod excellent in scale peelability for mechanical descaling, and a manufacturing method thereof. The steel wire rod in accordance with the present invention has: a base metal portion formed of a steel containing C in an amount of not more than 1.1% and Si in an amount of 0.05 to 0.80% on a mass % basis as components; and a scale layer deposited on the surface of the base metal portion, wherein the Si average concentration in the interface portion of the scale with the base metal portion is not less than 2.0 times the Si content of the base metal portion.

Abstract: The present invention provides a steel wire rod excellent in scale peelability for mechanical descaling, and a manufacturing method thereof.