Abstract: A method of inkjet printing includes ink jetting an aqueous inkjet ink composition to form a white printed image on a substrate. The aqueous inkjet ink composition comprises particles of titanium dioxide that are present in an amount of at least 4 to 15 weight % and the particles have a 95th percentile particle size of less than 200 nm and a 50th percentile particle size of less than 130 nm. The titanium dioxide particles are dispersed within the aqueous inkjet ink composition using a dispersing polymer that is a styrene-(meth)acrylic acid polymer, styrene-maleic anhydride polymer, or styrene-maleic acid polymer and the weight ratio of the titanium dioxide particles to the dispersing polymer is from 19:1 to and including 2:1.

Abstract: An aqueous dispersion contains pigment colorant particles that are present in an amount of at least 5 weight % and up to and including 80 weight %; a dispersing polymer that is a hexyloxy benzoic acid polymer; and an aqueous medium. The weight ratio of the pigment colorant particles to the dispersing polymer is from 19:1 to and including 2:1. Such aqueous dispersions can be incorporated into aqueous inkjet ink compositions that can be used for forming opaque images such as white images using inkjet printing methods.

Abstract: Inkjet printing is carried out on a substrate having a topmost layer comprising aqueous soluble multivalent metal cations and a hydrophilic polymeric binder. An aqueous inkjet ink composition is drawn from a main fluid supply as a continuous stream that is broken into both printing drops and non-printing drops, forming a white printed image on the substrate with the printing drops. The non-printing drops are collected and returned to the main fluid supply. The aqueous inkjet ink composition comprises particles of titanium dioxide in an amount of at least 4 to 15 weight %. The particles of titanium dioxide have a 95th percentile particle size of less than 200 nm, a 50th percentile particle size of less than 130 nm, and are dispersed using a dispersing polymer comprising acidic groups. The weight ratio of the particles of titanium dioxide to the dispersing polymer is 19:1 to 2:1.

Abstract: An aqueous dispersion contains pigment colorant particles (of various types of materials) at 5 weight % and up to and including 80 weight %; a dispersing polymer that is prepared from the Diels Alder adduct of 3-maleimidopropionic acid and furfuryl (meth)acrylate; and an aqueous medium. The weight ratio of the pigment colorant particles to the dispersing polymer is from 19:1 to and including 2:1. This aqueous dispersion can be incorporated into an aqueous inkjet ink composition that can be used in various inkjet printing methods to provide opaque images particularly when titanium dioxide particles are used as the pigment colorant.

Abstract: Inkjet printing is carried out on a substrate having a topmost layer comprising aqueous soluble multivalent metal cations and a hydrophilic polymeric binder. An aqueous inkjet ink composition is drawn from a main fluid supply as a continuous stream that is broken into both printing drops and non-printing drops, forming a white printed image on the substrate with the printing drops. The non-printing drops are collected and returned to the main fluid supply. The aqueous inkjet ink composition comprises particles of titanium dioxide in an amount of at least 4 to 15 weight %. The particles of titanium dioxide have a 95th percentile particle size of less than 200 nm, a 50th percentile particle size of less than 130 nm, and are dispersed using a dispersing polymer comprising acidic groups. The weight ratio of the particles of titanium dioxide to the dispersing polymer is 19:1 to 2:1.

Abstract: An aqueous dispersion contains pigment colorant particles that are present in an amount of at least 5 weight % and up to and including 80 weight %; a dispersing polymer that is a hexyloxy benzoic acid polymer; and an aqueous medium. The weight ratio of the pigment colorant particles to the dispersing polymer is from 19:1 to and including 2:1. Such aqueous dispersions can be incorporated into aqueous inkjet ink compositions that can be used for forming opaque images such as white images using inkjet printing methods.

Abstract: An aqueous dispersion contains pigment colorant particles (of various types of materials) at 5 weight % and up to and including 80 weight %; a dispersing polymer that is prepared from the Diels Alder adduct of 3-maleimidopropionic acid and furfuryl (meth)acrylate; and an aqueous medium. The weight ratio of the pigment colorant particles to the dispersing polymer is from 19:1 to and including 2:1. This aqueous dispersion can be incorporated into an aqueous inkjet ink composition that can be used in various inkjet printing methods to provide opaque images particularly when titanium dioxide particles are used as the pigment colorant.

Abstract: A method of inkjet printing includes ink jetting an aqueous inkjet ink composition to form a white printed image on a substrate. The aqueous inkjet ink composition comprises particles of titanium dioxide that are present in an amount of at least 4 to 15 weight % and the particles have a 95th percentile particle size of less than 200 nm and a 50th percentile particle size of less than 130 nm. The titanium dioxide particles are dispersed within the aqueous inkjet ink composition using a dispersing polymer that is a styrene-(meth)acrylic acid polymer, styrene-maleic anhydride polymer, or styrene-maleic acid polymer and the weight ratio of the titanium dioxide particles to the dispersing polymer is from 19:1 to and including 2:1.

Abstract: Porous organic polymeric films having multiple discrete cavities can be prepared using a water-in-oil emulsion that includes a cavity stabilizing hydrocolloid on the inner walls of the multiple discrete cavities. The multiple discrete cavities can also include organic catalytic materials for various catalytic reactions, markers materials for security applications, or the multiple discrete cavities can be used to increase opacity, hydrophobicity, or other desirable properties compared to nonporous organic polymeric films composed of the composition and dry thickness.

Abstract: Crosslinked polymeric organic porous particles have a crosslinked organic solid phase and discrete pores dispersed within the crosslinked organic solid phase, which discrete pores are isolated from each other. The crosslinked organic porous particles are prepared using one or more water-in-oil emulsions containing a polyfunctional reactive compound and a reagent that causes crosslinking, and can be incorporated into or applied to various articles for many purposes. If marker materials are incorporated into the crosslinked organic porous particles, these marker materials can be detected using appropriate instruments.

Abstract: Porous particles can be prepared using an evaporative limited coalescence process in which one or more discrete cavities are stabilized within the continuous polymeric solid phase of the porous particles. The one or more discrete cavities have inner walls and are dispersed within the continuous polymeric solid phase. The porous particles further comprise a cavity stabilizing hydrocolloid on the inner walls of the one or more discrete cavities, and an amphiphilic (low HLB) block copolymer that is disposed at the interface of the discrete cavities and the continuous polymeric solid phase.

Abstract: A method of manufacturing porous core-shell polymer particles having a nonporous shell including: providing a first organic solvent containing a dissolved polymer; dispersing the organic solvent in an aqueous phase containing a stabilizer to form an emulsion; adding the emulsion to a second organic solvent wherein the second organic solvent is miscible with water and the first organic solvent, and a non-solvent for the polymer; and evaporating the first and second organic solvents from the emulsion to form core-shell polymer particles. The method results in core-shell polymer particles comprising a common binder polymer for the core and the shell wherein the core has a porosity and the shell is non-porous. The particles have a porosity from 10 to 70 percent.

Abstract: Porous organic polymeric films having multiple discrete cavities can be prepared using a water-in-oil emulsion that includes a cavity stabilizing hydrocolloid on the inner walls of the multiple discrete cavities. The multiple discrete cavities can also include organic catalytic materials for various catalytic reactions, markers materials for security applications, or the multiple discrete cavities can be used to increase opacity, hydrophobicity, or other desirable properties compared to nonporous organic polymeric films composed of the composition and dry thickness.

Abstract: Porous organic polymeric films having multiple discrete cavities can be prepared using an water-in-oil emulsion that includes a cavity stabilizing hydrocolloid on the inner walls of the multiple discrete cavities. The multiple discrete cavities can also include organic catalytic materials for various catalytic reactions, markers materials for security applications, or the multiple discrete cavities can be used to increase opacity, hydrophobicity, or other desirable properties compared to nonporous organic polymeric films composed of the composition and dry thickness.

Abstract: Porous particles can be prepared using an evaporative limited coalescence process in which one or more discrete cavities are stabilized within the continuous polymeric solid phase of the porous particles. The one or more discrete cavities have inner walls and are dispersed within the continuous polymeric solid phase. The porous particles further comprise a cavity stabilizing hydrocolloid on the inner walls of the one or more discrete cavities, and an amphiphilic (low HLB) block copolymer that is disposed at the interface of the discrete cavities and the continuous polymeric solid phase.

Abstract: Porous organic polymeric films having multiple discrete cavities can be prepared using an water-in-oil emulsion that includes a cavity stabilizing hydrocolloid on the inner walls of the multiple discrete cavities. The multiple discrete cavities can also include organic catalytic materials for various catalytic reactions, markers materials for security applications, or the multiple discrete cavities can be used to increase opacity, hydrophobicity, or other desirable properties compared to nonporous organic polymeric films composed of the composition and dry thickness.

Abstract: The present invention is core-shell polymer particles comprising a common binder polymer for the core and the shell wherein the core has a porosity and the shell is non-porous The particles have a porosity from 10 to 70 percent.

Abstract: An article comprises one or more porous particles. Each porous particle comprises a polymer that provides a continuous solid phase including an external particle surface, and first and second discrete pores that are isolated from each other and dispersed within the continuous solid phase. The porous particle further comprises a first marker material present in the first discrete pores, and a second marker material that is detectably different from the first marker material and is present within the second discrete pores. The marker materials can provide a means for identifying documents, clothing, or other articles as genuine, and providing a detectable security system.

Abstract: Polymeric porous particles have a continuous solid phase and at least two different internal pores that are isolated from each other within the continuous phase. At least one set of discrete pores contains a marker material, and some instances, each set of discrete pores contain different pores marker materials that are isolated from each other. These marker materials are detectably different from each other. The porous particles can be spherical or non-spherical and can be used in any situation where the detectably different marker materials can be evaluated.

Abstract: Crosslinked polymeric organic porous particles have a crosslinked organic solid phase and discrete pores dispersed within the crosslinked organic solid phase, which discrete pores are isolated from each other. The crosslinked organic porous particles are prepared using one or more water-in-oil emulsions containing a polyfunctional reactive compound and a reagent that causes crosslinking, and can be incorporated into or applied to various articles for many purposes. If marker materials are incorporated into the crosslinked organic porous particles, these marker materials can be detected using appropriate instruments.