Patents by Inventor Tatsuhiko Shibuya
Tatsuhiko Shibuya has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7235500Abstract: A material for forming a silica based film which enables the production of a silica based film with a reduced etching rate relative to hydrofluoric acid. This material includes a solid fraction containing a film forming component capable of generating a silica based film, an organic solvent, and water, and the water content of the material, as determined by gas chromatography measurement, is within a range from 0.1 to 50% by weight.Type: GrantFiled: December 1, 2004Date of Patent: June 26, 2007Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Yasushi Fujii, Tatsuhiko Shibuya, Isao Sato
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Patent number: 7135064Abstract: A silica-based coating film having a low dielectric constant not exceeding 2.5 can be formed on the surface of a substrate to serve as a planarizing layer or an interlayer insulating layer by coating the surface with a unique coating solution containing a hydrolysis-condensation product of a polyalkoxy silane compound such as tetraethoxy silane and monomethyl trimethoxy silane, which is formed by the hydrolysis of a polyalkoxy silane in the presence of a basic catalyst such as ammonia in an alcohol solvent in a relatively low concentration followed by replacement of the alcohol solvent with an aprotic polar solvent such as N-methyl pyrrolidone, followed by drying and baking at 350 to 800° C.Type: GrantFiled: February 28, 2005Date of Patent: November 14, 2006Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Yoshio Hagiwara
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Patent number: 7060361Abstract: A film is provided which can be applied to high-temperature processes and can fill microspaces between wirings without forming voids and prevent the occurrence of side etching, and also causes less degassing due to increase of an atmospheric temperature. A coating solution containing a reaction product which is obtained by hydrolyzing at least one first alkoxysilane compound selected from the group consisting of compounds represented by general formula (I) and compounds represented by general formula (II) in an organic solvent in the presence of an acid catalyst is applied on a target material to form a coating film, and then the coating film is baked in an atmosphere having an oxygen concentration of 1000 ppm or less to form a silica-based organic film.Type: GrantFiled: July 10, 2003Date of Patent: June 13, 2006Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Yasushi Fujii
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Publication number: 20050147833Abstract: A silica-based coating film having a low dielectric constant not exceeding 2.5 can be formed on the surface of a substrate to serve as a planarizing layer or an interlayer insulating layer by coating the surface with a unique coating solution containing a hydrolysis-condensation product of a polyalkoxy silane compound such as tetraethoxy silane and monomethyl trimethoxy silane, which is formed by the hydrolysis of a polyalkoxy silane in the presence of a basic catalyst such as ammonia in an alcohol solvent in a relatively low concentration followed by replacement of the alcohol solvent with an aprotic polar solvent such as N-methyl pyrrolidone, followed by drying and baking at 350 to 800° C.Type: ApplicationFiled: February 28, 2005Publication date: July 7, 2005Inventors: Tatsuhiko Shibuya, Yoshio Hagiwara
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Publication number: 20050136692Abstract: A material for forming a silica based film which enables the production of a silica based film with a reduced etching rate relative to hydrofluoric acid. This material includes a solid fraction containing a film forming component capable of generating a silica based film, an organic solvent, and water, and the water content of the material, as determined by gas chromatography measurement, is within a range from 0.1 to 50% by weight.Type: ApplicationFiled: December 1, 2004Publication date: June 23, 2005Inventors: Yasushi Fujii, Tatsuhiko Shibuya, Isao Sato
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Patent number: 6875262Abstract: A silica-based coating film having a low dielectric constant not exceeding 2.5 can be formed on the surface of a substrate to serve as a planarizing layer or an interlayer insulating layer by coating the surface with a unique coating solution containing a hydrolysis-condensation product of a polyalkoxy silane compound such as tetraethoxy silane and monomethyl trimethoxy silane, which is formed by the hydrolysis of a polyalkoxy silane in the presence of a basic catalyst such as ammonia in an alcohol solvent in a relatively low concentration followed by replacement of the alcohol solvent with an aprotic polar solvent such as N-methyl pyrrolidone, followed by drying and baking at 350 to 800° C.Type: GrantFiled: April 30, 1999Date of Patent: April 5, 2005Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Yoshio Hagiwara
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Publication number: 20040180223Abstract: A film is provided which can be applied to high-temperature processes and can fill microspaces between wirings without forming voids and prevent the occurrence of side etching, and also causes less degassing due to increase of an atmospheric temperature. A coating solution containing a reaction product which is obtained by hydrolyzing at least one first alkoxysilane compound selected from the group consisting of compounds represented by general formula (I) and compounds represented by general formula (II) in an organic solvent in the presence of an acid catalyst is applied on a target material to form a coating film, and then the coating film is baked in an atmosphere having an oxygen concentration of 1000 ppm or less to form a silica-based organic film.Type: ApplicationFiled: March 15, 2004Publication date: September 16, 2004Applicant: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Yasushi Fujii
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Publication number: 20040028915Abstract: A film is provided which can be applied to high-temperature processes and can fill microspaces between wirings without forming voids and prevent the occurrence of side etching, and also causes less degassing due to increase of an atmospheric temperature. A coating solution containing a reaction product which is obtained by hydrolyzing at least one first alkoxysilane compound selected from the group consisting of compounds represented by general formula (I) and compounds represented by general formula (II) in an organic solvent in the presence of an acid catalyst is applied on a target material to form a coating film, and then the coating film is baked in an atmosphere having an oxygen concentration of 1000 ppm or less to form a silica-based organic film.Type: ApplicationFiled: July 10, 2003Publication date: February 12, 2004Applicant: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Yasushi Fujii
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Patent number: 6338868Abstract: Disclosed is a method for the formation of a silica coating film having a remarkably high crack-forming thickness limit on the surface of a substrate which may be highly heat resistant, for example, having a circuit wiring layer of polycrystalline silicon to withstand a temperature higher than 500° C. without excessive diffusion of dopant through the source layer or drain layer of the semiconductor device. The method comprises the steps of: coating the substrate surface with a coating solution containing a modified polysilazane which is a reaction product of a polysilazane and a dialkyl alkanol amine, drying the coating layer, subjecting the coating layer to a first baking treatment at 350-450° C. for 10-60 minutes and subjecting the layer to a second baking treatment at 550-800° C. for 0.5-60 minutes.Type: GrantFiled: December 12, 2000Date of Patent: January 15, 2002Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Yoshio Hagiwara
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Patent number: 6190788Abstract: Disclosed is a method for the formation of a silica coating film having a remarkably high crack-forming thickness limit on the surface of a substrate which may be highly heat resistant, for example, having a circuit wiring layer of polycrystalline silicon to withstand a temperature higher than 500° C. without excessive diffusion of dopant through the source layer or drain layer of the semiconductor device. The method comprises the steps of: coating the substrate surface with a coating solution containing a modified polysilazane which is a reaction product of a polysilazane and a dialkyl alkanol amine, drying the coating layer, subjecting the coating layer to a first baking treatment at 350-450° C. for 10-60 minutes and subjecting the layer to a second baking treatment at 550-800° C. for 0.5-60 minutes.Type: GrantFiled: June 8, 1999Date of Patent: February 20, 2001Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Yoshio Hagiwara
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Patent number: 5885654Abstract: Proposed is a coating solution for the formation of an interlayer insulating film of silicon dioxide in the manufacture of various kinds of electronic devices having excellent storage stability and coating workability. The principal ingredient of the coating solution, of which the solvent is preferably a dialkyl ether, is a polysilazane compound modified with a trimethylsilylating agent such as hexamethyl disilazane to such an extent that, in the .sup.1 H-NMR spectrometric diagram, the ratio of the area of the peak assignable to SiH.sub.3 to the total area of the peaks assignable to SiH.sub.1 and SiH.sub.2 is in the range from 0.15 to 0.45. An interlayer insulating film can be formed by coating a substrate with the coating solution, drying the coating layer and baking the dried coating layer at 300.degree. to 800.degree. C. in a moisturized atmosphere.Type: GrantFiled: August 12, 1997Date of Patent: March 23, 1999Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Yoshio Hagiwara, Tatsuhiko Shibuya
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Patent number: 5614271Abstract: Proposed is an improved method for the formation of a silica-based coating film on the surface of a substrate such as a silicon wafer in the manufacture of semiconductor devices by coating the substrate surface with a polysilazane-containing coating solution followed by conversion of the coating layer of polysilazane into a silica-based coating film. The method comprises drying the coating layer of the polysilazane according to a heating schedule at a specified heating rate with continuous or stepwise increase of the temperature up to 240.degree. to 350.degree. C. followed by an irradiation treatment with far ultraviolet light at a temperature of 240.degree. to 350.degree. C. and then by a baking treatment at 350.degree. to 800.degree. C.Type: GrantFiled: August 5, 1996Date of Patent: March 25, 1997Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tatsuhiko Shibuya, Susumu Okano, Hideya Kobari, Yoshio Hagiwara, Toshimasa Nakayama