Abstract: A glassy adhesive including a composition containing at least: a polysilazane compound having structures represented by the following formulae (A-1) and (A-2) and not containing a hydrosilyl group; and a curing catalyst, where a mole ratio of the component (A-1) to the component (A-2), which is (A-1):(A-2), is within a range of 3:7 to 7:3, the composition has a non-volatile content of 50 mass % or more, when the composition being heated at 105° C. for 3 hours, and the curing catalyst is at least one selected from the group consisting of an organic acid, a simple substance of a d block element belonging to the fourth period of the periodic table, a platinum group element, and an amphoteric element, and a compound containing the element. This provides an adhesive that is low-cost, has high UV resistance, and in which cracks and so forth do not occur even after a reflow process.

Abstract: The present invention is a normal temperature-curable hard coat composition containing at least (A) a polysilazane compound having structures shown by the following formula (1) and (B) an alkoxysilane compound. The ratio of [a] the number of Si—H bonds in the polysilazane compound and [b] the number of alkoxy groups in the alkoxysilane compound is in a range of [b]/[a]=1.5 to 3. The present invention provides the normal temperature-curable hard coat composition which has excellent workability on outdoors, cures at normal temperature, improves surface hardness of plastic materials, and is used as an alternative material to glass.

Abstract: The present invention is a normal temperature-curable hard coat composition containing at least (A) a polysilazane compound having structures shown by the following formula (1) and (B) an alkoxysilane compound. The ratio of [a] the number of Si—H bonds in the polysilazane compound and [b] the number of alkoxy groups in the alkoxysilane compound is in a range of [b]/[a]=1.5 to 3. The present invention provides the normal temperature-curable hard coat composition which has excellent workability on outdoors, cures at normal temperature, improves surface hardness of plastic materials, and is used as an alternative material to glass.

Abstract: A glassy adhesive including a composition containing at least: a polysilazane compound having structures represented by the following formulae (A-1) and (A-2) and not containing a hydrosilyl group; and a curing catalyst, where a mole ratio of the component (A-1) to the component (A-2), which is (A-1):(A-2), is within a range of 3:7 to 7:3, the composition has a non-volatile content of 50 mass % or more, when the composition being heated at 105° C. for 3 hours, and the curing catalyst is at least one selected from the group consisting of an organic acid, a simple substance of a d block element belonging to the fourth period of the periodic table, a platinum group element, and an amphoteric element, and a compound containing the element. This provides an adhesive that is low-cost, has high UV resistance, and in which cracks and so forth do not occur even after a reflow process.

Abstract: A transparent coating film forming composition contains: (A) a polysilazane having units represented by the following formulae (1) and (2), and having predetermined modification rate and weight average molecular weight, (B) an organic solvent containing (B-1) and (B-2), (B-1) an organic solvent having a dielectric constant of 2.1 to 15.0 on average and a higher boiling point under atmospheric pressure (1013 hPa) than that of an organic solvent contained as the component (B-2), and (B-2) a saturated aliphatic hydrocarbon organic solvent; and (C) a predetermined curing catalyst. The mixing ratio of the component (A) and the component (B) satisfies a predetermined range. This provides a transparent coating film forming composition using an organic solvent having high polysilazane solubility, volatility at an appropriate speed during application, high safety and workability, the composition enabling formation of a coating film that is uniform and has high transparency and hardness after curing.

Abstract: Provided is a material with improved surface hardness and abrasion resistance of a plastic substrate and a process for manufacturing the same. A plastic laminate including a plastic substrate and a hard coat layer formed on the plastic substrate, wherein the hard coat layer consists of a cured film of a hard coat agent including at least a polysilazane compound and nano-silica having an average particle size of 20 to 100 nm, wherein a continuous hardness difference is provided between the plastic substrate side of the hard coat layer and the surface layer side opposite thereto.

Abstract: Provided is a material with improved surface hardness and abrasion resistance of a plastic substrate and a process for manufacturing the same. A plastic laminate including a plastic substrate and a hard coat layer formed on the plastic substrate, wherein the hard coat layer consists of a cured film of a hard coat agent including at least a polysilazane compound and nano-silica having an average particle size of 20 to 100 nm, wherein a continuous hardness difference is provided between the plastic substrate side of the hard coat layer and the surface layer side opposite thereto.

Abstract: A transparent coating film forming composition contains: (A) a polysilazane having units represented by the following formulae (1) and (2), and having predetermined modification rate and weight average molecular weight, (B) an organic solvent containing (B-1) and (B-2), (B-1) an organic solvent having a dielectric constant of 2.1 to 15.0 on average and a higher boiling point under atmospheric pressure (1013 hPa) than that of an organic solvent contained as the component (B-2), and (B-2) a saturated aliphatic hydrocarbon organic solvent; and (C) a predetermined curing catalyst. The mixing ratio of the component (A) and the component (B) satisfies a predetermined range. This provides a transparent coating film forming composition using an organic solvent having high polysilazane solubility, volatility at an appropriate speed during application, high safety and workability, the composition enabling formation of a coating film that is uniform and has high transparency and hardness after curing.

Abstract: A polysilazane-containing composition includes: (A) a polysilazane containing units shown by the formulae (1) and (2), the ratio of the Si—R bond to the total number of the Si—H bond and the Si—R bond being 0.01 between 0.05, inclusive; and (B) an aliphatic hydrocarbon solvent. The proportion of (A)/(B) of the components is in a mass ratio range of 0.001 or more and 1.0 or less, R is selected from an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aromatic hydrocarbon group having 6 to 12 carbon atoms, and an alkoxy group having 1 to 6 carbon atoms. Each R may be the same or different in one molecule of the polysilazane. The polysilazane-containing composition with the polysilazane is readily soluble in an aliphatic hydrocarbon solvent to give a cured film having the same silica glass-like properties as those of the cured film of perhydropolysilazane.