Abstract: Provided is a method for separating impurities and cobalt without using an electrolysis process from a cobalt chloride solution containing impurities and producing a high purity cobalt sulfate.

Abstract: Provided is a method for separating copper from nickel and cobalt with which it is possible to selectively and efficiently separate copper, as well as nickel and cobalt, from an alloy including copper, nickel, and cobalt such as an alloy having high corrosion resistance that includes copper, nickel, and cobalt obtained by dry treatment of waste lithium ion cells. An alloy including copper, nickel, and cobalt is brought into contact with sulfuric acid in the joint presence of a sulfurizing agent, and a solid containing copper and a leachate containing nickel and cobalt are obtained.

Abstract: Provided is a method for separating copper from nickel and cobalt, which is capable of efficiently and selectively separating copper, and nickel and cobalt from an alloy containing copper, nickel and cobalt such as a highly anticorrosive alloy that is obtained by subjecting a waste lithium ion battery to a dry treatment and contains copper, nickel and cobalt. According to the present invention, an alloy containing copper, nickel and cobalt is brought into contact with an acid in the coexistence of a sulfurization agent, thereby obtaining a solid that contains copper and a leachate that contains nickel and cobalt.

Abstract: Provided is a method for separating copper from nickel and cobalt, which can efficiently and selectively separate copper from nickel and cobalt in a substance containing copper, nickel, and cobalt in a waste lithium ion battery, etc. In this method, a substance containing copper, nickel, and cobalt is sulfurated to obtain a sulfide, the obtained sulfide that contains copper, nickel, and cobalt is brought into contact with an acid solution to obtain a solid containing copper and a leachate containing nickel and cobalt. The sulfide preferably contains copper sulfide as a main component, and contains nickel metal and cobalt metal. In-addition, when bringing the sulfide into contact with the acid solution, the added amounts of the sulfide and the acid solution are preferably adjusted such that the oxidation-reduction potential of the obtained leachate is maintained at 150 mV or less where a silver/silver chloride electrode is a reference electrode.

Abstract: Provided is a method for separating impurities and cobalt without using an electrolysis process from a cobalt chloride solution containing impurities and producing a high purity cobalt sulfate.

Abstract: A method for recovering scandium, by which scandium is able to be recovered from nickel oxide ore. The present invention comprises: a leaching step S1 for obtaining a leachate by leaching a nickel oxide ore containing scandium with use of sulfuric acid; a neutralization step by adding a neutralizing agent thereto; a sulfurization step by adding a sulfurizing agent to the post-neutralization solution; an ion exchange step by bringing the post-sulfurization solution into contact with a chelating resin; a dissolution step by obtaining a precipitate of scandium hydroxide by adding an alkali into the scandium eluent, and subsequently adding an acid solution to the scandium hydroxide; a solvent extraction step by bringing the scandium acid dissolution liquid into contact with a neutral extractant; and a scandium recovery step by adding oxalic acid to the extraction residue and subsequently roasting the salt of scandium oxalate.

Abstract: Provided is a method for recovering scandium as scandium oxide that contains high-quality scandium and in which coarse particles having good handling properties are formed. This method for recovering scandium includes a step for carrying out an oxalate conversion process wherein oxalic acid is used in a solution containing scandium (scandium-containing solution) to generate a reaction in which the scandium is converted into an oxalate form, the method characterized in that the temperature of the reaction solution during the oxalate conversion process is 50° C. to 80° C.

Abstract: Provided is a method for producing, from scandium oxalate crystals obtained through an oxalate conversion process, a readily-soluble scandium compound that dissolves easily in an aqueous solution such as an acid. This method for producing a scandium compound involves carrying out an oxalate conversion process using oxalic acid in a solution containing scandium, separating the product obtained through the oxalate conversion process into a liquid and scandium oxalate crystals, and obtaining a scandium compound by roasting the obtained scandium oxalate crystals at a temperature of 400° C. to 800° C., preferably 400° C. to 600° C.

Abstract: Provided is a method for efficiently separating copper from nickel and cobalt from a sulfide containing nickel and cobalt together with copper. The present invention is a method for separating copper from nickel and cobalt, the method comprising pulverizing a sulfide containing copper and nickel and cobalt into a predetermined size and then stirring the resultant product under the condition having an oxidation-reduction potential (a reference electrode: a silver/silver chloride electrode) of less than 100 mV using an acid solution to perform a leaching treatment. In this separation method, a leach liquor in which nickel and cobalt are leached and a leach residue containing copper sulfate are produced as the result of the leaching treatment.

Abstract: A method for recovering scandium, by which scandium is able to be recovered from nickel oxide ore. The present invention comprises: a leaching step S1 for obtaining a leachate by leaching a nickel oxide ore containing scandium with use of sulfuric acid; a neutralization step by adding a neutralizing agent thereto; a sulfurization step by adding a sulfurizing agent to the post-neutralization solution; an ion exchange step by bringing the post-sulfurization solution into contact with a chelating resin; a dissolution step by obtaining a precipitate of scandium hydroxide by adding an alkali into the scandium eluent, and subsequently adding an acid solution to the scandium hydroxide; a solvent extraction step by bringing the scandium acid dissolution liquid into contact with a neutral extractant; and a scandium recovery step by adding oxalic acid to the extraction residue and subsequently roasting the salt of scandium oxalate.

Abstract: Provided is a method for separating copper from nickel and cobalt, which can efficiently and selectively separate copper from nickel and cobalt in a substance containing copper, nickel, and cobalt in a waste lithium ion battery, etc. In this method, a substance containing copper, nickel, and cobalt is sulfurated to obtain a sulfide, the obtained sulfide that contains copper, nickel, and cobalt is brought into contact with an acid solution to obtain a solid containing copper and a leachate containing nickel and cobalt. The sulfide preferably contains copper sulfide as a main component, and contains nickel metal and cobalt metal. In-addition, when bringing the sulfide into contact with the acid solution, the added amounts of the sulfide and the acid solution are preferably adjusted such that the oxidation-reduction potential of the obtained leachate is maintained at 150 mV or less where a silver/silver chloride electrode is a reference electrode.

Abstract: Provided is a method for obtaining high-purity scandium oxide efficiently from a solution containing scandium. The method for producing high-purity scandium oxide of the present invention has a first firing step S12 for subjecting a solution containing scandium to oxalation treatment using oxalic acid and firing the obtained crystals of scandium oxalate at a temperature of 400 to 600° C., inclusive, a dissolution step S13 for dissolving the scandium compound obtained by firing in one or more solutions selected from hydrochloric acid and nitric acid to obtain a solution, a reprecipitation step S14 for subjecting the solution to oxalation treatment using oxalic acid and generating a reprecipitate of scandium oxalate, and a second firing step S15 for firing the reprecipitate of obtained scandium oxalate to obtain scandium oxide.

Abstract: Provided is a method for obtaining high-purity scandium oxide efficiently from a solution containing scandium. The method for producing high-purity scandium oxide of the present invention has a first firing step S12 for subjecting a solution containing scandium to oxalation treatment using oxalic acid and firing the obtained crystals of scandium oxalate at a temperature of 400 to 600° C., inclusive, a dissolution step S13 for dissolving the scandium compound obtained by firing in one or more solutions selected from hydrochloric acid and nitric acid to obtain a solution, a reprecipitation step S14 for subjecting the solution to oxalation treatment using oxalic acid and generating a reprecipitate of scandium oxalate, and a second firing step S15 for firing the reprecipitate of obtained scandium oxalate to obtain scandium oxide.

Abstract: Provided is a method for separating copper, nickel, and cobalt, the method being capable of efficiently and selectively separating copper, nickel, and cobalt from alloys containing copper, nickel, and cobalt, such as highly corrosive alloys containing copper, nickel, and cobalt obtained by dry-processing used lithium ion batteries. The alloy containing copper, nickel, and cobalt is brought into contact with nitric acid in the co-presence of a sulfiding agent to obtain a solid containing copper and a leachate containing nickel and cobalt.

Abstract: Provided is a method for separating copper from nickel and cobalt with which it is possible to selectively and efficiently separate copper, as well as nickel and cobalt, from an alloy including copper, nickel, and cobalt such as an alloy having high corrosion resistance that includes copper, nickel, and cobalt obtained by dry treatment of waste lithium ion cells. An alloy including copper, nickel, and cobalt is brought into contact with sulfuric acid in the joint presence of a sulfurizing agent, and a solid containing copper and a leachate containing nickel and cobalt are obtained.

Abstract: Provided is a method for separating copper from nickel and cobalt, which is capable of efficiently and selectively separating copper, and nickel and cobalt from an alloy containing copper, nickel and cobalt such as a highly anticorrosive alloy that is obtained by subjecting a waste lithium ion battery to a dry treatment and contains copper, nickel and cobalt. According to the present invention, an alloy containing copper, nickel and cobalt is brought into contact with an acid in the coexistence of a sulfurization agent, thereby obtaining a solid that contains copper and a leachate that contains nickel and cobalt.

Abstract: A method for recovering scandium is provided, which is capable of recovering highly-pure scandium from nickel oxide ore in a simple and efficient manner. The method for recovering scandium according to the present invention includes a scandium elution step S2 of passing a solution containing scandium through an ion exchange resin to obtain an eluted liquid containing scandium from the ion exchange resin, a neutralization step S3 of adding for neutralization a neutralizing agent to the eluted liquid, a solvent extraction step S4 of solvent-extracting the neutralized eluted liquid using an amine-based extracting agent, and a scandium recovering step S5 of obtaining a scandium precipitate from residual liquid separated by the solvent extraction, and then roasting the precipitate to obtain scandium oxide.

Abstract: A nickel recovery process capable of decreasing nickel remaining in a byproduct by recovering nickel from the byproduct of electrolytic nickel manufacturing process by chlorine-leaching, and also, capable of simplifying a cementation step simultaneously, is provided. In a nickel recovery step S60, a nickel recovery step S70 and a nickel recovery step S80, nickel is recovered in each step from S0 slurry, residue flaker and chlorine-leached residue, which are byproducts of electrolytic nickel manufacturing process by chlorine-leaching, by using an aqueous solution containing 80 g/L to 390 g/L of chlorine and 30 g/L to 70 g/L of copper.

Abstract: A method for recovering scandium is provided, which is capable of recovering highly-pure scandium from nickel oxide ore in a simple and efficient manner. The method for recovering scandium according to the present invention includes a scandium elution step S2 of passing a solution containing scandium through an ion exchange resin to obtain an eluted liquid containing scandium from the ion exchange resin, a neutralization step S3 of adding for neutralization a neutralizing agent to the eluted liquid, a solvent extraction step S4 of solvent-extracting the neutralized eluted liquid using an amine-based extracting agent, and a scandium recovering step S5 of obtaining a scandium precipitate from residual liquid separated by the solvent extraction, and then roasting the precipitate to obtain scandium oxide.

Abstract: The method for recovering scandium pertaining to the present invention has: a first neutralization step for passing a solution containing scandium over an ion exchange resin, adding a neutralizing agent to the eluent eluted from the ion exchange resin and performing a neutralization treatment, and obtaining a primary neutralized sediment and a primary neutralized filtrate by solid-liquid separation; a second neutralization step for further adding a neutralizing agent to the primary neutralized filtrate and performing a neutralization treatment, and obtaining a secondary neutralized sediment and a secondary neutralized filtrate by solid-liquid separation; a hydroxide dissolution step for adding acid to the secondary neutralized sediment and obtaining a hydroxide solution; a solvent extraction step for subjecting the hydroxide solution to solvent extraction; and a scandium recovery step for recovering scandium oxide from a raffinate separated in the solvent extraction step.