Abstract: A battery assembly includes a first plurality of battery cells, a second plurality of battery cells, and an intermediate layer arranged in a stack. Each of the first plurality of battery cells includes a first cathode, a first cathode current collector, a first anode, a first anode current collector, and a first solid state separator, and each of the second plurality of battery cells includes a second cathode, a second cathode current collector, a second anode, a second anode current collector, and a second solid state separator. The first cathode current collectors are electrically connected in parallel to a first terminal, and the second anode current collectors are electrically connected in parallel to a second terminal. The first anode current collectors of the first plurality of battery cells are electrically connected and are electrically connected to the second cathode current collectors of the second plurality of battery cells.

Abstract: A battery charging system includes a charger that is dynamically controlled during charging, including during rapid charging events that include elevated voltage and/or elevated current levels. The charger is connectable to a battery cell of a rechargeable energy storage system. Operation includes transferring electric power having a charging current at a maximum charging rate to the battery cell. An anode potential offset setpoint is determined. A predicted anode potential offset is determined at an interface between the anode and the separator based upon the cell voltage for the battery cell. The charger is controlled to transfer the electric power to the battery cell based upon a temperature distribution in the battery cell and a difference between the anode potential offset setpoint and the predicted anode potential offset.

Abstract: A system for in-situ mapping of electrode potential and thermal distribution is provided. The system includes a test device. The test device includes an anode, a cathode, a reference electrode, a separator disposed between the anode and the cathode, and a voltage potential sensor configured for monitoring a voltage potential at a first position upon one of the anode or the cathode as compared to a voltage potential of the reference electrode. The system further includes an infrared sensor device configured for collecting data describing temperature variation across a surface of one of the anode or the cathode.

Abstract: An electrochemical battery cell includes a plurality of first electrodes, a plurality of second electrodes, a plurality of layers interleaved between and stacked in an electrode stack along a central stack axis with the first and second electrodes, a first current collector, and a second current collector. The second current collector includes an elongated cylinder and a fluidic coupler, the second current collector extends axially through the central stack cavity, and the second current collector includes a flow channel extending longitudinally between a first end and a second end.

Abstract: A battery electric device includes a battery cell, e.g., a pouch, prismatic, or cylindrical cell, connectable to an electric load, and a direct-to-air thermoelectric assembly (TEA) or another heat pump connected to a surface of the cell. A pressure control device maintains constant pressure on the cell surface when the cell is connected to the load. Connection to the load causes the TEA/heat pump to pump heat from the cell. A sensor, e.g., thermocouple(s) and/or heat flux sensor(s), generate an output voltage signal indicative of the quantity of heat. A battery system includes the device and a processor in communication with the cell, the load, and the power supply. The processor generates an electronic control signal in response to the quantity of heat.

Abstract: A method, apparatus, and control system for a battery cell include a heat exchanger in thermal contact with the battery cell, and a first controller. The first controller connects to the heat exchanger, and monitors the battery cell. The first controller includes a reduced order electrochemical model, a heat generation model, and a heat generation controller. The first controller determines a target parameter for the battery cell, and determines battery cell parameters. The reduced order electrochemical model determines internal ROM variables based upon the battery cell parameters. The heat generation model determines an electrochemical heat generation parameter from the battery cell based upon the internal ROM variables and the target parameter for the battery cell. The heat generation controller determines a heat work parameter based upon the electrochemical heat generation and the target parameter for the battery cell. The heat exchanger is controlled based upon the heat work parameter.

Abstract: A battery cell monitoring system provides a direct measurement of electrical and heat distributions in a battery cell, using segmented elements that are in direct contact with an electrode of the battery. The battery cell monitoring system provides distributed local through-plane current, temperature, and pressure measurements with power for operation of the battery being supplied via battery tabs. An embodiment of a battery cell monitoring system includes a two-dimensional current collector array, a two-dimensional temperature sensor array, a plurality of pressure sensors, and a plurality of reference electrodes interspersed within the current collector array. The current collector array, the temperature sensor array, the pressure sensors, and the reference electrodes are arranged on a printed circuit board. The current collector array is configured to have direct physical contact with an electrode of the battery cell. The current collector array is disposed within a container of the battery cell.

Abstract: A battery electric device includes a battery cell, e.g., a pouch, prismatic, or cylindrical cell, connectable to an electric load, and a direct-to-air thermoelectric assembly (TEA) or another heat pump connected to a surface of the cell. A pressure control device maintains constant pressure on the cell surface when the cell is connected to the load. Connection to the load causes the TEA/heat pump to pump heat from the cell. A sensor, e.g., thermocouple(s) and/or heat flux sensor(s), generate an output voltage signal indicative of the quantity of heat. A battery system includes the device and a processor in communication with the cell, the load, and the power supply. The processor generates an electronic control signal in response to the quantity of heat.

Abstract: A system for self-discharge prognostics for vehicle battery cells with an internal short circuit includes a plurality of battery cells and a voltage sensor providing open-circuit voltage data over time for each battery cell. The system further includes a computerized prognostic controller operating programming to monitor the open-circuit voltage data over time for each of the plurality of battery cells and evaluate a voltage drop rate through a time window for each of the plurality of battery cells based upon the open-circuit voltage data. The controller further identifies one of the plurality of battery cells to include the internal short circuit based upon the voltage drop rate and signals an alert based upon the one of the plurality of battery cells including the internal short circuit.

Abstract: A negative electrode of a lithium battery includes a current collector and a negative electrode layer disposed on a major surface of the current collector. The negative electrode layer exhibits a gradient structure including a proximal portion adjacent the major surface of the current collector and an opposite distal portion that defines a facing surface of the negative electrode layer. The negative electrode layer is configured such that a power density of the distal portion of the negative electrode layer is greater than that of the proximal portion of the negative electrode layer, and an energy density of the proximal portion of the negative electrode layer is greater than that of the distal portion of the negative electrode layer.

Abstract: Presented are electrochemical devices with in-stack sensor arrays, methods for making/using such electrochemical devices, and lithium-class battery cells with stacked electrode assemblies having in-stack sensor arrays. An electrochemical device includes a device housing that stores an electrolyte composition for conducting ions. An electrode stack, which is located inside the device housing in electrochemical contact with the electrolyte, includes at least two working electrodes. An electrically insulating and ionically transmissive separator is interposed between each neighboring pair of working electrodes. A reference electrode is attached to one side of the separator and connected to multiple electrical sensing devices.

Abstract: A system for self-discharge prognostics for vehicle battery cells with an internal short circuit includes a plurality of battery cells and a voltage sensor providing open-circuit voltage data over time for each battery cell. The system further includes a computerized prognostic controller operating programming to monitor the open-circuit voltage data over time for each of the plurality of battery cells and evaluate a voltage drop rate through a time window for each of the plurality of battery cells based upon the open-circuit voltage data. The controller further identifies one of the plurality of battery cells to include the internal short circuit based upon the voltage drop rate and signals an alert based upon the one of the plurality of battery cells including the internal short circuit.

Abstract: A method, apparatus, and control system for a battery cell include a heat exchanger in thermal contact with the battery cell, and a first controller. The first controller connects to the heat exchanger, and monitors the battery cell. The first controller includes a reduced order electrochemical model, a heat generation model, and a heat generation controller. The first controller determines a target parameter for the battery cell, and determines battery cell parameters. The reduced order electrochemical model determines internal ROM variables based upon the battery cell parameters. The heat generation model determines an electrochemical heat generation parameter from the battery cell based upon the internal ROM variables and the target parameter for the battery cell. The heat generation controller determines a heat work parameter based upon the electrochemical heat generation and the target parameter for the battery cell. The heat exchanger is controlled based upon the heat work parameter.