Abstract: A thermoelectric generator includes an enclosure accommodating therein multiple segments of anode thermoelectric material and multiple segments of cathode thermoelectric material, both having low thermal conductivity. The anode thermoelectric material segments are respectively jointed to the corresponding ones of the cathode thermoelectric material segments to form a plurality of V-shaped electrode pairs each having an apex. The plurality of V-shaped electrode pairs is connected in cascade to form a serially connected sequence with the apexes of the V-shaped electrode pairs of the sequence set in a common given direction. A conductive lead is connected to each of a first one and a last one of the plurality V-shaped electrode pairs of the sequence and extends out of the enclosure. The generator can be directly put in a flame or a high temperature environment and can bear a maximum temperature beyond 1000° C. without additionally mounted heat dissipation device.