Patents by Inventor Teofilo ROJO

Teofilo ROJO has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230207808
    Abstract: Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds may be obtained by a direct synthesis embodying a hydrothermal method. The method may include preparing an aqueous mixture including a M-containing compound, a M?-containing compound and a M?-containing compound to obtain a M-M?-M? mixture; adding a P-containing compound to the mixture M-M?-M? mixture to obtain a M-M?-M?-P mixture; adding a Na-containing compound to the M-M?-M?-P mixture to obtain a Na-M-M?-M?-P mixture; and introducing the Na-M-M?-M?-P mixture into an autoclave to perform crystal growth and obtain the compound of general formula NahMiM?jM?kPO4.
    Type: Application
    Filed: December 22, 2022
    Publication date: June 29, 2023
    Applicants: HYDRO-QUÉBEC, CIC ENERGIGUNE
    Inventors: Montse GALCERAN MESTRES, Montse CASAS-CABANAS, Abdelbast GUERFI, Michel ARMAND, Teofilo ROJO, Karim ZAGHIB, Andrea PAOLELLA
  • Patent number: 11569506
    Abstract: This disclosure provides for Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds of the invention are obtained by a direct synthesis embodying a hydrothermal method.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: January 31, 2023
    Assignees: HYDRO-QUÉBEC, CIC ENERGIGUNE
    Inventors: Montse Galceran Mestres, Montse Casas-Cabanas, Abdelbast Guerfi, Michel Armand, Teofilo Rojo, Karim Zaghib, Andrea Paolella
  • Patent number: 10964941
    Abstract: The present invention relates to a sodium-ion battery comprising a positive electrode compartment comprising a positive electrode, said positive electrode comprising a Na-insertion compound; a negative electrode compartment comprising a negative electrode, said negative electrode comprising metallic sodium; and an electrolyte composition comprising a solid sodium-ion conductive ceramic electrolyte and a catholyte comprising a metallic salt with formula MY, wherein M is a cation selected from an alkali metal and an alkali-earth metal; and Y is an anion selected from [R1SO2NSO2R2], CF3SO3?, C(CN)3?, B(C2O4)2? and BF2(C2O4)?, wherein R1 and R2 are independently selected from fluorine or a fluoroalkyl group. The device is able to operate below the melting point of the anode component.
    Type: Grant
    Filed: October 14, 2015
    Date of Patent: March 30, 2021
    Assignee: FUNDACION CENTRO DE INVESTIGACION COOPERATIVA DE ENERGIAS ALTERNATIVAS CIC ENERGIGUNE FUNDAZIOA
    Inventors: Michel Armand, Teofilo Rojo, Gurpreet Singh, Laida Otaegui Ameztegui, Frederic Aguesse, Lucienne Buannic
  • Patent number: 10892521
    Abstract: The present invention refers to a method for preparing a solid polymer electrolyte based on modified cellulose, the method comprising the steps of: a) lithiation or sodiation of at least a hydroxyl group of each repeating unit of a “cellulose” to obtain Li(cellulose) or Na(cellulose); b) functionalization of the Li(cellulose) or Na(cellulose) obtained in step a), in the presence of an aprotic solvent by reacting it with an organic linker, wherein the organic linker serves to covalently attach at least one organic salt to the “cellulose”, and the use of the solid polymer electrolyte in lithium or sodium secondary batteries.
    Type: Grant
    Filed: June 27, 2018
    Date of Patent: January 12, 2021
    Assignee: FUNDACION CENTRO DE INVESTIGACION COOPERATIVA DE ENERGIAS ALTERNATIV AS CIC ENERGIGUNE FUNDAZIOA
    Inventors: Hicham Ben Youcef, Michel Armand, Brahim Orayech, Damien Saurel, Devaraj Shanmukaraj, Teofilo Rojo
  • Publication number: 20200274162
    Abstract: This disclosure provides for Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds of the invention are obtained by a direct synthesis embodying a hydrothermal method.
    Type: Application
    Filed: December 20, 2016
    Publication date: August 27, 2020
    Applicants: HYDRO-QUÉBEC, CIC ENERGIGUNE
    Inventors: Montse GALCERAN MESTRES, Montse CASAS-CABANAS, Abdelbast GUERFI, Michel ARMAND, Teofilo ROJO, Karim ZAGHIB, Andrea PAOLELLA
  • Patent number: 10544050
    Abstract: A positive electrode active material for a sodium-ion secondary battery contains a compound of formula NaxMn1-y-zMyM?zO2 or its hydrate. A cathode can contain the active material and rechargeable sodium-ion battery can contain such a cathode.
    Type: Grant
    Filed: March 31, 2016
    Date of Patent: January 28, 2020
    Assignee: FUNDACIÓN CENTRO DE INVESTIGACIÓN COOPERATIVA DE ENERGÍAS ALTERNATIVAS CIC ENERGIGUNE FUNDAZIOA
    Inventors: Man Huon Han, Elena Gonzalo, Teófilo Rojo
  • Publication number: 20180123164
    Abstract: A positive electrode active material for a sodium-ion secondary battery contains a compound of formula NaxMn1?y?zMyM?zO2 or its hydrate. A cathode can contain the active material and rechargeable sodium-ion battery can contain such a cathode.
    Type: Application
    Filed: March 31, 2016
    Publication date: May 3, 2018
    Inventors: Man Huon HAN, Elena GONZALO, Teófilo ROJO
  • Patent number: 9923235
    Abstract: A nanoparticulate organic hybrid material comprising inorganic nanoparticles covalently grafted with at least one anion of an organic sodium or lithium salt is provided. In addition, a process for preparing the nanoparticulate organic hybrid material and its use in the preparation of electrolytes suitable for lithium and sodium secondary batteries are provided.
    Type: Grant
    Filed: January 21, 2013
    Date of Patent: March 20, 2018
    Assignee: CIC ENERGIGUNE
    Inventors: Michel Armand, Irune Villaluenga, Teófilo Rojo Aparicio
  • Publication number: 20170250406
    Abstract: The present invention relates to a sodium-ion battery comprising a positive electrode compartment comprising a positive electrode, said positive electrode comprising a Na-insertion compound; a negative electrode compartment comprising a negative electrode, said negative electrode comprising metallic sodium; and an electrolyte composition comprising a solid sodium-ion conductive ceramic electrolyte and a catholyte comprising a metallic salt with formula MY, wherein M is a cation selected from an alkali metal and an alkali-earth metal; and Y is an anion selected from [R1SO2NSO2R2], CF3SO3?, C(CN)3?, B(C2O4)2? and BF2(C2O4)?, wherein R1 and R2 are independently selected from fluorine or a fluoroalkyl group. The device is able to operate below the melting point of the anode component.
    Type: Application
    Filed: October 14, 2015
    Publication date: August 31, 2017
    Inventors: Michel ARMAND, Teofilo ROJO, Gurpreet SINGH, Laida OTAEGUI AMEZTEGUI, Frederic AGUESSE, Lucienne BUANNIC
  • Publication number: 20150188189
    Abstract: A nanoparticulate organic hybrid material comprising inorganic nanoparticles covalently grafted with at least one anion of an organic sodium or lithium salt is provided. In addition, a process for preparing the nanoparticulate organic hybrid material and its use in the preparation of electrolytes suitable for lithium and sodium secondary batteries are provided.
    Type: Application
    Filed: January 21, 2013
    Publication date: July 2, 2015
    Inventors: Michel Armand, Irune Villaluenga, Teófilo Rojo Aparicio
  • Publication number: 20120315480
    Abstract: The present invention relates to thiol- or an amine-associated ferromagnetic or superparamagnetic copper nanoparticles with an average diameter less than 30 nm, to the method for obtaining them and their applications in biomedicine and other fields.
    Type: Application
    Filed: July 31, 2009
    Publication date: December 13, 2012
    Applicant: UNIVERSIDAD DEL PAIS VASCO
    Inventors: José Javier Saiz Garitaonandia, Eider Goikolea Núñez, Teófilo Rojo Aparicio, Maite Insausti Peña, Fernando Plazaola Muguruza