Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.

Abstract: The present invention relates to thermochromatic inks. The present invention provides a toy, wherein the toy includes at least one thermochromatic ink. The present invention provides a pre-printed item, wherein when the temperature of the pre-printed item is changed to particular temperatures, the color of a marking, the color of a drawing, or both, change. The present invention provides an interactive item, wherein the visual appearance of the item is changed by changing the color of at least one of a first or second inks. The present invention provides a drawing device, wherein the position of a substrate and a temperature element are such that a thermochromatic ink does not change color unless sufficient pressure is applied to the substrate effective to deflect the surface of the substrate and bring it temporarily sufficiently more proximate to the temperature element. The present invention provides a smart wand for drawing on a substrate that includes thermochromatic ink.

Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer and a porous uppermost layer, each with particular limitations The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density, and image quality.

Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer, a porous intermediate layer, and a porous uppermost layer, each with particular limitations. The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density and image quality.

Abstract: The present invention relates to thermochromatic inks. The present invention provides a toy, wherein the toy includes at least one thermochromatic ink. The present invention provides a pre-printed item, wherein when the temperature of the pre-printed item is changed to particular temperatures, the color of a marking, the color of a drawing, or both, change. The present invention provides an interactive item, wherein the visual appearance of the item is changed by changing the color of at least one of a first or second inks. The present invention provides a drawing device, wherein the position of a substrate and a temperature element are such that a thermochromatic ink does not change color unless sufficient pressure is applied to the substrate effective to deflect the surface of the substrate and bring it temporarily sufficiently more proximate to the temperature element. The present invention provides a smart wand for drawing on a substrate that includes thermochromatic ink.

Abstract: The present invention is directed to an image-recording medium comprising a paper support and, coated on one side of the support, in order: a lower ink-receiving layer, an upper gloss layer and, coated on the opposite side of the support, an inner layer comprising at least 75% by weight of fine inorganic particles and a binder, and an outer layer substantially consisting of a polymeric material. Another aspect of the present invention relates to an inkjet printing process.

Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.

Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.

Abstract: The present invention discloses an ink printing method using an image-recording element, which provides an image having excellent image quality and superior dry time, comprising insoluble cationic core-shell polymeric particles each comprising a core comprising cationic core polymer having at least 10 mole percent of a cationic mordant monomeric unit and a shell comprising hydrophilic shell polymer that is substantially less cationic than the cationic core polymer, wherein the shell is at least 10% by weight of the core.

Abstract: An inkjet recording element comprising an absorbent support, a porous base layer nearest the support and comprising precipitated calcium carbonate, a porous ink-receiving intermediate layer above the base layer and comprising hydrated alumina, and a porous ink-receiving upper layer above the intermediate layer and comprising a mixture of hydrated and fumed alumina. Also disclosed is an advantageous method of making such inkjet recording materials.

Abstract: An inkjet recording element comprising an absorbent support, a porous base layer nearest the support, a porous ink-receiving intermediate layer above the base layer, and a porous ink-receiving upper layer above the intermediate layer. The base layer and intermediate layers are each present in an amount of at least 25 g/m2 and the total dry weight coverage of the base layer, the intermediate layer, and the upper layer is 60 to 130 g/m2 in order to handle high fluxes of ink compositions during printing and to provide high gloss upon calendering. Also disclosed is an advantageous method of making such inkjet recording materials.

Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer, a porous intermediate layer, and a porous uppermost layer, each with particular limitations. The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density and image quality.

Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer and a porous uppermost layer, each with particular limitations The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density, and image quality.

Abstract: The present invention is directed to an image-recording medium comprising a paper support and, coated on one side of the support, in order: a lower ink-receiving layer, an upper gloss layer and, coated on the opposite side of the support, an inner layer comprising at least 75% by weight of fine inorganic particles and a binder, and an outer layer substantially consisting of a polymeric material. Another aspect of the present invention relates to an inkjet printing process.

Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.

Abstract: The present invention discloses an ink printing method using an image-recording element, which provides an image having excellent image quality and superior dry time, comprising insoluble cationic core-shell polymeric particles each comprising a core comprising cationic core polymer having at least 10 mole percent of a cationic mordant monomeric unit and a shell comprising hydrophilic shell polymer that is substantially less cationic than the cationic core polymer, wherein the shell is at least 10% by weight of the core.

Abstract: An ink jet recording element comprising a support having thereon, in order, a hydrophilic absorbing layer and a polymeric overcoat layer comprising particles of a substantially amorphous synthetic aluminosilicate. Such recording elements exhibit improved humidity keeping and smudge resistance, while maintaining good differential gloss.

Abstract: An inkjet recording element comprising a support having thereon, in order, a support having thereon a ink-receiving layer comprising a hydrophilic polymer and particles of an aluminosilicate in an amount of less than 30 weight percent solids, based on the total weight of the layer. Such recording elements exhibit improved humidity keeping for print sharpness.

Abstract: An inkjet recording element comprising a support having thereon, in order, a support having thereon an ink-receiving layer comprising a hydrophilic polymer, a polymeric mordant, and particles of an aluminosilicate. Such recording elements exhibit improved humidity keeping.

Abstract: An inkjet recording element comprising a support having thereon a subbing layer comprising particles of an aluminosilicate for improved adhesion.