Patents by Inventor Terry Marker
Terry Marker has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240010922Abstract: Liquefied petroleum gas (LPG) synthesis catalyst systems are disclosed that provide activities for both alcohol (e.g., methanol) synthesis and in situ dehydration of the alcohol (e.g., methanol) to hydrocarbons, and particularly the LPG hydrocarbons propane and/or butane. The incorporation of a stabilizer such as platinum and/or yttrium (e.g., as yttria or yttrium oxide) can benefit these catalyst systems, particularly in terms of improving their activity and/or stability. Other advantages may be realized by the incorporation of promoters such as manganese (Mn), magnesium (Mg), and/or silicon (Si) into these catalyst systems, such as to improve selectivity to, and/or yield of, desired LPG hydrocarbons.Type: ApplicationFiled: July 5, 2023Publication date: January 11, 2024Inventors: Patrick LITTLEWOOD, Terry MARKER, Michael BRADFORD
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Publication number: 20230382820Abstract: Pathways are disclosed for the production of liquid hydrocarbon products comprising gasoline and/or diesel boiling-range hydrocarbons, and in certain cases renewable products having non-petroleum derived carbon. In representative processes, a gaseous feed mixture comprising CO2 in combination H2 and/or CH4 (or other hydrocarbon source of H2) is converted by reforming and/or reverse water-gas shift (RWGS) reactions, optionally further in combination with Fischer-Tropsch (FT) synthesis and/or cracking. A preferred gaseous feed mixture comprises biogas or otherwise a mixture of CO2 and H2 that is not readily upgraded using conventional processes. Catalysts described herein have a high activity for catalyzing the reforming (including dry reforming) of CH4 and other light hydrocarbons (e.g., those having been produced via FT synthesis and recycled as light ends back to the process) as well as simultaneously catalyzing the RWGS reaction.Type: ApplicationFiled: May 22, 2023Publication date: November 30, 2023Inventors: Terry MARKER, Jim WANGEROW, Martin LINCK
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Publication number: 20230348800Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (?H) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Such dry reforming (reaction with CO2 only) or CO2-steam reforming (reaction with both CO2 and steam) processes are advantageously integrated with Fischer-Tropsch synthesis to yield liquid hydrocarbon fuels. Further integration may involve the use of a downstream finishing stage involving hydroisomerization to remove FT wax.Type: ApplicationFiled: April 18, 2023Publication date: November 2, 2023Inventors: Terry MARKER, Martin B. LINCK, Jim WANGEROW, Pedro ORTIZ-TORAL
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Patent number: 11667853Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (?H) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Such dry reforming (reaction with CO2 only) or CO2-steam reforming (reaction with both CO2 and steam) processes are advantageously integrated with Fischer-Tropsch synthesis to yield liquid hydrocarbon fuels. Further integration may involve the use of a downstream finishing stage involving hydroisomerization to remove FT wax.Type: GrantFiled: July 14, 2020Date of Patent: June 6, 2023Assignee: GTI EnergyInventors: Terry Marker, Martin B. Linck, Jim Wangerow, Pedro Ortiz-Toral
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Publication number: 20230069964Abstract: Pathways are disclosed for the production of liquefied petroleum gas (LPG) products comprising propane and/or butane, and in certain cases renewable products having non-petroleum derived carbon. In particular, a gaseous feed mixture comprising CO2 in combination with CH4 and/or H2 is converted by reforming and/or reverse water-gas shift (RWGS) reactions, further in combination with LPG synthesis. A preferred gaseous feed mixture comprises biogas or otherwise a mixture of CO2 and H2 that is not readily upgraded using conventional processes. Catalysts described herein have a high activity for reforming (including dry reforming) of CH4, as well as simultaneously catalyzing RWGS. These attributes improve the management of CO2 that is input to the disclosed processes, particularly in those utilizing recycle operation to increase overall CO2 conversion.Type: ApplicationFiled: September 9, 2021Publication date: March 9, 2023Inventors: Patrick LITTLEWOOD, Jim WANGEROW, Terry MARKER, Andrew WOLEK
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Publication number: 20220134298Abstract: Electrically heated reforming reactors and associated reforming processes are disclosed, which benefit from a number of advantages in terms of attaining and controlling the input of heat to catalytic conversion processes such as in the reforming of hydrocarbons (e.g., methane) using H2O and/or CO2 as an oxidant. The disclosed reactors provide the ability to target the input of heat to specific regions within a catalyst bed volume. This allows for the control of the temperature profile in one or more dimensions (e.g., axially and/or radially) and/or otherwise tailoring heat input for processing specific reformer feeds, achieving specific reformer products, effectively utilizing the catalyst, and/or compensating for a number of operating parameters (e.g., flow distribution). Dynamic control of the heat input may be used in response to changes in feed or product composition and/or catalyst activity.Type: ApplicationFiled: August 16, 2021Publication date: May 5, 2022Inventors: Terry MARKER, Jim WANGEROW, Martin LINCK
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Publication number: 20210348063Abstract: Process are disclosed for converting plastics, and especially thermoplastic oxygenated polymers, by hydrodeoxygenation (HDO) to hydrocarbons, such as aromatic hydrocarbons including benzene, toluene, ethylbenzene, and xylene isomers. These hydrocarbons may be recovered as chemicals and/or fuels, depending on the particular chemical structures of the starting materials, including the presence of oxygen in the polymer backbones. Advantageously, using a sufficiently active catalyst, only moderate conditions, such as in terms of hydrogen partial pressure, are required, in comparison to known hydrotreating processes. This leads to the formation, with fewer non-selective side reactions, of desired liquid hydrocarbons from substantially all carbon in the oxygenated polymer, as well as water from substantially all oxygen in the oxygenated polymer. In some cases, the liquid hydrocarbons obtained are platform chemicals that can be used for a number of specialized purposes.Type: ApplicationFiled: February 23, 2021Publication date: November 11, 2021Inventors: Martin B. LINCK, Terry MARKER, Pedro ORTIZ-TORAL, Jim WANGEROW
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Patent number: 11111142Abstract: Processes and catalysts for producing hydrogen by reforming methane are disclosed, which afford considerable flexibility in terms of the quality of the reformer feed. This can be attributed to the robustness of the noble metal-containing catalysts described herein for use in reforming, such that a number of components commonly present in methane-containing process streams can advantageously be maintained without conventional upgrading (pretreating) steps, thereby improving process economics. This also allows for the reforming of impure reformer feeds, even in relatively small quantities, which may be characterized as complex gas mixtures due to significant quantities of non-methane components. A representative reforming catalyst comprises 1 wt-% Pt and 1 wt-% Rh as noble metals, on a cerium oxide support.Type: GrantFiled: September 18, 2018Date of Patent: September 7, 2021Assignee: Gas Technology InstituteInventors: Terry Marker, Jim Wangerow, Pedro Ortiz-Toral, Martin Linck
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Patent number: 11104852Abstract: Processes and catalyst systems are disclosed for performing Fischer-Tropsch (FT) synthesis to produce C4+ hydrocarbons, such as gasoline boiling-range hydrocarbons and/or diesel boiling-range hydrocarbons. Advantageously, catalyst systems described herein have additional activity (beyond FT activity) for in situ hydroisomerization and/or hydrocracking of wax that is generated according to the distribution of hydrocarbons obtained from the FT synthesis reaction. This not only improves the yield of hydrocarbons (e.g., C4-19 hydrocarbons) that are useful for transportation fuels, but also allows for alternative reactor types, such as a fluidized bed reactor.Type: GrantFiled: May 7, 2019Date of Patent: August 31, 2021Assignee: Gas Technology InstituteInventors: Terry Marker, Jim Wangerow, Pedro Ortiz-Toral, Martin Linck
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Publication number: 20210171345Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (AH) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Catalysts for such processes advantageously possess high activity and thereby can achieve significant levels of methane conversion at temperatures below those used conventionally under comparable conditions. These catalysts also exhibit high sulfur tolerance, in addition to reduced rates of carbon (coke) formation, even in the processing (reforming) of heavier (e.g., naphtha boiling-range or jet fuel boiling-range) hydrocarbons. The robustness of the catalyst translates to high operating stability.Type: ApplicationFiled: January 20, 2021Publication date: June 10, 2021Inventors: Terry MARKER, Martin B. LINCK, Jim WANGEROW, Pedro ORTIZ-TORAL
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Patent number: 10906808Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (?H) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Catalysts for such processes advantageously possess high activity and thereby can achieve significant levels of methane conversion at temperatures below those used conventionally under comparable conditions. These catalysts also exhibit high sulfur tolerance, in addition to reduced rates of carbon (coke) formation, even in the processing (reforming) of heavier (e.g., naphtha boiling-range or jet fuel boiling-range) hydrocarbons. The robustness of the catalyst translates to high operating stability.Type: GrantFiled: November 15, 2017Date of Patent: February 2, 2021Assignee: Gas Technology InstituteInventors: Terry Marker, Martin Linck, Jim Wangerow, Pedro Ortiz-Toral
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Publication number: 20200392416Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (?H) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Such dry reforming (reaction with CO2 only) or CO2-steam reforming (reaction with both CO2 and steam) processes are advantageously integrated with Fischer-Tropsch synthesis to yield liquid hydrocarbon fuels. Further integration may involve the use of a downstream finishing stage involving hydroisomerization to remove FT wax.Type: ApplicationFiled: July 14, 2020Publication date: December 17, 2020Inventors: Terry MARKER, Martin B. LINCK, Jim WANGEROW, Pedro ORTIZ-TORAL
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Patent number: 10759722Abstract: Aspects of the invention are associated with the discovery of approaches for the conversion of sour natural gas streams, by conversion to liquid hydrocarbons. Particular processes and their associated apparatuses advantageously combine (i) dehydroaromatization (DHA) of methane in a gaseous feedstock, to produce aromatic hydrocarbons such as benzene, with (ii) the reaction of H2S and methane in this feedstock, to produce organic sulfur compounds such as carbon disulfide (CS2) and thiophene (C4H4S). A gaseous product having a reduced concentration of H2S is thereby generated. The aromatic hydrocarbons and organic sulfur compounds may be recovered in a liquid product. Both the gaseous and liquid products may be easily amenable to further upgrading. Other advantages of the disclosed processes and apparatuses reside in their simplicity, whereby the associated streams, including a potential gaseous recycle, generally avoid high partial pressures of H2S.Type: GrantFiled: January 11, 2018Date of Patent: September 1, 2020Assignee: Gas Technology InstituteInventors: Terry Marker, Jim Wangerow, Dane Boysen, Martin B. Linck, Pedro Ortiz-Toral
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Patent number: 10738247Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (?H) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Such dry reforming (reaction with CO2 only) or CO2-steam reforming (reaction with both CO2 and steam) processes are advantageously integrated with Fischer-Tropsch synthesis to yield liquid hydrocarbon fuels. Further integration may involve the use of a downstream finishing stage involving hydroisomerization to remove FT wax.Type: GrantFiled: November 15, 2017Date of Patent: August 11, 2020Assignee: Gas Technology InstituteInventors: Terry Marker, Martin B. Linck, Jim Wangerow, Pedro Ortiz-Toral
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Publication number: 20200087144Abstract: Processes and catalysts for producing hydrogen by reforming methane are disclosed, which afford considerable flexibility in terms of the quality of the reformer feed. This can be attributed to the robustness of the noble metal-containing catalysts described herein for use in reforming, such that a number of components commonly present in methane-containing process streams can advantageously be maintained without conventional upgrading (pretreating) steps, thereby improving process economics. This also allows for the reforming of impure reformer feeds, even in relatively small quantities, which may be characterized as complex gas mixtures due to significant quantities of non-methane components. A representative reforming catalyst comprises 1 wt-% Pt and 1 wt-% Rh as noble metals, on a cerium oxide support.Type: ApplicationFiled: September 18, 2018Publication date: March 19, 2020Inventors: Terry MARKER, Jim WANGEROW, Pedro ORTIZ-TORAL, Martin LINCK
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Publication number: 20200087576Abstract: Processes and catalysts for producing hydrogen by reforming methane are disclosed, which afford considerable flexibility in terms of the quality of the reformer feed. This can be attributed to the robustness of the noble metal-containing catalysts described herein for use in reforming, such that a number of components commonly present in methane-containing process streams can advantageously be maintained without conventional upgrading (pretreating) steps, thereby improving process economics. This also allows for the reforming of impure reformer feeds, even in relatively small quantities, which may be characterized as complex gas mixtures due to significant quantities of non-methane components. A representative reforming catalyst comprises 1 wt-% Pt and 1 wt-% Rh as noble metals, on a cerium oxide support.Type: ApplicationFiled: July 17, 2019Publication date: March 19, 2020Inventors: Terry MARKER, Jim WANGEROW, Pedro ORTIZ-TORAL, Martin LINCK
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Publication number: 20200032146Abstract: Processes and catalyst systems are disclosed for performing Fischer-Tropsch (FT) synthesis to produce C4+ hydrocarbons, such as gasoline boiling-range hydrocarbons and/or diesel boiling-range hydrocarbons. Advantageously, catalyst systems described herein have additional activity (beyond FT activity) for in situ hydroisomerization and/or hydrocracking of wax that is generated according to the distribution of hydrocarbons obtained from the FT synthesis reaction. This not only improves the yield of hydrocarbons (e.g., C4-19 hydrocarbons) that are useful for transportation fuels, but also allows for alternative reactor types, such as a fluidized bed reactor.Type: ApplicationFiled: May 7, 2019Publication date: January 30, 2020Inventors: Terry MARKER, Jim WANGEROW, Pedro ORTIZ-TORAL, Martin LINCK
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Publication number: 20190210941Abstract: Aspects of the invention are associated with the discovery of approaches for the conversion of sour natural gas streams, by conversion to liquid hydrocarbons. Particular processes and their associated apparatuses advantageously combine (i) dehydroaromatization (DHA) of methane in a gaseous feedstock, to produce aromatic hydrocarbons such as benzene, with (ii) the reaction of H2S and methane in this feedstock, to produce organic sulfur compounds such as carbon disulfide (CS2) and thiophene (C4H4S). A gaseous product having a reduced concentration of H2S is thereby generated. The aromatic hydrocarbons and organic sulfur compounds may be recovered in a liquid product. Both the gaseous and liquid products may be easily amenable to further upgrading. Other advantages of the disclosed processes and apparatuses reside in their simplicity, whereby the associated streams, including a potential gaseous recycle, generally avoid high partial pressures of H2S.Type: ApplicationFiled: January 11, 2018Publication date: July 11, 2019Inventors: Terry MARKER, Jim WANGEROW, Dane BOYSEN, Martin B. LINCK, Pedro ORTIZ-TORAL
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Publication number: 20190144274Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (?H) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Catalysts for such processes advantageously possess high activity and thereby can achieve significant levels of methane conversion at temperatures below those used conventionally under comparable conditions. These catalysts also exhibit high sulfur tolerance, in addition to reduced rates of carbon (coke) formation, even in the processing (reforming) of heavier (e.g., naphtha boiling-range or jet fuel boiling-range) hydrocarbons. The robustness of the catalyst translates to high operating stability.Type: ApplicationFiled: November 15, 2017Publication date: May 16, 2019Inventors: Terry MARKER, Martin LINCK, Jim WANGEROW, Pedro ORTIZ-TORAL
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Publication number: 20190144765Abstract: Processes for converting methane and/or other hydrocarbons to synthesis gas (i.e., a gaseous mixture comprising H2 and CO) are disclosed, in which at least a portion of the hydrocarbon(s) is reacted with CO2. At least a second portion of the methane may be reacted with H2O (steam), thereby improving overall thermodynamics of the process, in terms of reducing endothermicity (?H) and the required energy input, compared to “pure” dry reforming in which no H2O is present. Such dry reforming (reaction with CO2 only) or CO2-steam reforming (reaction with both CO2 and steam) processes are advantageously integrated with Fischer-Tropsch synthesis to yield liquid hydrocarbon fuels. Further integration may involve the use of a downstream finishing stage involving hydroisomerization to remove FT wax.Type: ApplicationFiled: November 15, 2017Publication date: May 16, 2019Inventors: Terry MARKER, Martin B. LINCK, Jim WANGEROW, Pedro ORTIZ-TORAL