Abstract: Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II).

Abstract: The present invention provides a process for producing an ?-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher ?-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

Abstract: The present invention provides an olefin polymerization catalyst, which is free of polyfunctional aromatic compounds and has a large particle diameter, and a solid titanium component (I) which forms the catalyst.

Abstract: A solid titanium catalyst component (I) comprising titanium, magnesium, halogen, a specific cyclic ester compound (a) and a specific cyclic ester compound (b), an olefin polymerization catalyst containing this catalyst component (I), and an olefin polymerization process using this olefin polymerization catalyst are disclosed. According to the solid titanium catalyst component, the olefin polymerization catalyst and the process for preparing an olefin polymer of the invention, an olefin polymer having high stereoregularity and a wide molecular weight distribution can be prepared with high activity, preparation of an olefin polymer excellent not only in molding properties such as high-speed streatchability and high-speed moldability but also in rigidity becomes possible, and besides, production cost can be reduced.

Abstract: The present invention provides a process for producing an ?-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher ?-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

Abstract: Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II).

Abstract: Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II).

Abstract: A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

Abstract: The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1): wherein n is an integer of 5 to 10, R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, and a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, and an organometallic compound catalyst component (II), at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature.

Abstract: Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II).

Abstract: Ethylene polymer particles having an intrinsic viscosity [?] of 5 dl/g to 30 dl/g, a degree of crystallinity of as high as 80% or more, and a specific shape on the surface of the particles. The ethylene polymer particles can be obtained by carrying out polymerization of olefins including ethylene using an olefin polymerization catalyst containing a solid titanium catalyst component including magnesium, halogen and titanium under specific conditions. The ethylene polymer particles obtained by a solid phase method, such as solid phase drawing molding, are capable of providing a molded article with high strength.

Abstract: The present invention provides a process for producing an ?-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher ?-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

Abstract: A solid titanium catalyst component (I) comprising titanium, magnesium, halogen, a specific cyclic ester compound (a) and a specific cyclic ester compound (b), an olefin polymerization catalyst containing this catalyst component (I), and an olefin polymerization process using this olefin polymerization catalyst are disclosed. According to the solid titanium catalyst component, the olefin polymerization catalyst and the process for preparing an olefin polymer of the invention, an olefin polymer having high stereoregularity and a wide molecular weight distribution can be prepared with high activity, preparation of an olefin polymer excellent not only in molding properties such as high-speed streatchability and high-speed moldability but also in rigidity becomes possible, and besides, production cost can be reduced.

Abstract: The present invention provides an olefin polymerization catalyst, which is free of polyfunctional aromatic compounds and has a large particle diameter, and a solid titanium component (I) which forms the catalyst.

Abstract: A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.

Abstract: The present invention relates to a solid titanium catalyst component containing magnesium, titanium, halogen and a specific ester compound; a catalyst for olefin polymerization containing the solid titanium catalyst component, an organometallic compound catalyst component and an electron donor where necessary; and a polymerization method of an olefin using the catalyst for olefin polymerization. According to the present invention, an olefin polymer having a high Mw/Mn value which is an index of the molecular weight distribution is obtained, even by a single-stage polymerization. Especially an olefin polymer having a high Mz/Mw which is a high content of high molecular weight components is obtained.

Abstract: A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.

Abstract: The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1): wherein n is an integer of 5 to 10, R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, and a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, and an organometallic compound catalyst component (II), at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature.

Abstract: A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

Abstract: A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.