Abstract: Poly(3-hydroxyalkanoate) foam particles are obtained by: introducing a blowing agent into an aqueous dispersion in a pressure-resistant vessel, the aqueous dispersion containing a crosslinking agent and resin particles containing a poly(3-hydroxyalkanoate); heating the contents of the pressure-resistant vessel to a given temperature in a range of 130 to 150° C.; holding the contents of the pressure-resistant vessel at the given temperature for 5 to 55 minutes; and opening one end of the pressure-resistant vessel to discharge the contents of the pressure-resistant vessel into a low-pressure atmosphere and foam the resin particles. The poly(3-hydroxyalkanoate) is a mixture containing a poly(3-hydroxyalkanoate) copolymer and a poly(3-hydroxybutyrate) homopolymer at a weight ratio of 99:1 to 80:20, and the crosslinking agent is an organic peroxide which is a percarbonate.

Abstract: Provided are poly(3-hydroxyalkanoate) foam particles, which can give a foam molded article having good surface aspects and a low shrinkage ratio of a molding, and the foam molded article. The poly(3-hydroxyalkanoate) foam particles have at least two melting peaks on a DSC curve obtained by differential scanning calorimetry and in which a melting calorie (X) on a high temperature side is 0.1 to 20 J/g, a gel fraction (Y) is 20 to 75% by weight, and the melting calorie (X) and the gel fraction (Y) satisfy Formula: X+Y?30.

Abstract: Provided are poly(3-hydroxyalkanoate) foam particles in which a gel fraction of the whole foam particles is from 30 to 80% by weight and a difference in gel fraction between inside and outside of the foam particles is 25% by weight or less. Preferably, the foam particles are particles crosslinked by an organic peroxide. Preferably, the organic peroxide has a 1 hour half-life temperature of 114 to 124° C., contains a carbonate group, and is liquid at room temperature.

Abstract: A PHA copolymer which is slowly crystallized is improved in crystallization speed to improve the melt workability of the PHA copolymer in working such as injection molding, film molding, blow molding, fiber spinning, extrusion foaming or bead foaming, thereby improving the resultant articles in productivity. A method for the improvement is a method for producing a PHA mixture, including the step of culturing a microorganism having both of a gene encoding a PHA synthase that synthesizes a copolymer PHA (A) and that is derived from the genus Aeromonas, and a gene encoding a PHA synthase that synthesizes a PHA (B) different in melting point from the copolymer PHA (A) by 10° C. or more to produce, in a cell of the microorganism, two or more PHAs different in melting point from one another by 10° C. or more simultaneously.

Abstract: Provided are poly(3-hydroxyalkanoate) foam particles, which can give a foam molded article having good surface aspects and a low shrinkage ratio of a molding, and the foam molded article. The poly(3-hydroxyalkanoate) foam particles have at least two melting peaks on a DSC curve obtained by differential scanning calorimetry and in which a melting calorie (X) on a high temperature side is 0.1 to 20 J/g, a gel fraction (Y) is 20 to 75% by weight, and the melting calorie (X) and the gel fraction (Y) satisfy Formula: X+Y?30.

Abstract: A PHA copolymer which is slowly crystallized is improved in crystallization speed to improve the melt workability of the PHA copolymer in working such as injection molding, film molding, blow molding, fiber spinning, extrusion foaming or bead foaming, thereby improving the resultant articles in productivity. A method for the improvement is a method for producing a PHA mixture, including the step of culturing a microorganism having both of a gene encoding a PHA synthase that synthesizes a copolymer PHA (A) and that is derived from the genus Aeromonas, and a gene encoding a PHA synthase that synthesizes a PHA (B) different in melting point from the copolymer PHA (A) by 10° C. or more to produce, in a cell of the microorganism, two or more PHAs different in melting point from one another by 10° C. or more simultaneously.

Abstract: A biodegradable polyester resin composition containing 30 to 60 parts by weight of (A) a polylactic acid, 25 to 45 parts by weight of (B) a poly-3-hydroxyalkanoate, and 5 to 25 parts by weight of (C) an aliphatic-aromatic polyester, based on 100 parts by weight in total of (A) the polylactic acid, (B) the poly-3-hydroxyalkanoate and (C) the aliphatic-aromatic polyester. The biodegradable polyester resin composition further contains 0.05 to 20 parts by weight: of (D) pentaerythritol, 10 to 40 parts by weight of (E) a silicate, and 0 to 3 parts by weight of (F) a compatibilizer having an epoxy group, relative to 100 parts by weight in total of (A) the polylactic acid, (B) the poly-3-hydroxyalkanoate, and (C) the aliphatic-aromatic polyester.

Abstract: A PHA copolymer which is slowly crystallized is improved in crystallization speed to improve the melt workability of the PHA copolymer in working such as injection molding, film molding, blow molding, fiber spinning, extrusion foaming or bead foaming, thereby improving the resultant articles in productivity. A method for the improvement is a method for producing a PHA mixture, including the step of culturing a microorganism having both of a gene encoding a PHA synthase that synthesizes a copolymer PHA (A) and that is derived from the genus Aeromonas, and a gene encoding a PHA synthase that synthesizes a PHA (B) different in melting point from the copolymer PHA (A) by 10° C. or more to produce, in a cell of the microorganism, two or more PHAs different in melting point from one another by 10° C. or more simultaneously.

Abstract: A biodegradable polyester resin composition containing 30 to 60 parts by weight of (A) a polylactic acid, 25 to 45 parts by weight of (B) a poly-3-hydroxyalkanoate, and 5 to 25 parts by weight of (C) an aliphatic-aromatic polyester, based on 100 parts by weight in total of (A) the polylactic acid, (B) the poly-3-hydroxyalkanoate, and (C) the aliphatic-aromatic polyester. The biodegradable polyester resin composition further contains 0.05 to 20 parts by weight of (D) pentaerythritol, 10 to 40 pans by weight of (E) a silicate, and 0 to 3 parts by weight of (F) a compatibilizer having an epoxy group, relative to 100 parts by weight in total of (A) the polylactic acid, (B) the poly-3-hydroxyalkanoate, and (C) the aliphatic-aromatic polyester.

Abstract: A polyester resin composition includes: a polylactic acid; a poly(3-hydroxyalkanoate); pentaerythritol; and a silicate. In the polyester resin composition, an amount of the polylactic acid is from 55 to 75 parts by weight, and an amount of the poly(3-hydroxyalkanoate) (B) is from 25 to 45 parts by weight, with respect to 100 parts by weight of a total amount of the polylactic acid and the poly(3-hydroxyalkanoate); an amount of the pentaerythritol is from 0.05 to 20 parts by weight with respect to 100 parts by weight of the total amount of the polylactic acid and the poly(3-hydroxyalkanoate); and an amount of the silicate is from 10 to 40 parts by weight with respect to 100 parts by weight of the total amount of the polylactic acid and the poly(3-hydroxyalkanoate).

Abstract: An object of the present invention is to: improve slowness of crystallization that is a drawback of polyhydroxyalkanoate; suppress bloom of a nucleating agent or the like; and improve surface smoothness and mold transferability of an obtained molded body. The present invention provides an aliphatic polyester resin composition including polyhydroxyalkanoate (A), pentaerythritol (B), and a filler (C).

Abstract: An object is to improve slow crystallization that is a drawback of polyhydroxyalkanoates, improve processability in mold processing, such as injection molding, improve processing speed, and suppress blooming from a obtaining molded article. Provided is an aliphatic polyester resin composition including a polyhydroxyalkanoate (A), a vinyl acetate-containing copolymer (B), and pentaerythritol (C), wherein the polyhydroxyalkanoate (A) and the vinyl acetate-containing copolymer (B) are immiscible.

Abstract: Methods may include methods of producing polyester resin composition and methods of producing a polyester resin formed article that make it possible to improve thermal resistance, and to provide the polyester resin composition and the polyester resin formed article. Methods of producing a polyester resin composition may include: a step (I-a) of obtaining a polylactic acid composition (X) containing a polylactic acid (A), pentaerythritol (C), and a silicate (D); and a step (II-a) of mixing the polylactic acid composition (X) with a poly(3-hydroxyalkanoate) (B).

Abstract: A polyester resin composition includes: a polylactic acid; a poly(3-hydroxyalkanoate); pentaerythritol; and a silicate. In the polyester resin composition, an amount of the polylactic acid is from 55 to 75 parts by weight, and an amount of the poly(3-hydroxyalkanoate) (B) is from 25 to 45 parts by weight, with respect to 100 parts by weight of a total amount of the polylactic acid and the poly(3-hydroxyalkanoate); an amount of the pentaerythritol is from 0.05 to 20 parts by weight with respect to 100 parts by weight of the total amount of the polylactic acid and the poly(3-hydroxyalkanoate); and an amount of the silicate is from 10 to 40 parts by weight with respect to 100 parts by weight of the total amount of the polylactic acid and the poly(3-hydroxyalkanoate).

Abstract: Provided is a resin composition excellent in processability and productivity, which improves low crystallization rate and improves processability in forming such as injection molding or sheet forming. Provided is a polyester resin composition including a polyester resin (A), a crystallization promoter (B), and pentaerythritol (C).

Abstract: An object of the present invention is to improve spinnability, productivity, and tensile strength of a polyester fiber containing poly(3-hydroxybutyrate-co-3-hydroxyhexanoate). By spinning the polyester resin containing the poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) at a high spinning velocity, the spinnability, productivity, and tensile strength of the polyester fiber can be improved.

Abstract: A PHA copolymer which is slowly crystallized is improved in crystallization speed to improve the melt workability of the PHA copolymer in working such as injection molding, film molding, blow molding, fiber spinning, extrusion foaming or bead foaming, thereby improving the resultant articles in productivity. A method for the improvement is a method for producing a PHA mixture, including the step of culturing a microorganism having both of a gene encoding a PHA synthase that synthesizes a copolymer PHA (A) and that is derived from the genus Aeromonas, and a gene encoding a PHA synthase that synthesizes a PHA (B) different in melting point from the copolymer PHA (A) by 10° C. or more to produce, in a cell of the microorganism, two or more PHAs different in melting point from one another by 10° C. or more simultaneously.

Abstract: The purpose of the present invention is to improve processability in the melt-molding by improving the slowness of crystallization that is a disadvantage of polyhydroxyalkanoate, which is slow to crystallize, and to improve processing speed. Provided is a polyester resin composition including a first polyhydroxyalkanoate and a second polyhydroxyalkanoate, wherein the melting point of the second polyhydroxyalkanoate in the polyester resin composition is observed at a temperature lower than the melting point measured for the second polyhydroxyalkanoate alone.

Abstract: Disclosed herein is an aliphatic polyester resin composition that simultaneously improves slow crystallization, low impact strength, and low tensile elongation that are the drawbacks of a polyhydroxyalkanoate. The aliphatic polyester resin composition comprises: a polyhydroxyalkanoate (A); a graft copolymer (B); and pentaerythritol (C), wherein the graft copolymer (B) is obtained by graft polymerization of a vinyl-based monomer onto at least one rubber selected from the group consisting of a composite rubber (b1) comprising a polyorganosiloxane component and a polyalkyl(meth)acrylate component, an acrylic rubber (b2), and a diene-based rubber (b3) comprising a diene-based monomer.

Abstract: An object is to improve both slow crystallization and brittleness that are drawbacks of polyhydroxyalkanoates, so that processability in mold processing, such as injection molding, is improved, processing speed is increased, and ductility is imparted to a resulting molded article. Provided is an aliphatic polyester resin composition including a polyhydroxyalkanoate (A), an ethylene-vinyl acetate copolymer resin (B), and pentaerythritol (C), wherein the ethylene-vinyl acetate copolymer resin (B) has a vinyl acetate content of 65 to 95 wt %, and the polyhydroxyalkanoate (A) and the ethylene-vinyl acetate copolymer resin (B) are compatible.