Abstract: Provided herein are TiO2-x nanoparticles and materials that show unusual photophysical and optical properties. These TiO2-x particles and materials can be used as efficient photocatalysts for the reduction of CO2 with H2O to produce CH4. Also provided herein are methods of making TiO2-x nanoparticles using a polymer-derived mesoporous carbon (PDMC) as a template.

Abstract: The present disclosure relates to compositions and methods of treating a wound, or location of interest, in a subject by topically administering to the subject the therapeutic composition of the disclosure. The composition of the disclosure comprises nanoparticle (NP) composites for delivering one or more therapeutic agents to the wound.

Abstract: The present invention relates in one aspect to the discovery of novel mesoporous silica nanoparticles (MSNs) templated around and comprising benzalkonium chloride (BAC). In certain embodiments, the BAC-SiO2 mesoporous nanoparticles are capable of sustained release of BAC under acidic conditions, thereby acting as a long release antimicrobial agent. In other embodiments, the BAC-SiO2 mesoporous nanoparticles can be incorporated into a variety of consumer products as an antimicrobial agent additive, including for example, but not limited to, surgical dressings, bandages, deodorants, soaps, facial cleansers and industrial cleaners.

Abstract: The present invention relates in one aspect to the discovery of novel mesoporous silica nanoparticles (MSNs) templated around and comprising benzalkonium chloride (BAC). In certain embodiments, the BAC-SiO2 mesoporous nanoparticles are capable of sustained release of BAC under acidic conditions, thereby acting as a long release antimicrobial agent. In other embodiments, the BAC-SiO2 mesoporous nanoparticles can be incorporated into a variety of consumer products as an antimicrobial agent additive, including for example, but not limited to, surgical dressings, bandages, deodorants, soaps, facial cleansers and industrial cleaners.

Abstract: A multi-catalytic material that includes a polyelectrolyte membrane and methods of preparing the same are provided herein.

Abstract: Provided is a method for preparing a catalyst for a dehydrogenation reaction of formate and a hydrogenation reaction of bicarbonate, the method including: adding a silica colloid to a polymerization step of polymerizing aniline and reacting the resulting mixture to form a poly(silica-aniline) composite; carbonizing the corresponding poly(silica-aniline) composite under an atmosphere of an inert gas; removing silica particles from the corresponding poly(silica-aniline) composite to form a polyaniline-based porous carbon support; and fixing palladium particles on the corresponding polyaniline-based porous carbon support to prepare the catalyst.

Abstract: The present invention relates in part to the unexpected discovery of novel hybrid organic-inorganic aerogel materials with one-dimensionally aligned pores.

Abstract: Electrocatalytic polyaniline-derived mesoporous carbon nanoparticles and methods of synthesizing and using the same are provided.

Abstract: Provided is a method for preparing a catalyst for a dehydrogenation reaction of formate and a hydrogenation reaction of bicarbonate, the method including: adding a silica colloid to a polymerization step of polymerizing aniline and reacting the resulting mixture to form a poly(silica-aniline) composite; carbonizing the corresponding poly(silica-aniline) composite under an atmosphere of an inert gas; removing silica particles from the corresponding poly(silica-aniline) composite to form a polyaniline-based porous carbon support; and fixing palladium particles on the corresponding polyaniline-based porous carbon support to prepare the catalyst.

Abstract: A multi-catalytic material that includes a polyelectrolyte membrane and methods of preparing the same are provided herein.

Abstract: Efficient and recyclable heterogeneous nanocatalysts and methods of synthesizing and using the same are provided.

Abstract: A method of synthesizing corrugated and nanoporous microspheres including the steps of synthesizing substantially smooth spherical microspheres, and controlled wet-etching of the substantially smooth spherical microspheres with a basic solution having a pH above 10.00 is provided. The microspheres can include, for example, silica microspheres or titania microspheres of various sized diameters of between 50 nm and 600 nm. The basic solution can include an aqueous potassium cyanide solution or an aqueous potassium hydroxide solution. Methods of using the corrugated and nanoporous microspheres described herein are also provided.

Abstract: Selective and efficient multifunctional nanoporous catalysts containing spatially distributed organoamine and silanol groups, and methods of preparation thereof. The catalysts have been observed to be very highly efficient in catalysis of the Henry reaction.

Abstract: Electrocatalytic polyaniline-derived mesoporous carbon nanoparticles and methods of synthesizing and using the same are provided.

Abstract: A method for synthesizing a phosphonic acid functionalized mesoporous metal oxide material (e.g., silica, titania, alumina, preferably silica material) is provided. Further, a method of using the phosphonic acid functionalized mesoporous silica material as a solid acid catalyst in a pinicole-pinacolone rearrangement reaction, and a method of using a phosphonic acid functionalized mesoporous silica material as a solid acid catalyst in a transesterification reaction is provided. A method for preparing a mesoporous titania film for use in a dye sensitized solar cell is also provided.

Abstract: Efficient and recyclable heterogeneous nanocatalysts and methods of synthesizing and using the same are provided.

Abstract: Nanocatalysts and methods of synthesizing and using the same are provided.

Abstract: Selective and efficient multifunctional nanoporous catalysts containing spatially distributed organoamine and silanol groups, and methods of preparation thereof. The catalysts have been observed to be very highly efficient in catalysis of the Henry reaction.

Abstract: A method for synthesizing a phosphonic acid functionalized mesoporous metal oxide material (e.g., silica, titania, alumina, preferably silica material) is provided. Further, a method of using the phosphonic acid functionalized mesoporous silica material as a solid acid catalyst in a pinicole-pinacolone rearrangement reaction, and a method of using a phosphonic acid functionalized mesoporous silica material as a solid acid catalyst in a transesterification reaction is provided. A method for preparing a mesoporous titania film for use in a dye sensitized solar cell is also provided.

Abstract: The present invention provides a synthetic strategy for creating a new class of materials called hybrid mesoporous, macroporous, or mesoporous-macroporous organometaloxide materials, exemplified but not limited to hybrid mesoporous organosilicas. This strategy involves taking a pre-assembled mesoporous material having a porous framework and then attaching an organic, inorganic or biological guest molecule to the pore walls of the framework material through two or more chemical linkages. The unusual combination of inorganic and organic components organized into a material with mesoscale porosity and having bridge bonded organic, organometallic, or biological functionalized surfaces suggests a myriad of uses for these composite materials, such as the controlled release and uptake of chemicals and drugs, chiral separations and catalysis, electronic printing and microelectronic packaging, thermal and acoustical insulation.