Patents by Inventor Thaddeus F. Kroplinski

Thaddeus F. Kroplinski has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4281210
    Abstract: A cured, cross-linked, mineral oil extended polyurethane which is non-spewing. The mineral oil extended polyurethane is further characterized by being grease compatible in that the tendency of the mineral oil to migrate is substantially reduced or eliminated. The mineral oil extended polyurethane is comprised of a defined polyurethane, mineral oil, and coupling agent. In other aspects, the present invention relates to a process for reclaiming or sealing an insulated electrical device and to an insulated electrical device which is formed by such process.
    Type: Grant
    Filed: April 6, 1979
    Date of Patent: July 28, 1981
    Assignee: NL Industries, Inc.
    Inventors: Melvin Brauer, Thaddeus F. Kroplinski
  • Patent number: 4267044
    Abstract: Novel thixotropic polyurethane compositions particularly useful as sealants for the edges of folded membrane separatory devices are provided which comprise;(a) a prepolymer comprising the reaction product of a polyol having a hydroxyl functionality of at least 2 with one mole per hydroxy group of said polyol of an organic diisocyanate; and(b) a crosslinking agent comprising a polyether polyol having a hydroxyl functionality of at least 2 and a primary amine-terminated polyether having an amine functionality of at least 2.To accelerate curing of the composition, the crosslinking agent can be modified by employing primary hydroxyl-terminated polyethers and/or adding hydroxyl-containing tertiary amines.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: May 12, 1981
    Assignee: NL Industries, Inc.
    Inventors: Thaddeus F. Kroplinski, Barton C. Case
  • Patent number: 4256617
    Abstract: The present invention is directed to improvements in non-toxic polyurethane compositions and separatory devices employing the same, such as hollow fiber separatory devices intended to be used in biomedical applications. The separatory device employs at least one separatory membrane suitable for the intended end use application which is secured, potted or sealed in a housing using a cured flexible polyurethane composition. The improvement in the polyurethane composition employed in the separatory device is achieved by reacting at least one NCO-terminated prepolymer and at least one polyol in the presence of a ricinoleic acid reactive catalyst. The catalyst reduces the curing time of the polyurethane resin and because it is sufficiently reactive with the NCO-terminated prepolymer, it is incorporated into the structure of the polyurethane and cannot be released during operation of the separatory device.
    Type: Grant
    Filed: November 1, 1979
    Date of Patent: March 17, 1981
    Assignee: NL Industries, Inc.
    Inventors: Thaddeus F. Kroplinski, Barton C. Case
  • Patent number: 4231986
    Abstract: A cured, cross-linked, mineral oil extended polyurethane which is non-spewing. The mineral oil extended polyurethane is further characterized by being grease compatible in that the tendency of the mineral oil to migrate is substantially reduced or eliminated. The mineral oil extended polyurethane is comprised of a defined polyurethane, mineral oil, and coupling agent. In other aspects, the present invention relates to a process for reclaiming or sealing an insulated electrical device and to an insulated electrical device which is formed by such process.
    Type: Grant
    Filed: April 6, 1979
    Date of Patent: November 4, 1980
    Assignee: NL Industries, Inc.
    Inventors: Melvin Brauer, Thaddeus F. Kroplinski
  • Patent number: 4224164
    Abstract: A non-wicking polyurethane casting system has been developed which comprises the reaction product obtained by admixing a polyol containing N-N-N'-N'-tetrakis (2-hydroxypropyl) ethylene diamine, (hereafter referred to as QUADROL) with an isocyanate terminated polyurethane based prepolymer. This non-wicking casting system is useful as a potting compound in biomedical applications such as dialysis and hemoultrafiltration devices and the like.
    Type: Grant
    Filed: October 20, 1978
    Date of Patent: September 23, 1980
    Assignee: NL Industries, Inc.
    Inventors: Melvin Brauer, Barton C. Case, Thaddeus F. Kroplinski
  • Patent number: 4176239
    Abstract: This invention provides a method of sealing and purging contaminants from the internal free spaces of an insulated electrical device by forcing into said free spaces a low viscosity material that acts to displace fluid contaminants from within said free spaces. The material later cures in situ to form a hydrophobic seal with good electrical properties. Also disclosed herein is a method for rehabilitating waterlogged plastic insulated multiconductor communications cables of the type employed in telephone system.
    Type: Grant
    Filed: March 9, 1978
    Date of Patent: November 27, 1979
    Assignee: N L Industries, Inc.
    Inventors: Melvin Brauer, Thaddeus F. Kroplinski
  • Patent number: 4171998
    Abstract: This invention provides a method of sealing and purging contaminants from the internal free spaces of an insulated electrical device by forcing into said free spaces a low viscosity material that acts to displace fluid contaminants from within said free spaces. The material later cures in situ to form a hydrophobic seal with good electrical properties. Also disclosed herein is a method for rehabilitating waterlogged plastic insulated multiconductor communications cables of the type employed in telephone systems.
    Type: Grant
    Filed: September 30, 1976
    Date of Patent: October 23, 1979
    Assignee: N L Industries, Inc.
    Inventors: Melvin Brauer, Thaddeus F. Kroplinski
  • Patent number: 4170559
    Abstract: A hollow fiber separatory device is provided wherein a polyurethane prepolymer is cross-linked or cured with an ester of a polyhydric alcohol which contains two or three hydroxyl groups, e.g., propylene glycol monoricinoleate, and an aliphatic acid of at least 12 carbon atoms and one or more epoxy and/or hydroxy groups per molecule.
    Type: Grant
    Filed: March 31, 1977
    Date of Patent: October 9, 1979
    Assignee: N L Industries, Inc.
    Inventors: Thaddeus F. Kroplinski, Barton C. Case
  • Patent number: 4168258
    Abstract: A cured, cross-linked, mineral oil extended polyurethane which is non-spewing. The mineral oil extended polyurethane is further characterized by being grease compatible in that the tendency of the mineral oil to migrate is substantially reduced or eliminated. The mineral oil extended polyurethane is comprised of a defined polyurethane, mineral oil and coupling agent. In other aspects, the present invention relates to a process for reclaiming or sealing an insulated electrical device and to an insulated electrical device which is formed by such process.
    Type: Grant
    Filed: February 15, 1978
    Date of Patent: September 18, 1979
    Assignee: N L Industries, Inc.
    Inventors: Melvin Brauer, Thaddeus F. Kroplinski
  • Patent number: 4125545
    Abstract: Liquid 4,4'diphenylmethane diisocyanate (MDI) prepolymers have been produced which remain fluid and do not crystallize at temperatures below 40.degree. F. These prepolymers comprise the reaction product of a polyol, 4,4'diphenylmethane diisocyanate (MDI) and an aliphatic and/or cycloaliphatic diisocyanate. The polyol employed is selected from the group consisting of castor oil, polyoxypropylene glycol, polyhydric alcohol mono- and di-esters of hydroxyacids of at least 12 carbon atoms and mixtures thereof.The reaction product contains the polyol in amount from about 10% to about 40%, the 4,4'diphenylmethane diisocyanate in amount from about 50% to about 70% and the aliphatic or cycloaliphatic isocyanate in amount from about 10% to about 20%. The prepolymer should be prepared such that the NCO/OH ratio should fall within the range of about 3 to about 7.
    Type: Grant
    Filed: September 26, 1977
    Date of Patent: November 14, 1978
    Assignee: N L Industries, Inc.
    Inventors: Thaddeus F. Kroplinski, Melvin Brauer
  • Patent number: RE30321
    Abstract: This invention provides a method of sealing and purging contaminants from the internal free spaces of an insulated electrical device by forcing into said free spaces a low viscosity material that acts to displace fluid contaminants from within said free spaces. The material later cures in situ to form a hydrophobic seal with good electrical properties. Also disclosed herein is a method for rehabilitating waterlogged plastic insulated multiconductor communications cables of the type employed in telephone systems.
    Type: Grant
    Filed: April 3, 1978
    Date of Patent: July 1, 1980
    Assignee: N L Industries, Inc.
    Inventors: Melvin Brauer, Thaddeus F. Kroplinski
  • Patent number: RE31389
    Abstract: A non-wicking polyurethane casting system has been developed which comprises the reaction product obtained by admixing a polyol containing N-N-N'-N'-tetrakis (2-hydroxypropyl) ethylene diamine, (hereafter referred to as QUADROL) with an isocyanate terminated polyurethane based prepolymer. This non-wicking casting system is useful as a potting compound in biomedical applications such as dialysis and hemoultrafiltration devices and the like.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: September 20, 1983
    Assignee: CasChem, Inc.
    Inventors: Melvin Brauer, Barton C. Case, Thaddeus F. Kroplinski