Abstract: Anode half-cells for the electrocatalytic oxidation of a liquid or gaseous fuel or other reductant are disclosed, along with electrochemical cells that include such half-cells. The anode half-cells include redox mediator/heterogeneous redox catalyst pairs within an electrolyte solution that is also in contact with an electrode. The electrode is not in direct contact with the heterogeneous catalyst. The redox mediator must include at least one carbon atom and be capable of transferring or accepting electrons and protons while undergoing reduction or oxidation. In operation, the fuel or other reductant is oxidized and the redox mediator is reduced at the heterogeneous catalyst. The reduced form of the redox mediator can then migrate to the electrode, where it is converted back to its oxidized form, which can then migrate back to the heterogeneous catalyst, where the cycle is repeated.

Abstract: Anode half-cells for the electrocatalytic oxidation of a liquid or gaseous fuel or other reductant are disclosed, along with electrochemical cells that include such half-cells. The anode half-cells include redox mediator/heterogeneous redox catalyst pairs within an electrolyte solution that is also in contact with an electrode. The electrode is not in direct contact with the heterogeneous catalyst. The redox mediator must include at least one carbon atom and be capable of transferring or accepting electrons and protons while undergoing reduction or oxidation. In operation, the fuel or other reductant is oxidized and the redox mediator is reduced at the heterogeneous catalyst. The reduced form of the redox mediator can then migrate to the electrode, where it is converted back to its oxidized form, which can then migrate back to the heterogeneous catalyst, where the cycle is repeated.

Abstract: Disclosed are methods for synthesizing an ester or a carboxylic acid from an organic alcohol. To form the ester one reacts, in the presence of oxygen gas, the alcohol with methanol or ethanol. This reaction occurs in the presence of a catalyst comprising palladium and a co-catalyst comprising bismuth, tellurium, lead, cerium, titanium, zinc and/or niobium (most preferably at least bismuth and tellurium). Alternatively that catalyst can be used to generate an acid from that alcohol, when water is also added to the reaction mix.

Abstract: Disclosed are methods for synthesizing an ester or a carboxylic acid from an organic alcohol. To form the ester one reacts, in the presence of oxygen gas, the alcohol with methanol or ethanol. This reaction occurs in the presence of a catalyst comprising palladium and a co-catalyst comprising bismuth, tellurium, lead, cerium, titanium, zinc and/or niobium (most preferably at least bismuth and tellurium). Alternatively that catalyst can be used to generate an acid from that alcohol, when water is also added to the reaction mix.

Abstract: Disclosed are methods for synthesizing an ester or a carboxylic acid from an organic alcohol. To form the ester one reacts, in the presence of oxygen gas, the alcohol with methanol or ethanol. This reaction occurs in the presence of a catalyst comprising palladium and a co-catalyst comprising bismuth, tellurium, lead, cerium, titanium, zinc and/or niobium (most preferably at least bismuth and tellurium). Alternatively that catalyst can be used to generate an acid from that alcohol, when water is also added to the reaction mix.

Abstract: Disclosed are methods for synthesizing an ester or a carboxylic acid from an organic alcohol. To form the ester one reacts, in the presence of oxygen gas, the alcohol with methanol or ethanol. This reaction occurs in the presence of a catalyst comprising palladium and a co-catalyst comprising bismuth, tellurium, lead, cerium, titanium, zinc and/or niobium (most preferably at least bismuth and tellurium). Alternatively that catalyst can be used to generate an acid from that alcohol, when water is also added to the reaction mix.

Abstract: A device and a method are provided for measuring the yield stress of a fluid. The device includes a container for receiving the fluid therein and an auger having a shaft extending along an axis and a helical flange extending radially about the shaft. The auger is movable in the fluid between a first position and a second position. A sensor is operatively connected to the auger. The sensor measures a force on the auger as the auger moves from the first position to the second position. A linkage is interconnected to the sensor. The linkage translates motion to the auger.

Abstract: The present invention provides systems and methods for transferring heat using a variable composition organic heat transfer fluid that remains liquid over a wide operating temperature range useful for solar heating applications. Variable composition heat transfer fluids of the present invention comprise a miscible mixture, optionally a completely miscible mixture, of a high boiling point component selected for its beneficial high temperature physical properties, and a low freezing point component selected for its beneficial low temperature physical properties. In some embodiments, the low freezing point component is removed from the heat transfer fluid as the heat transfer fluid is heated, for example by being removed in the vapor phase, thereby selectively varying the composition and physical properties (e.g., vapor pressure, boiling point, etc.) of the heat transfer fluid as a function of temperature.

Abstract: A device and a method are provided for measuring the yield stress of a fluid. The device includes a container for receiving the fluid therein and an auger having a shaft extending along an axis and a helical flange extending radially about the shaft. The auger is movable in the fluid between a first position and a second position. A sensor is operatively connected to the auger. The sensor measures a force on the auger as the auger moves from the first position to the second position. A linkage is interconnected to the sensor. The linkage translates motion to the auger.

Abstract: The present invention provides systems and methods for transferring heat using a variable composition organic heat transfer fluid that remains liquid over a wide operating temperature range useful for solar heating applications. Variable composition heat transfer fluids of the present invention comprise a miscible mixture, optionally a completely miscible mixture, of a high boiling point component selected for its beneficial high temperature physical properties, and a low freezing point component selected for its beneficial low temperature physical properties. In some embodiments, the low freezing point component is removed from the heat transfer fluid as the heat transfer fluid is heated, for example by being removed in the vapor phase, thereby selectively varying the composition and physical properties (e.g., vapor pressure, boiling point, etc.) of the heat transfer fluid as a function of temperature.