Abstract: Multi-dimensional Rydberg fingerprint spectroscopy can be used for chemical sensing in gaseous mixtures. A pulsed laser beam having a first wavelength can be delivered to a sample using a tunable pulsed excitation laser; and a pulsed laser beam having a second wavelength can be delivered to the sample point using a tunable pulsed transition laser. The pulsed laser beam having the first wavelength and the pulsed laser beam having the second wavelength have energy sufficient to excite an electron of a sample molecule to a Rydberg state. A level of ionization or light absorption can be detected at the sample point. The level of ionization or light absorption detected and the first and second wavelengths are used to determine the presence and identity of one or more chemicals in the sample of the gaseous mixture.

Abstract: A method of treating a carbonate formation includes introducing a stimulation fluid into the carbonate formation at a pressure greater than a fracture pressure of the formation and creating openings in the carbonate formation via the stimulation fluid. Then, a fluoride salt solution, optionally including a proppant, may be introduced into the carbonate formation such that it at least partially penetrates into the openings. The fluoride salt may then be reacted with a carbonate surface in the carbonate formation to form fluorite on a surface of the formation thereby increasing a hardness of the carbonate formation.

Abstract: A method for stabilizing a wellbore includes introducing a hardening agent into the wellbore, mixing the hardening agent with a carrier fluid in the wellbore to produce a wellbore stabilizing fluid, and treating a wellbore wall of the wellbore by contacting the wellbore stabilizing fluid to a surface of the wellbore wall for at least 48 hours. A wellbore stabilizing fluid includes a hardening agent and a carrier fluid. The hardening agent is selected from one of 10 to 100 g/L of the calcium hydroxide nanocrystals, 5 to 99.9% by volume of tetraethyl orthosilicate (TEOS), and 10 to 50 g/L of zinc sulfate. A stabilized wellbore includes a wellbore having a wellbore wall treated with a wellbore stabilizing fluid comprising a hardening agent. The Young's modulus of the treated wellbore wall is at least 5% higher than a Young's modulus of a non-treated wellbore wall.

Abstract: A method is described for strengthening a carbonate formation rock within a subterranean formation. The method involves contacting the rock with a composition of Ca(OH)2 nanoparticles in an organic solvent, which results in a treated rock having a Young's modulus that is increased by at least 10%. The composition may optionally comprise a CO2 source.

Abstract: A method is described for strengthening a carbonate formation rock within a subterranean formation. The method involves contacting the rock with a composition of Ca(OH)2 nanoparticles in an organic solvent, which results in a treated rock having a Young's modulus that is increased by at least 10%. The composition may optionally comprise a CO2 source.