Abstract: A branched polyester prepared as the reaction product of a polyacid comprising at least 90 mole % isophthalic acid, including its ester and/or anhydride, and a polyol comprising a tri- or higher-functional polyol is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.

Abstract: The present invention is directed to a method for producing a dispersion comprising: (a) forming a first reaction product by reacting: (a1) at least one monomer comprising an ethylenically unsaturated double bond; (a2) at least one carboxylic acid group-containing monomer; and (a3) at least one glycidyl ester compound; wherein the molar ratio of (a2) to (a3) is substantially 1:1; (b) forming a second reaction product in the presence of the first reaction product by reacting: (b1) at least one monomer comprising an ethylenically unsaturated double bond; and (b2) at least one carboxylic acid group-containing monomer; and (c) reacting an amine compound with the second reaction product; and wherein steps (a), (b), and (c) are conducted in a substantially solvent free environment.

Abstract: The present invention is directed to a method for producing a dispersion comprising: (a) forming a first reaction product by reacting: (a1) at least one monomer comprising an ethylenically unsaturated double bond; (a2) at least one carboxylic acid group-containing monomer; and (a3) at least one glycidyl ester compound; wherein the molar ratio of (a2) to (a3) is substantially 1:1; (b) forming a second reaction product in the presence of the first reaction product by reacting: (b1) at least one monomer comprising an ethylenically unsaturated double bond; and (b2) at least one carboxylic acid group-containing monomer; and (c) reacting an amine compound with the second reaction product; and wherein steps (a), (b), and (c) are conducted in a substantially solvent free environment.

Abstract: The present invention is directed to a method for producing a dispersion comprising: (a) reacting (i) a monomer comprising an ethylenically unsaturated double bond; (ii) a carboxylic acid group-containing monomer; and (iii) a glycidyl ester compound to form a reaction product comprising a carboxylic acid group; and (b) reacting the reaction product of (a) with an amine compound; and wherein there is a molar excess of (ii) to (iii); wherein steps (a) and (b) are conducted in a substantially solvent free environment and wherein the reaction product of (b) is not further reacted with a polyester polyol.

Abstract: A waterborne film-forming composition is provided that includes a stable aqueous dispersion of a mixture of a polyester polyol and a carboxylic acid-containing acrylic polymer polyol having a weight ratio of polyester polyol to acrylic polymer polyol in the range of 10:90 to 30:70; and a polyisocyanate crosslinking agent where the equivalent ratio of hydroxyl groups to isocyanate groups is from 0.8:1 to 1.7:1. The polyol component is prepared by polymerizing a mixture of ethylenically unsaturated polymerizable monomers that includes at least one carboxylic acid group-containing monomer; at least one primary alcohol group-containing monomer; and at least one glycidyl ester of an aliphatic saturated monocarboxylic acid in the presence of at least one polyester polyol. Multi-layer composite coatings and coated substrates are also provided.

Abstract: A film-forming composition that includes a stable aqueous dispersion of a mixture of a polyester polyol and a carboxylic acid-containing acrylic polymer polyol and a crosslinking agent having functional groups reactive with hydroxyl groups. The weight ratio of polyester polyol to acrylic polymer polyol is in the range of 10:90 to 30:70. The crosslinking agent is one or more blocked isocyanates or aminoplasts. The equivalent ratio of hydroxyl groups to reactive functional groups on the crosslinking agent is from 0.8:1 to 1.7:1. The film forming composition can be used in multi-layer composite coating compositions that include a base coat layer and a substantially pigment-free topcoat deposited over at least a portion of the base coat layer, the topcoat composition including the present film-forming composition.

Abstract: A film-forming composition that includes a stable aqueous dispersion of a mixture of a polyester polyol and a carboxylic acid-containing acrylic polymer polyol and a crosslinking agent having functional groups reactive with hydroxyl groups. The weight ratio of polyester polyol to acrylic polymer polyol is in the range of 10:90 to 30:70. The crosslinking agent is one or more blocked isocyanates or aminoplasts. The equivalent ratio of hydroxyl groups to reactive functional groups on the crosslinking agent is from 0.8:1 to 1.7:1. The film forming composition can be used in multi-layer composite coating compositions that include a base coat layer and a substantially pigment-free topcoat deposited over at least a portion of the base coat layer, the topcoat composition including the present film-forming composition.

Abstract: A waterborne film-forming composition is provided that includes a stable aqueous dispersion of a mixture of a polyester polyol and a carboxylic acid-containing acrylic polymer polyol having a weight ratio of polyester polyol to acrylic polymer polyol in the range of 10:90 to 30:70; and a polyisocyanate crosslinking agent where the equivalent ratio of hydroxyl groups to isocyanate groups is from 0.8:1 to 1.7:1. The polyol component is prepared by polymerizing a mixture of ethylenically unsaturated polymerizable monomers that includes at least one carboxylic acid group-containing monomer; at least one primary alcohol group-containing monomer; and at least one glycidyl ester of an aliphatic saturated monocarboxylic acid in the presence of at least one polyester polyol. Multi-layer composite coatings and coated substrates are also provided.