Abstract: The subject invention discloses thermoplastic composition which is comprised of a blend of a thermoplastic polyolefin resin and a modified elastomer, wherein said thermoplastic polyolefin resin selected at least from the group of polyethylene, isotactic polypropylene, syndiotactic polypropylene, polypropylene impact copolymers containing about 1-7% by weight of ethylene, butene, hexene, or octene, polyolefin copolymers such as ethylene-butene, hexene, or octene, polybutene, reactor grade modified polypropylene, metallocene polypropylene, oxypolypropylene, wherein said modified elastomer is comprised of a conjugated diene selected from 1,3-butadiene and isoprene, wherein said modified elastomer is highly branched, wherein said modified elastomer is characterized by having a G′ and G″ frequency crossover of no more than 4 radians/s at 100° C.

Abstract: This invention relates to a rubber composite made from an elastomer polymerized on the surface of a silanized filler, a rubber composition containing such composite and an article such as for example a tire, which has at least one component comprised of such composition. Such reinforcement is applied by polymerizating a conjugated diene hydrocarbon in the presence of a filler silanized with an alkenyl silane. In particular a silanized reinforcing filler is pre-treated with butyl lithium or peroxide catalyst, preferably with butyl lithium, followed by polymerizing a conjugated diene hydrocarbon in the presence of such treated filler via an anionic or free radical polymerization in an organic solvent. Such pre-formed elastomer composite is also contemplated as well as a rubber composition comprised of a blend of such pre-formed composite and at least one additional elastomer. Such filler may be, for example, precipitated silica, carbon black and/or a modified carbon black.

Abstract: The subject invention discloses a thermoplastic composition which is comprised of a blend of a thermoplastic polyolefin resin and a modified elastomer, wherein said thermoplastic polyolefin resin selected at least from the group of polyethylene, isotactic polypropylene, syndiotactic polypropylene, polypropylene impact copolymers containing about 1-7% by weight of ethylene, butene, hexene, or octene, polyolefin copolymers such as ethylene-butene, hexene, or octene, polybutene, reactor grade modified polypropylene, metallocene polypropylene, oxypolypropylene, wherein said modified elastomer is comprised of a conjugated diene selected from 1,3-butadiene and isoprene, wherein said modified elastomer is highly branched, wherein said modified elastomer is characterized by having a G′ and G″ frequency crossover of no more than 4 radians/s at 100° C.

Abstract: The invention relates to the preparation of a silica reinforced rubber composition where alkoxysilane and/or sulfur cure reactions within the elastomer host are controlled by the use of a selected amino acid, or amino acid-containing protein based, activator. The invention also relates to such composite and to a tire having at least one component of such composite.

Abstract: The present invention discloses a thermoplastic elastomer composition which is comprised of (a) a thermoplastic resin selected from the group consisting of polyolefin resin, polyphenylene ether, and polystyrene, wherein the thermoplastic resin is present at a level of up to 60 parts by weight, (b) 5 to 90 parts by weight of a rubbery elastomer that is comprised of repeat units that are derived from a conjugated diene monomer selected from 1,3-butadiene and isoprene, wherein the repeat units in the rubbery polymer are distributed through the rubbery polymer in an essentially random manner, wherein the rubbery polymer is a solution polymer, and is optionally, at least partially crosslinked, (c) 5 to 90 parts by weight of a highly saturated elastomer selected from the group consisting of styrene-ethylene butylene-styrene, styrene-ethylene propylene-styrene, hydrogenated polybutadiene, hydrogenated polyisoprene, hydrogenated styrene-isoprene random copolymers, hydrogenated styrene-isoprene block copolymers, hydro

Abstract: This invention relates to preparation of a rubber composition by pre-mixing at least one functionalized carbon black with an organic solvent solution or aqueous emulsion of at least one host elastomer. Functionalized carbon blacks for the purposes of this invention preferably contain a functional moiety on their surface to aid in promoting covalent bonds between the functionalized carbon black and said host polymer. The invention also contemplates the use of such rubber composition, or blend of such rubber composition with at least one additional elastomer and/or rubber compounding ingredient, as a component of an article of manufacture. Such article of manufacture may be, for example, a tire. Such article may also be an industrial product such as, for example, a hose or belt such as a conveyor belt or power transmission belt.

Abstract: There is disclosed a pneumatic tire having a rubberized component comprising:

Abstract: A rubber composition comprised of an elastomer(s) reinforced with a particulate carbon black composite, and a coupling agent. Said carbon black composite contains integral silica on the surface thereof, wherein said carbon black composite is prepared by co-precipitating carbon black and silica from a dispersion of carbon black in sodium silicate to provide integral silica domains on the outer surface of the carbon black. Said carbon black composite is further functionalized by reacting it with a trialkoxy silane. A tire having a component comprised of such rubber composition, such as, for example, a tire tread is contemplated.

Abstract: The invention relates to the preparation of a silica reinforced rubber composition where alkoxysilane and/or sulfur cure reactions within the elastomer host are controlled by the use of a selected amino acid, or amino acid-containing protein based, activator.

Abstract: This invention relates to a carbon black modified by a two step process in which carbon black is initially treated with functional monomers by an electropolymerization process to form a functionalized carbon black having an initial polymer attached to, of grafted to, the carbon black following which

Abstract: The invention relates to an elastomer/reinforcing filler composite in which said elastomer contains a dispersion therein of said reinforcing filler wherein said composite is prepared by forming said filler reinforcement in situ within the elastomer host. Such in-situ formation of reinforcement filler is created by a condensation reaction of a filler precursor within a solvent solution of a diene hydrocarbon based elastomer and with the aid of a phase transfer agent and a condensation reaction promoter. The invention further relates to a tire having at least one component comprised of the resulting elastomer/filler composite. The invention includes a rubber composition of at least two elastomers wherein one of said elastomers is a said pre-formed composite of said elastomer/filler reinforcement. A tire having a component of such rubber composition, particularly a tire tread, is specifically contemplated.

Abstract: A pneumatic tire having a tread comprised of (a) a diene-based elastomer containing olefinic unsaturation and (b) from 1 to 150 phr of a metal oxide aerogel.

Abstract: This invention relates to a rubber composite made from an elastomer polymerized on the surface of a silanized filler, a rubber composition containing such composite and an article such as for example a tire, which has at least one component comprised of such composition. Such reinforcement is applied by polymerizating a conjugated diene hydrocarbon in the presence of a filler silanized with an alkenyl silane. In particular a silanized reinforcing filler is pre-treated with butyl lithium or peroxide catalyst, preferably with butyl lithium, followed by polymerizing a conjugated diene hydrocarbon in the presence of such treated filler via an anionic or free radical polymerization in an organic solvent. Such pre-formed elastomer composite is also contemplated as well as a rubber composition comprised of a blend of such pre-formed composite and at least one additional elastomer. Such filler may be, for example, precipitated silica, carbon black and/or a modified carbon black.

Abstract: This invention relates to a carbon black modified by a two step process in which carbon black is initially treated with functional monomers by an electropolymerization process to form a functionalized carbon black having an initial polymer attached to, of grafted to, the carbon black following which (A) at least one diene monomer, or (B) living anionic catalysis prepared polymer, is introduced to the functionalized carbon black to continue the polymerization, starting from a living end of the initially formed polymer, and thereby form an extended diene-based polymer. By the addition of the diene monomer or the live anionic polymer to form the associated extended diene-based polymer, it is contemplated that the modified carbon black is rendered more compatible with diene-based elastomers. Such modified carbon black may be used, for example, as reinforcement for component(s) of various articles of manufacture, including tires.

Abstract: The present invention relates to a rubber composition comprising (A) an elastomer containing olefinic unsaturation and (B) 35 to 110 phr of silica filler, wherein said silica filler is comprised of (i) 10 to 100 phr of a first silica having a pore size distribution maximum of the aggregates in the first silica ranging from greater than 55 to 400 nm as determined by mercury porosimetry and an average specific surface area ranging from 60 to 135 m2/g as determined by N2 adsorption; and (ii) 10 to 100 phr of a second silica having a pore size distribution maximum of the aggregates in the second silica ranging from 5 to 50 nm as determined by mercury porosimetry and an average specific surface area ranging from 140 to 250 m2/g as determined by N2 adsorption.

Abstract: This invention relates to preparation of a rubber composition by pre-mixing at least one functionalized carbon black with an organic solvent solution or aqueous emulsion of at least one host elastomer. Functionalized carbon blacks for the purposes of this invention preferably contain a functional moiety on their surface to aid in promoting covalent bonds between the functionalized carbon black and said host polymer. The invention also contemplates the use of such rubber composition, or blend of such rubber composition with at least one additional elastomer and/or rubber compounding ingredient, as a component of an article of manufacture. Such article of manufacture may be, for example, a tire. Such article may also be an industrial product such as, for example, a hose or belt such as a conveyor belt or power transmission belt.

Abstract: The present invention relates to siloxy compounds of the formulae wherein R1, R2 and R3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; R5 is selected from the group consisting of alkyl groups having from 1 to 15 carbon atoms, aryl and alkyl substituted aryl groups having 6 to 10 carbon atoms; x is 3 when M is Al and x is 4 when M is selected from the group consisting of C, Ti, Si and Zr.

Abstract: The invention relates to the preparation of a rubber composition containing starch/plasticizer composite reinforcement, together with at least one additional reinforcing filler, through the utilization of a combination of an organosilane disulfide compound mixed with a rubber composition in a preparatory, non-productive, mixing stage(s) followed by adding an organosilane polysulfide compound in a subsequent, productive, mixing stage. The invention further relates to the resulting rubber composition and use thereof in rubber products, including tires.

Abstract: There is disclosed a rubber composition particularly suited for use in tires. The rubber composition is composed of 100 parts by weight of at least one rubber containing olefinic unsaturation; and from 1 to 150 parts per 100 parts by weight of rubber, of a silica having predispersed on the surface of the silica a liquid epoxidized butadiene polymer having a number average molecular weight of from 500 to 10,000.

Abstract: The present invention relates to siloxy compounds of the formula 1