Abstract: An electrochemical cell of the lithium/sulfur type comprising: a) a cathode comprising: i) microporous carbon in the form of particles, the particle size distribution being characterized by a median volume diameter Dv50 of the particles which is greater than or equal to 1 ?m and less than or equal to 5 ?m; ii) sulfur having an oxidation degree in the range of 0 to ?2 in the pores of the microporous carbon; b) an electrolyte comprising a solvent, said solvent comprising at least one fluorinated carbonate; c) an anode composed of lithium metal or of a lithium metal alloy. The electrochemical cell exhibits an improved specific gravimetry and an improved life cycle.

Abstract: A lithium/sulfur electrochemical element (1) comprising: a cathode (2) comprising: i) carbon having a porous structure (5) comprising pores with a mean diameter less than or equal to 6 nm; ii) sulfur having a degree of oxidation between 0 and ?2 in the pores of the carbon; b) an electrolyte comprising: i) at least one organic solvent which is a carbonate; ii) one or more salts, at least one salt being lithium bis(fluorosulfonyl)imide; c) an anode (4) comprising lithium metal or a metallic alloy of lithium. Such an element provides increased safety of use because it limits the quantity of hydrogen sulfide that can be emitted in the event of an electrolyte leak or in the event of exposure of an electrode of the element to water.

Abstract: An electrochemical cell of the lithium/sulfur type comprising: a) a cathode comprising: i) microporous carbon in the form of particles, the particle size distribution being characterized by a median volume diameter Dv50 of the particles which is greater than or equal to 1 ?m and less than or equal to 5 ?m; ii) sulfur having an oxidation degree in the range of 0 to ?2 in the pores of the microporous carbon; b) an electrolyte comprising a solvent, said solvent comprising at least one fluorinated carbonate; c) an anode composed of lithium metal or of a lithium metal alloy. The electrochemical cell exhibits an improved specific gravimetry and an improved life cycle.

Abstract: A lithium/sulfur electrochemical element (1) comprising: a cathode (2) comprising: i) carbon having a porous structure (5) comprising pores with a mean diameter less than or equal to 6 nm; ii) sulfur having a degree of oxidation between 0 and ?2 in the pores of the carbon; b) an electrolyte comprising: i) at least one organic solvent which is a carbonate; ii) one or more salts, at least one salt being lithium bis(fluorosulfonyl)imide; c) an anode (4) comprising lithium metal or a metallic alloy of lithium. Such an element provides increased safety of use because it limits the quantity of hydrogen sulfide that can be emitted in the event of an electrolyte leak or in the event of exposure of an electrode of the element to water.

Abstract: A compound of formula Li4+xMnM1aM2bOc wherein: M1 is selected from the group consisting in Ni, Mn, Co, Fe and a mixture thereof; M2 is selected from the group consisting in Si, Ti, Mo, B, Al and a mixture thereof; with: ?1.2?x?3; 0<a?2.5; 0?b?1.5; 4.3?c?10; and c=4+a+n·b+x/2 wherein n=2 when M2 is selected from the group consisting in Si, Ti, Mo or a mixture thereof; and n=1.5 when M2 is selected from the group consisting in B, Al or a mixture thereof; and n=0 if b=0.

Abstract: A compound of formula Li4+xMnM1aM2bOc wherein: M1 is selected from the group consisting in Ni, Mn, Co, Fe and a mixture thereof; M2 is selected from the group consisting in Si, Ti, Mo, B, Al and a mixture thereof; with: ?1.2?x?3; 0<a?2.5; 0?b?1.5; 4.3?c?10; and c=4+a+n·b+x/2 wherein n=2 when M2 is selected from the group consisting in Si, Ti, Mo or a mixture thereof; and n=1.5 when M2 is selected from the group consisting in B, Al or a mixture thereof; and n=0 if b=0.

Abstract: An alloy comprising tin, silicon and carbon, and containing a crystalline M-Sn phase, M being an inert metal. An alloy comprising tin and silicon, comprising: a) a nanocrystalline phase containing at least 50 at. % of the element silicon Si°; b) a nanocrystalline phase containing a compound based on tin; c) a nanocrystalline phase constituted by the element tin Sn°. A manufacturing process for this alloy.

Abstract: A compound of formula Lia+y(M1(1?t)Mot)2M2b(O1?xF2x)c wherein: M1 is selected from the group consisting in Ni, Mn, Co, Fe, V or a mixture thereof; M2 is selected from the group consisting in B, Al, Si, P, Ti, Mo; with 4?a?6; 0<b?1.8; 3.8?c?14; 0?x<1; ?0.5?y?0.5; 0?t?0.9; b/a<0.45; the coefficient c satisfying one of the following relationships: c=4+y/2+z+2t+1.5b if M2 is selected from B and Al; c=4+y/2+z+2t+2b if M2 is selected from Si, Ti and Mo; c=4+y/2+z+2t+2.5b if M2 is P; with z=0 if M1 is selected from Ni, Mn, Co, Fe and z=1 if M1 is V.

Abstract: An alloy comprising tin, silicon and carbon, and containing a crystalline M-Sn phase, M being an inert metal. An alloy comprising tin and silicon, comprising: a) a nanocrystalline phase containing at least 50 at. % of the element silicon Si°; b) a nanocrystalline phase containing a compound based on tin; c) a nanocrystalline phase constituted by the element tin Sn°. A manufacturing process for this alloy.

Abstract: The invention relates to an alkaline electrochemical cell of improved lifetime, including at least one compound based on barium or strontium, said compound being present in the cell with the exception of the cathode. The invention also provides a method of fabricating such a cell.

Abstract: An electrochemically active material consisting of a CaCu5 structure single-phase hydridable alloy with the formula MmNiaMnbAlcCodCre in which Mm is a mischmetal containing at least 50 wt % La, where: 5.10≦(a+b+c+d+e), d≦0.55, and 0.03≦e≦0.1.

Abstract: An electrochemically active material consisting of a CaCu5 structure single-phase hydridable alloy with the formula MmNiaMKnbAlcCodCre in which Mm is a mischmetal containing at least 50 wt % La, where: 5.10≦(a+b+c+d+e), d≦0.55, and 0.03≦e≦0.1.