Patents by Inventor Thomas A. Rosiek
Thomas A. Rosiek has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6824936Abstract: The present invention relates to an imaged element comprising at least one imaged layer comprising at least one yellow dye and a support, wherein said support comprises at least one face side resin layer comprising a material capable of improving the yellow dark stability of said imaged element, wherein said materials has the formula:Type: GrantFiled: August 5, 2003Date of Patent: November 30, 2004Assignee: Eastman Kodak CompanyInventors: Thomas A. Rosiek, Elizabeth K. Priebe
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Patent number: 6555304Abstract: Disclosed is a silver halide direct view multicolor photographic element comprising a red record containing (1) a red light sensitized silver halide emulsion, (2) a cyan dye-forming NB first coupler, and (3) a second coupler selected from (a) a magenta dye forming coupler in an amount of 2-30 mole % of the total coupler in the red record and (b) a cyan dye-forming coupler having a greater absorption in the green spectra than the first coupler in an amount sufficient to provide a Status A green density in the range of 0.27 to 0.40 using a red light separation exposure at a Status A red density of 1.0. Such an element exhibits improved flesh tone reproduction and good dye dark stability.Type: GrantFiled: January 18, 2002Date of Patent: April 29, 2003Assignee: Eastman Kodak CompanyInventors: Walter H. Isaac, Vincent J. Flow, James S. Honan, Jeffrey C. Smitley, Patrick W. Webber, Glenn M. Brown, Cynthia A. Fitzgerald, Jess B. Hendricks, Thomas A. Rosiek, John H. Harder, Carolyn H. Ellinger
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Patent number: 6420103Abstract: Silver halide light sensitive photographic elements are disclosed comprising a support bearing at least one yellow image forming hydrophilic colloid layer comprising a yellow dye-forming coupler and a trialkyl citrate coupler solvent of the formula C3H4(OH)(CO2R)3, where each R independently represents an alkyl group and the total number of carbon atoms for the three R groups combined is greater than 6. The combination of such citrate ester solvents with yellow dye forming couplers in photographic elements leads to both good reactivity and good image-dye light stability. The advantages of the invention are particularly useful for photographic color paper elements on reflective supports.Type: GrantFiled: March 10, 1999Date of Patent: July 16, 2002Assignee: Eastman Kodak CompanyInventors: James S. Honan, Thomas A. Rosiek, Brian Thomas, David D. Miller
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Patent number: 6413707Abstract: A photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide based yellow dye forming coupler and a compound of the following Formula I: wherein R1, R2 and R3 are each independently aromatic, cyclic, linear, or branched chained hydrocarbon groups. The invention provides photographic elements which exhibit exceptional yellow dye light stability, and which retain desirable properties derived from the use of acetanilide based yellow dye-forming couplers, particularly when used in combination with substituted phenolic and/or thiomorpholine dioxide stabilizers. In addition to stabilizing properties, compounds of Formula I have organic solvent properties, and accordingly may be advantageously used partly or totally in place of conventional high boiling permanent and/or auxiliary organic coupler solvents to disperse the acetanilide-based couplers.Type: GrantFiled: August 30, 2001Date of Patent: July 2, 2002Assignee: Eastman Kodak CompanyInventors: Kurt M. Schroeder, James S. Honan, Brian Thomas, Thomas A. Rosiek, Paul D. Yacobucci
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Patent number: 6312881Abstract: In accordance with one embodiment of the invention, a photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide-based yellow dye forming coupler and a stabilizer compound of the formula S-I: wherein R0 represents an aryl or heterocyclic group; Ra is H or a substituent group; L represents an alkylene linking group and p represents 0 or 1; and Rb is a substituent group, provided that substituent groups represented by Ra and Rb may be joined to form a ring. The presence of substituted amine compounds of formula S-I improves the efficiency of dye formation reaction for acetanilide-based couplers. When used in combination with known bis-phenolic stabilizers, substantial improvements in the light stability of the image dyes can be also be obtained.Type: GrantFiled: January 14, 2000Date of Patent: November 6, 2001Assignee: Eastman Kodak CompanyInventors: Danuta Gibson, James S. Honan, Llewellyn J. Leyshon, Thomas A. Rosiek, Brian Thomas
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Patent number: 6261755Abstract: The invention provides a photographic element comprising at least one light-sensitive silver halide emulsion layer having associated therewith: (A) a phenolic cyan dye-forming narrow bandwidth “NB coupler”; (B) a phenolic cyan dye-forming coupler of formula (II): wherein: R3 is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R4 is an unsubstituted or substituted alkyl group; R5 is hydrogen, halogen or an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; and Z is a hydrogen atom or a group which can be split off by the reaction of the coupler with an oxidized color-developing agent; and (C) a stabilizer of formula (III) wherein: eacType: GrantFiled: February 28, 2000Date of Patent: July 17, 2001Assignee: Eastman Kodak CompanyInventors: Danuta Gibson, James S. Honan, Thomas A. Rosiek
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Patent number: 6110658Abstract: Disclosed is a photographic element having a reduced rate of crystal formation comprising a silver halide emulsion layer having associated therewith:(a) a phenolic cyan dye-forming "NB coupler";(b) a first high boiling solvent having Formula (IV):G--C--OO--R.sup.1 (IV)wherein:R.sup.1 is an alkyl or aryl groups; andG is an alkyl (including cycloalkyl and aralkyl) containing linking group; and(c) one or more second high boiling solvents selected from phosphates, phosphonates, phosphine oxides, sulfoxides, and carbonamides, said second high boiling solvent being present in amounts (by weight) sufficient to reduce crystal formation in a dispersion of the coupler compared to a dispersion of the same coupler in a dispersion where the second solvent is replaced with a like amount of the first solvent.Type: GrantFiled: March 10, 1999Date of Patent: August 29, 2000Assignee: Eastman Kodak CompanyInventors: James S. Honan, Raymond P. Scaringe, Thomas A. Rosiek
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Patent number: 5879870Abstract: Improvements in post process Dmin are provided in a photographic element that has a preferred coupler, hardener, and permanent solvent. The coupler of the element comprises between about 20 and 40 percent by weight of the coupler and oil phase components and the element further comprises chromanol stabilizer.Type: GrantFiled: October 21, 1996Date of Patent: March 9, 1999Assignee: Eastman Kodak CompanyInventors: Thomas A. Rosiek, Alberto M. Martinez, Walter H. Isaac
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Patent number: 5851748Abstract: The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a yellow dye-forming coupler having the formula: ##STR1## wherein X, Y, Z, W are independently selected from the group consisting of H, alkyl, aryl, halogen, alkoxy and aryloxy groups, provided that X and W may join to form a saturated ring;Each A is selected from the group consisting of halogen, alkoxy and aryloxy groups;m is an integer from 1 to 3;each B is independently selected from the group consisting of --C(O)OR.sub.2 and --NHSO.sub.2 R.sub.3 wherein R.sub.2 and R.sub.3 are independently selected from the group consisting of alkyl and aryl groups;n is an integer from 1 to 3; andR.sub.1 is a substituent group.Type: GrantFiled: December 12, 1996Date of Patent: December 22, 1998Assignee: Eastman Kodak CompanyInventors: Ping-Wah Tang, Stanley W. Cowan, David J. Decker, Thomas A. Rosiek
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Patent number: 5594047Abstract: Loaded latex dispersions of hydrophobic photographically useful compounds with a wide variety of polymer latices are prepared by preparing an oil phase solution of the hydrophobic compound or compounds, preferably essentially free of water-miscible or volatile solvent, combining the oil solution with one or more aqueous solutions, at least one of which contains a polymer latex, and mixing the combination of oil solution, aqueous solution and latex under high shear or turbulence sufficient to cause loading of the photographically useful compound into the dispersed polymer latex wherein the pH of the mixture does not need to be significantly changed.Type: GrantFiled: February 17, 1995Date of Patent: January 14, 1997Assignee: Eastman Kodak CompanyInventors: Ralph B. Nielsen, Thomas A. Rosiek, David F. Bates, James S. Honan, Hwei-Ling Yau
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Patent number: 5591568Abstract: This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the rheology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.Type: GrantFiled: September 6, 1994Date of Patent: January 7, 1997Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, James L. Edwards, Danuta Gibson, Thomas A. Rosiek, Brian Thomas, Vincent J. Flow, III
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Patent number: 5558980Abstract: Photographic elements comprising loaded latex compositions are prepared by (a) combining under conditions of low or moderate shear, in the presence of surfactant, and in the substantial absence of water-miscible or volatile organic solvents, a liquid organic composition comprising at least one photographically useful compound with an aqueous polymer latex, (b) holding the combination resulting from (a) in a liquid state for sufficient time for substantial loading of the organic coposition into the polymer latex to occur, and (c) coating the loaded latex resulting from (b) on a support.Type: GrantFiled: February 17, 1995Date of Patent: September 24, 1996Assignee: Eastman Kodak CompanyInventors: Ralph B. Nielson, Thomas A. Rosiek, James S. Honan
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Patent number: 5491052Abstract: It has been discovered that when polyalkylene oxide compounds or block polymeric or block oligomeric surface active compounds comprising at least a polyoxypropylene (POP) block and a polyoxyethylene (POE) block are added to conventional dispersions of yellow couplers (that is dispersions in which the dispersed particles have a particle size of 0.1 to 0.6 .mu.m), such dispersions in a coated silver halide photographic element produce substantially higher dye yield compared to the conventional dispersion without any additive. Further, the yellow dye formed from such dispersions containing the addenda of this invention are substantially more light stable compared to dispersions that does not contain such addenda.The invention is carried out just by adding required amounts of the said polyoxyethylene (POE)--polyoxypropylene (POP) compound to a preformed milled coupler dispersion prior to coating the photographic element.Type: GrantFiled: June 7, 1995Date of Patent: February 13, 1996Assignee: Eastman Kodak CompanyInventors: James P. Van Meter, Pranab Bagchi, Brian Thomas, Thomas A. Rosiek
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Patent number: 5426021Abstract: A photographic element containing a silver halide emulsion layer having associated therewith, a dye-forming coupler and a dye stabilizer which has a melting point of less than 150.degree. C. (and preferably less than 100.degree. C.) and is of the formula: ##STR1## wherein R, m, q, X, Y, r, and (R.sup.7).sub.n are defined in the specification.The element particularly contains a coupler which forms a yellow dye upon reaction with oxidized developer. A method of making stabilizers of the above type using particular solvents and a non-aqueous workup, is also provided.Type: GrantFiled: July 2, 1993Date of Patent: June 20, 1995Inventors: Sundaram Krishnamurthy, Rakesh Jain, Paul P. Spara, Thomas A. Rosiek
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Patent number: 5358831Abstract: This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the theology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.Type: GrantFiled: December 13, 1990Date of Patent: October 25, 1994Assignee: Eastman Kodak companyInventors: Pranab Bagchi, James L. Edwards, Danuta Gibson, Thomas A. Rosiek, Brian Thomas, Vincent J. Flow, III
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Patent number: 5262292Abstract: Pyrazolone magenta dye-forming couplers having a particular arylthio coupling-off group enhance the photographic properties and improve the manufacturing and handling characteristics of materials and processes employing such couplers. The coupler contains an N-phenyl group, a 3-anilino group and a 4-(arylthio) coupling off group containing a particular aryloxymethylacylamino group as an ortho substituent. A broad range of improvements are realized including stability, reactivity, hue, and dye density in addition to simplified and safer manufacture.Type: GrantFiled: April 23, 1992Date of Patent: November 16, 1993Assignee: Eastman Kodak CompanyInventors: Sundaram Krishnamurthy, Thomas A. Rosiek, Vincent J. Flow, David S. Bailey, David J. Giacherio, John L. Pawlak, Stephen P. Singer