Abstract: A method for evaluating the pH of an aqueous solution by utilizing the optical properties of a pH sensing material comprised of plurality of optically active nanoparticles dispersed in matrix material. The optically active nanoparticles have an electronic conductivity greater than about 10?1 S/cm and generally have an average nanoparticle diameter of less that about 500 nanometers, and the matrix material is a material which experiences a change in surface charge density over a pH range from 2.0 to 12.0 of at least 1%. The method comprises contacting the pH sensing material and the aqueous solution, illuminating the pH sensing material, and monitoring an optical signal generated through comparison of incident light and exiting light to determine the optical transmission, absorption, reflection, and/or scattering of the pH sensitive material. The optical signal of the pH sensitive material varies in response to the pH of the aqueous solution.

Abstract: A method of monitoring operation of a reactor system includes causing a chemical reaction to occur within an assembly of the reactor system, and measuring a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly using a sensor system structured to implement distributed sensing. The sensor system includes an optical fiber sensing member provided at least partially within the assembly, wherein the optical fiber sensing member comprises a functionalized optical fiber based sensor device structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.

Abstract: A method of monitoring operation of a reactor system includes causing a chemical reaction to occur within an assembly of the reactor system, and measuring a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly using a sensor system structured to implement distributed sensing. The sensor system includes an optical fiber sensing member provided at least partially within the assembly, wherein the optical fiber sensing member comprises a functionalized optical fiber based sensor device structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.

Abstract: The disclosure relates to a method for H2 sensing in a gas stream utilizing a hydrogen sensing material. The hydrogen sensing material is comprised of Pd-based or Pt-based nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10?7 S/cm at a temperature of 700° C. Exemplary inert matrix materials include SiO2, Al2O3, and Si3N4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. Additional exemplary matrix materials consist of zeolitic and zeolite-derivative structures which are microporous and/or nanoporous such as the alumino-silicates and the dealuminated zeolite NaA structures.

Abstract: A method of monitoring operation of a reactor system includes causing a chemical reaction to occur within an assembly of the reactor system, and measuring a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly using a sensor system structured to implement distributed sensing. The sensor system includes an optical fiber sensing member provided at least partially within the assembly, wherein the optical fiber sensing member comprises a functionalized optical fiber based sensor device structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.

Abstract: The disclosure relates to a plasmon resonance-based method for H2 sensing in a gas stream utilizing a hydrogen sensing material. The hydrogen sensing material is comprises Pd-based or Pt-based nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10?7 S/cm at a temperature of 700° C. Exemplary inert matrix materials include SiO2, Al2O3, and Si3N4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. The hydrogen sensing material utilized in the method of this disclosure may be prepared using means known in the art for the production of nanoparticles dispersed within a supporting matrix including sol-gel based wet chemistry techniques, impregnation techniques, implantation techniques, sputtering techniques, and others.

Abstract: The disclosure relates to an optical method for temperature sensing utilizing a temperature sensing material. In an embodiment the gas stream, liquid, or solid has a temperature greater than about 500° C. The temperature sensing material is comprised of metallic nanoparticles dispersed in a dielectric matrix. The metallic nanoparticles have an electronic conductivity greater than approximately 10?1 S/cm at the temperature of the temperature sensing material. The dielectric matrix has an electronic conductivity at least two orders of magnitude less than the dispersed metallic nanoparticles at the temperature of the temperature sensing material. In some embodiments, the chemical composition of a gas stream or liquid is simultaneously monitored by optical signal shifts through multiple or broadband wavelength interrogation approaches.

Abstract: The disclosure relates to a plasmon resonance-based method for gas sensing in a gas stream utilizing a gas sensing material. In an embodiment the gas stream has a temperature greater than about 500° C. The gas sensing material is comprised of gold nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10?7 S/cm at a temperature of 700° C. Exemplary inert matrix materials include SiO2, Al2O3, and Si3N4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. Changes in the chemical composition of the gas stream are detected by changes in the plasmon resonance peak. The method disclosed offers significant advantage over active and reducible matrix materials typically utilized, such as yttria-stabilized zirconia (YSZ) or TiO2.

Abstract: The disclosure relates to a plasmon resonance-based method for H2 sensing in a gas stream at temperatures greater than about 500° C. utilizing a hydrogen sensing material. The hydrogen sensing material is comprised of gold nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10?7 S/cm at a temperature of 700° C. Exemplary inert matrix materials include SiO2, Al2O3, and Si3N4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. At high temperatures, blue shift of the plasmon resonance optical absorption peak indicates the presence of H2. The method disclosed offers significant advantage over active and reducible matrix materials typically utilized, such as yttria-stabilized zirconia (YSZ) or TiO2.

Abstract: The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

Abstract: An isometric exercise apparatus includes a platform and a strap/cable/pulley system. A load cell or strain gauge type sensor is positioned beneath the platform and is attached to and stressed by the strap/cable/pulley system when a user performs an isometric exercise function. An LED readout module is electrically connected to the cell and is programmed to display the stress on the cell as pounds or kilograms of lifted weight.

Abstract: An isometric exercise apparatus includes a platform and a strap/cable/pulley system. A load cell or strain gauge type sensor is positioned beneath the platform and is attached to and stressed by the strap/cable/pulley system when a user performs an isometric exercise function. An LED readout module is electrically connected to the cell and is programmed to display the stress on the cell as pounds or kilograms of lifted weight.

Abstract: A collection game apparatus includes a random selection assembly which includes a base portion, a distributor pipe assembly supported by the base portion, and a funnel-shaped perimeter wall supported by a top portion of the distributor pipe assembly. A plurality of objects are provided to be collected, and the objects are grouped into color coded sets. The objects to be collected are randomly distributed by the distributor pipe assembly of the random selection assembly. A plurality of containers are provided for storing and carrying objects that are collected. Preferably, the random selection assembly and the objects to be collected, which are balls, float in water. The base portion of the random selection assembly is inflatable. The distributor pipe assembly includes a pipe-support body supported by the base portion. The pipe-support body includes a riser portion supported by the base portion and a baffle plate supported by a top part of the riser portion.

Abstract: A portable exercise device includes a base having a flat central section on which the user may either stand, sit or lie and a strap housing on each side of the central section. The base comprises two sections joined by mating extrusions such that the base may be disassembled to provide greater portability of the exercise device. One of the strap housings contains a supply/takeup reel onto which left and right straps are wound and from which they are unwound during a workout by the user. The right strap is routed underneath the base and around an idler pulley contained within the other housing. Each of the straps exits its respective housing and is connected to one end of an exercise bar. A rewind spring, a one-way clutch, and a band brake are coupled to the supply/takeup reel to adjust the force required of the user to pull the straps during a workout and to rewind the straps when the user releases the bar.

Abstract: A coal-water mixture (CWM) burner includes a conically shaped rotating cup into which fuel comprised of coal particles suspended in a slurry is introduced via a first, elongated inner tube coupled to a narrow first end portion of the cup. A second, elongated outer tube is coaxially positioned about the first tube and delivers steam to the narrow first end of the cup. The fuel delivery end of the inner first tube is provided with a helical slot on its lateral surface for directing the CWM onto the inner surface of the rotating cup in the form of a uniform, thin sheet which, under the influence of the cup's centrifugal force, flows toward a second, open, expanded end portion of the rotating cup positioned immediately adjacent to a combustion chamber. The steam delivered to the rotating cup wets its inner surface and inhibits the coal within the CWM from adhering to the rotating cup.

Abstract: A blue flame oil burner is provided wherein an oil atomizing nozzle produces sprayed oil droplets as a symetrical hollow cone having an included angle for the outside edge of the oil spray, when the oil is sprayed in still air, in the range 60.degree. to 80.degree., an air swirler with an air pre-swirler both have blades with a helix angle in the range 50.degree. to 65.degree., with the blades of the air swirler adjacent the spraying end of the atomizing nozzle inclined in the direction of the hollow cone at an angle in the range 20.degree. to 55.degree., and a supply tube for delivering air through the air pre-swirler to the air swirler. The air flows along the supply tube and is preswirled in the pre-swirler and then finally swirled in the air swirler so that sprayed oil droplets in the hollow cone are carried by the swirling air, which diffuses with them in such a manner that the oil droplets are evaporated prior to combustion and:I.