Abstract: Isopipes (13) for making glass sheets using a fusion process are provided. The isopipes are made from alumina materials which have low levels of the elements of group IVB of the periodic chart, i.e., Ti, Zr, and Hf, as well as low levels of Sn. In this way, the alumina isopipes can be used with glasses that contain tin (e.g., as a fining agent or as the result of the use of tin electrodes for electrical heating of molten glass) without generating unacceptable levels of tin-containing defects in the glass sheets, specifically, at the sheets' fusion lines. The alumina isopipes disclosed herein are especially beneficial when used with tin-containing glasses that exhibit low tin solubility, e.g., glasses that have (RO+R2O)/Al2O3 ratios between 0.9 and 1.1, where, in mole percent on an oxide basis, (RO+R2O) is the sum of the concentrations of the glass' alkaline earth and alkali metal oxides and Al2O3 is the glass' alumina concentration.

Abstract: Isopipes (13) for making a glass or a glass-ceramic using a fusion process are provided. The isopipes are made from an alumina material which has a higher static fatigue than existing alumina materials intended for use as isopipes. In particular, the alumina materials have times-to-failure (static fatigues) of greater than one hour at 1200° C. at an applied stress of 10,000 psi. These high levels of static fatigue allow alumina isopipes to replace zircon isopipes in the manufacture of high performance glass sheets by the fusion process, including glass sheets which are incompatible with zircon isopipes but compatible with alumina isopipes, e.g., chip and scratch resistant glass sheets which have high alkali contents.

Abstract: Isopipes (13) for making a glass or a glass-ceramic using a fusion process are provided. The isopipes are made from an alumina material which has a higher static fatigue than existing alumina materials intended for use as isopipes. In particular, the alumina materials have times-to-failure (static fatigues) of greater than one hour at 1200° C. at an applied stress of 10,000 psi. These high levels of static fatigue allow alumina isopipes to replace zircon isopipes in the manufacture of high performance glass sheets by the fusion process, including glass sheets which are incompatible with zircon isopipes but compatible with alumina isopipes, e.g., chip and scratch resistant glass sheets which have high alkali contents.

Abstract: Isopipes (13) for making glass sheets using a fusion process are provided. The isopipes are made from alumina materials which have low levels of the elements of group IVB of the periodic chart, i.e., Ti, Zr, and Hf, as well as low levels of Sn. In this way, the alumina isopipes can be used with glasses that contain tin (e.g., as a fining agent or as the result of the use of tin electrodes for electrical heating of molten glass) without generating unacceptable levels of tin-containing defects in the glass sheets, specifically, at the sheets' fusion lines. The alumina isopipes disclosed herein are especially beneficial when used with tin-containing glasses that exhibit low tin solubility, e.g., glasses that have (RO+R2O)/Al2O3 ratios between 0.9 and 1.1, where, in mole percent on an oxide basis, (RO+R2O) is the sum of the concentrations of the glass' alkaline earth and alkali metal oxides and Al2O3 is the glass' alumina concentration.

Abstract: According to one aspect of the present invention the fuel cell device includes an electrolyte sheet. The electrolyte sheet has a substantially non-porous body of a varied thickness, a relatively smooth surface and a more textured surface with multiple indentations therein, wherein the thickest part of the electrolyte sheet is at least 0.5 micrometers greater than the thinnest part of said electrolyte sheet. The side of the electrolyte sheet with a relatively smooth surface is subjected to the predominately tensile force and the other, more textured surface subjected to predominately compressive force. According to one embodiment, the fuel cell also includes one cathode disposed on the more textured side of said electrolyte sheet at least at least one anode disposed opposite the cathode on the relatively smooth side of aid electrolyte sheet. According to one embodiment, the relatively smooth side of the electrolyte sheet is the fuel facing side and the more textured side is the air-facing side.

Abstract: An electrode structure for a low voltage, high current electrical production device includes a charge transfer member (612). An electrically conductive member (605) having a non-uniform resistance is disposed on the charge transfer member 612 for optimizing current coupling.

Abstract: A fuel cell and method for manufacturing the fuel cell are described herein. Basically, the fuel cell is formed from an electrode/electrolyte structure including an array of anode electrodes and cathode electrodes disposed on opposing sides of an electrolyte sheet, the anode and cathode electrodes being electrically connected in series, parallel, or a combination thereof by electrical conductors that traverse via holes in the electrolyte sheet. Several different embodiments of electrical conductors which have a specific composition and/or a specific geometry are described herein.

Abstract: An electrolyte sheet comprises a substantially non-porous body and has at least one stress-relief area on at least a portion of the electrolyte sheet. The stress-relief area has a surface with a plurality of smoothly domed cells.

Abstract: A system and method for suppressing the formation of gaseous inclusions in glass sheets and the resulting glass sheets are described herein. The system includes a melting, fining, delivery, mixing or forming vessel that has a refractory metal component (e.g., platinum component) which has an inner wall that contacts molten glass and an outer wall coated with an oxygen ion transportable material (e.g., zirconia) which is coated with a conductive electrode. The system also includes a DC power source that supplies DC power across the oxygen ion transportable material which causes oxygen ions to migrate from the refractory metal component to the conductive electrode and enables one to control the partial pressure of oxygen around an exterior of the vessel which helps one to effectively prevent hydrogen permeation from the molten glass in order to suppress the formation of undesirable gaseous inclusions and surface blisters within the glass sheet.

Abstract: The present invention relates to a fuel cell apparatus which includes arrays of positive air electrodes and negative fuel electrodes with via interconnections disposed on an electrolyte sheet; optional electrode designs include symmetric electrodes comprising a conductive silver alloy metal phase and a thermally stabilizing ceramic phase, the latter providing low interface resistance and matching thermal properties.

Abstract: According to one aspect of the present invention the fuel cell device includes an electrolyte sheet. The electrolyte sheet has a substantially non-porous body of a varied thickness, a relatively smooth surface and a more textured surface with multiple indentations therein, wherein the thickest part of the electrolyte sheet is at least 0.5 micrometers greater than the thinnest part of said electrolyte sheet. The side of the electrolyte sheet with a relatively smooth surface is subjected to the predominately tensile force and the other, more textured surface subjected to predominately compressive force. According to one embodiment, the fuel cell also includes one cathode disposed on the more textured side of said electrolyte sheet at least at least one anode disposed opposite the cathode on the relatively smooth side of aid electrolyte sheet.

Abstract: An electrolyte sheet comprises a body of a varied thickness. The electrolyte sheet has at least one non-porous surface. This non-porous surface is a textured surface with multiple indentations therein. The thickest part of the electrolyte sheet is at least 0.5 micrometers greater than the thinnest part of the sheet.

Abstract: A fuel cell and method for manufacturing the fuel cell are described herein. Basically, the fuel cell is formed from an electrode/electrolyte structure including an array of anode electrodes and cathode electrodes disposed on opposing sides of an electrolyte sheet, the anode and cathode electrodes being electrically connected in series, parallel, or a combination thereof by electrical conductors that traverse via holes in the electrolyte sheet. Several different embodiments of electrical conductors which have a specific composition and/or a specific geometry are described herein.

Abstract: A ceramic filter for trapping and combusting diesel exhaust particulates offering improved configurations that are significantly more resistant to thermal cracking and melting damage comprises a honeycomb filter body composed of porous ceramic material and including a plurality of parallel cell channels traversing the body from a frontal inlet end to an outlet end thereof, a portion of the cell channels are plugged in a non-checkered pattern, and the remaining cell channels are plugged in a checkered pattern. In one embodiment the honeycomb filter body has a section of non-checkered and a section of checkered plugging at the frontal inlet end. In another embodiment the honeycomb filter body has a plurality of cell channels internal plugs. In another embodiment the honeycomb filter body has a plurality of partial cell channels which extend partially from the frontal inlet end into the honeycomb filter body, and are unplugged at the frontal inlet end.

Abstract: The present invention relates to electrode/electrolyte assemblies for solid oxide fuel cells (SOFCs) comprising a thin electrolyte sheet interposed between opposite electrodes, and wherein the positive air electrode (cathode) and negative fuel electrode (anode) are composed of similar electronically conductive metal phases and stabilizing ceramic phases, and wherein the anode exhibits both good oxidation resistance and good catalytic activity toward fuel oxidation.

Abstract: The present invention relates to a compliant fuel cell apparatus which includes arrays of positive air electrodes and negative fuel electrodes with via interconnections disposed on a thin compliant electrolyte sheet; optional electrode designs include symmetric electrodes comprising a conductive silver alloy metal phase and a thermally stabilizing ceramic phase, the latter providing low interface resistance and matching thermal properties, with the resulting fuel cells remaining sufficiently compliant to demonstrate good resistance to thermal shock damage.

Abstract: Flexible ceramic sheets with enhanced strain tolerance for electrochemical applications such as solid oxide fuel cell electrolytes incorporate a surface indentation pattern providing a strain tolerance of not less than 0.5% in any direction in the sheet plane, being made from flexible green ceramic sheet comprising a ceramic powder and a thermoplastic organic binder by heating and reshaping the green sheet to form a multi-directional surface corrugation pattern therein, followed by firing to sinter the ceramic powder to a flexible ceramic sheet having a multi-directional surface corrugation pattern.

Abstract: Solid oxide fuel cell assemblies comprise packets of multi-cell-sheet devices based on compliant solid oxide electrolyte sheets that form a fuel chamber and support anodes interiorly and cathodes exteriorly of the chamber that can be electrically interconnected to provide a compact, high voltage power-generating unit; added frames can support the oxide sheets and incorporate fuel supply and air supply conduits or manifolds permitting stacking of the assemblies into fuel cell stacks of any required size and power-generating capacity.

Abstract: A honeycomb structure for a diesel engine or an automotive engine where the wall thickness is varied in a controlled manner from the front surface to the back of the honeycomb. One example is grading the web thickness continuously from thin webs on the front of the DPF to thick webs on the back of the DPF. Another example is to make a two layer honeycomb with thinner walls and/or perhaps even lower cell density on the upstream side of the honeycomb. This provides a lower thermal mass front while retaining the thicker webs and higher thermal mass at the back of the honeycomb. The honeycomb structure has a thermal mass or heat capacity ranging from above 8.5×10−3cal/cubic cm-K to below 0.25 cal/cubic cm-K along an axis from the inlet end to the outlet end.

Abstract: The present invention relates to an electrolyte structure coated on at least one surface with a roughened interfacial nano-crystalline layer. Another aspect of the present invention is a solid oxide fuel cell which includes a positive air electrode, a negative fuel electrode, an electrolyte structure interposed between the positive air electrode and negative fuel electrode, and a roughened interfacial nano-crystalline layer interposed between the electrolyte structure and at least one of the positive air electrode and negative fuel electrode. The present invention also relates to methods of making the coated electrolyte and solid oxide fuel cell.