Abstract: Exemplary embodiments of the invention provide barrier coated substrates and methods of coating a substrate with a barrier coating derived from sol gels. An example includes a barrier coated aerospace component that is subject to hot salt corrosion during use. The barrier coating is derived from oxidation of a coating composition that includes at least one sol gel. The barrier coating resists hot salt corrosion for an incubation period of such duration that an uncoated superalloy substrate under the same conditions would suffer corrosion to a depth of about 2.0 mils. Methods of applying the barrier coating include the steps of selecting a first liquid sol gel and wetting surfaces of the superalloy substrate with the selected first liquid sol gel. The wetted surfaces of the superalloy substrate are subjected to heat treatment. The heat treatment includes sintering of sol gel to oxide to produce a barrier coating.

Abstract: Components and methods of forming a protective coating system on the components are provided. In an embodiment, and by way of example only, the component includes a ceramic substrate and a braze layer disposed over the ceramic substrate. The braze layer includes a silicon matrix having a first constituent and a second constituent that is different than the first constituent. The first constituent forms a first intermetallic with a portion of the silicon matrix and the second constituent forms a second intermetallic with another portion of the silicon matrix, wherein the braze layer is formulated to provide a barrier to oxygen diffusion therethrough.

Abstract: An armor material, body armor articles, and methods of manufacturing the armor material are provided. In an embodiment, by way of example only, the armor material includes a first plate, a second plate, and a powder material. The first plate includes a layer comprising a metallic material. The second plate is spaced apart from the first plate and includes a layer comprising a ceramic material. The powder material is disposed between the first and the second plates, and comprises loose powder including at least one of a plurality of ceramic particles and a plurality of metallic particles.

Abstract: Turbine components are provided. In an embodiment, by way of example, a hub and a ring are included. The hub comprises a first material. The ring is bonded to the hub. The ring comprises a plurality of arc segments forming a ring, each arc segment comprising a second material comprising a single crystal superalloy material having a predetermined primary orientation and a predetermined secondary orientation, each predetermined primary orientation of each arc segment being substantially equal, and each predetermined secondary orientation of each arc segment being substantially equal, each arc segment adjacent another arc segment, and the adjacent arc segments having a predetermined crystallographic mismatch therebetween. Methods of manufacturing are also provided.

Abstract: According to a method for forming a coating system on a turbine engine component substrate that comprises a nickel-based superalloy substrate having at least one refractory metal included therein, a nickel-based layer is formed on the substrate, the nickel-based layer comprising at least one active material selected from the group consisting of elemental silicon and a silicon compound. The at least one active material is then diffused into the substrate. An yttrium-modified platinum aluminide bond coating, or a MCrAlX bond coating, may be then formed over the active material-modified nickel-based layer.

Abstract: A dual alloy turbine rotor is provided and includes an integrally formed blade ring and a disk. The blade ring is made of a first alloy and includes a ring portion and a plurality of airfoils extending therefrom, where the ring portion includes an inner surface, and each airfoil includes an internal cavity formed therein. The disk is made of a second alloy and may have a beveled outer peripheral surface. The disk is disposed within the ring portion such that the disk outer peripheral surface contacts at least a portion of the ring portion inner surface. Methods of manufacturing the turbine rotor are also provided.

Abstract: An article having a thermal barrier coating includes a superalloy substrate having a columnar grained ceramic coat formed thereon. The ceramic coat includes a nanolaminate region comprising repeating layers of ceramic material with each layer being less than 500 nm in thickness, with dispersions of metal oxide doping material situated between each of the layers. The ceramic coat further includes a non-doped region having a thickness greater than 500 nm adjacent to the nanolaminate region, the non-doped region including one layer or a plurality of adjacent layers of ceramic material without dispersions of metal oxide doping material situated between each of the layers. In one embodiment, and by way of example only, a bond coat is formed between the substrate and the columnar grained ceramic coat. According to another embodiment, the superalloy substrate forms an adherent alumina scale, and no bond coat is necessary.

Abstract: An article having a thermal barrier coating includes a superalloy substrate having a columnar grained ceramic coat formed thereon. The ceramic coat includes a nanolaminate region comprising repeating layers of ceramic material with each layer being less than 500 nm in thickness, with dispersions of metal oxide doping material situated between each of the layers. The ceramic coat further includes a non-doped region having a thickness greater than 500 nm adjacent to the nanolaminate region, the non-doped region including one layer or a plurality of adjacent layers of ceramic material without dispersions of metal oxide doping material situated between each of the layers. In one embodiment, and by way of example only, a bond coat is formed between the substrate and the columnar grained ceramic coat. According to another embodiment, the superalloy substrate forms an adherent alumina scale, and no bond coat is necessary.

Abstract: A protective coating for a component comprising a ceramic based substrate, and methods for protecting the component, the protective coating adapted for withstanding repeated thermal cycling. The substrate may comprise silicon nitride or silicon carbide, and the protective coating may comprise at least one tantalate of scandium, yttrium, or a rare earth element. The protective coating may further comprise one or more metal oxides. The coating protects the substrate from combustion gases in the high temperature turbine engine environment. The coating may be multi-layered and exhibits strong bonding to Si-based substrate materials and composites.

Abstract: Components and methods of forming a protective coating system on the components are provided. In an embodiment, and by way of example only, the component includes a ceramic substrate and a braze layer disposed over the ceramic substrate. The braze layer includes a silicon matrix having a first constituent and a second constituent that is different than the first constituent. The first constituent forms a first intermetallic with a portion of the silicon matrix and the second constituent forms a second intermetallic with another portion of the silicon matrix, wherein the braze layer is formulated to provide a barrier to oxygen diffusion therethrough.

Abstract: Platinum containing coatings for corrosion and oxidation protection of a substrate, and platinum electrodeposition methods for coating a substrate. The coating may comprise platinum and at least one supplementary constituent, and the method may involve co-electrodeposition of platinum and the supplementary constituent from a single electrolyte composition. The supplementary constituent may comprise chromium, an oxidation protective reactive element, or an alloy of chromium with a reactive element. Components protected by such coatings are also disclosed.

Abstract: A diffuser particle separator may be integrated into a gas turbine engine to remove corrosive dust and salt particles from the engine's core air flow. The air flow may pass over a series of particle accumulator entrance orifices, trapping particles in a particle accumulator while allowing the air flow to continue unimpeded. Since dust deposits may become molten at high temperatures, removal of dust from the core and secondary airflow may be critical for long-life superalloy and ceramic components, particularly those with small diameter air-cooling holes and thermal barrier coatings.

Abstract: Methods and apparatus to make multilayer thermal barrier coatings for superalloy substrates such as turbine blades or vanes are disclosed. The methods produce non-homogeneous, nanometer-size, successive layers and a non-homogeneous interfacial layer without the use of baffles. Methods are also disclosed to use a lower cost metallic source and an oxygen bleed to create alumina or tantalum oxide vapor, to use a tantalum oxide or an alumina ingot and a low pressure inert gas feed to direct the vapor clouds, to use pulsed evaporation from a secondary vapor source to create non-homogeneous multilayer coating on non-rotated substrates, to use an electric bias to direct the vapor clouds, and to use a mechanical system to direct the vapor clouds or move and position the article to be coated in the clouds.

Abstract: Turbine components are provided. In an embodiment, by way of example, a hub and a ring are included. The hub comprises a first material. The ring is bonded to the hub. The ring comprises a plurality of arc segments forming a ring, each arc segment comprising a second material comprising a single crystal superalloy material having a predetermined primary orientation and a predetermined secondary orientation, each predetermined primary orientation of each arc segment being substantially equal, and each predetermined secondary orientation of each arc segment being substantially equal, each arc segment adjacent another arc segment, and the adjacent arc segments having a predetermined crystallographic mismatch therebetween. Methods of manufacturing are also provided.

Abstract: A turbine blade tip and shroud clearance control coating system comprising an abrasive blade tip coating and an abradable shroud coating are provided. The abrasive layer may comprise abrasive particles of cubic zirconia, cubic hafnia or mixtures thereof, and the abradable layer may be a nanolaminate thermal barrier coating that is softer than the abrasive layer. The invention further provides an alternate coating system comprising an abradable blade tip coating and an abrasive shroud coating.

Abstract: A turbine blade tip and shroud clearance control coating system comprising a dense abrasive blade tip layer and an abradable shroud layer are provided. The dense abrasive coating may comprise cubic zirconia, hafnia or mixtures thereof and the abradable layer may be a nanolaminate thermal barrier coating that is softer than the dense abrasive layer.

Abstract: A method for coating compressor or turbine blade tips of a bladed disk with abrasive particles includes installing the blades onto a disk, and then cold gas-dynamic spraying the abrasive particles onto the blade tips while the blades are installed in the disk. According to another embodiment, a method for coating compressor and turbine blade tips of a bladed wheel with abrasive particles includes grinding the blade tips to bring the bladed wheel to a predetermined diameter. Then, surfaces of the bladed wheel not requiring coating are masked. After masking the surface not to be coated, the abrasive particles are cold gas-dynamic sprayed onto the blade tips. For both embodiments, an oxidation resistant layer may be cold gas-dynamic sprayed on the blade tips prior to spraying the abrasive particles.

Abstract: A dual alloy turbine rotor is provided and includes an integrally formed blade ring and a disk. The blade ring is made of a first alloy and includes a ring portion and a plurality of airfoils extending therefrom, where the ring portion includes an inner surface, and each airfoil includes an internal cavity formed therein. The disk is made of a second alloy and may have a beveled outer peripheral surface. The disk is disposed within the ring portion such that the disk outer peripheral surface contacts at least a portion of the ring portion inner surface. Methods of manufacturing the turbine rotor are also provided.

Abstract: A turbine engine component includes an electron beam-physical vapor deposition thermal barrier coating covering at least a portion of a substrate. The thermal barrier coating includes an inner layer having a columnar-grained microstructure with inter-columnar gap porosity. The inner layer includes a stabilized ceramic material. The thermal barrier coating also includes a substantially non-porous outer layer, covering the inner layer and including the stabilized ceramic material. The outer layer is deposited with continuous line-of-sight exposure to the vapor source under oxygen deficient conditions. The outer layer may further comprise a dopant oxide that is more readily reducible than the stabilized ceramic material. During deposition, the outer layer may also have an oxygen deficient stoichiometry with respect to the inner layer. Oxygen stoichiometry in the outer layer may be restored by exposure of the coated component to an oxidizing environment.

Abstract: According to a method for forming a coating system on a turbine engine component substrate that comprises a nickel-based superalloy substrate having at least one refractory metal included therein, a nickel-based layer is formed on the substrate, the nickel-based layer comprising at least one active material selected from the group consisting of elemental silicon and a silicon compound. The at least one active material is then diffused into the substrate. An yttrium-modified platinum aluminide bond coating, or a MCrAlX bond coating, may be then formed over the active material-modified nickel-based layer.