Patents by Inventor Thomas F. Rutledge

Thomas F. Rutledge has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4438037
    Abstract: Anthracenes may be converted to their corresponding quinones by dissolving the anthracenes in an inert solvent and oxidizing the dissolved anthracenes with sodium hypochlorite as an oxidating agent where the reaction mixture has a pH in the range of 4.5 to 8.0.
    Type: Grant
    Filed: August 27, 1982
    Date of Patent: March 20, 1984
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4390731
    Abstract: Polymeric phenolic benzylic ether compositions are obtained by an intermolecular redox reaction thermolysis of tetraalkyldiphenoquinones at a minimum of about 150.degree. C. The compositions are useful as non-volatile oxidation inhibitors in polymers at high temperatures, as polymerization inhibitors for vinyl monomers, and as crosslinking co-monomers for epoxy and polycarbonate resins.
    Type: Grant
    Filed: September 24, 1981
    Date of Patent: June 28, 1983
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4147663
    Abstract: Self-condensation products obtained by the oxidative coupling of certain alkylphenols, alkoxyphenols or naphthols are prepared by contacting an aqueous mixture of the phenol or naphthol with oxygen in the presence of a metal complex of an aminocarboxylic acid or an aminosulfonic acid.
    Type: Grant
    Filed: October 31, 1977
    Date of Patent: April 3, 1979
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4139544
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of phenols and naphthols are prepared by contacting an aqueous mixture of phenol or naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 8.5-9.5 during the oxidative coupling reaction and a catalyst system comprising a copper, cobalt, nickel, iron, chromium, cerium, or manganese chelate of a polyimino acid containing more than two nitrogen atoms.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: February 13, 1979
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4132722
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols are prepared by contacting an aqueous mixture of an alkyl phenol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 9-9.5 during the oxidative coupling reaction and a catalyst system comprising a copper, cobalt, nickel, iron, chromium, cerium or manganese complex of a diimino acid. The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: January 2, 1979
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4130504
    Abstract: Self-condensation products obtained by the coupling of alkylphenols, alkoxyphenols or naphthols are prepared by contacting an aqueous mixture of the phenol or naphthol with oxygen or an oxygen-containing gas in the presence of a catalyst system comprising(a) a copper compound,(b) an anionic surfactant, and(c) an alkaline material.
    Type: Grant
    Filed: October 31, 1977
    Date of Patent: December 19, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4108908
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkylphenol or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 7.0-9.0 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous, manganous or chromic chelate of a thio-acid compound.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: August 22, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4101561
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols are prepared by contacting an aqueous mixture of an alkyl phenol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 8.5-9.5 during the oxidative coupling reaction and a catalyst system comprising certain imino acid chelates of Cu.sup.2, Ni.sup.2, Co.sup.2, Ce.sup.3, Cr.sup.3, Mn.sup.2 and Fe.sup.3. The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: July 18, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4100206
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkyl phenol or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 7.0-9.5 during the oxidative coupling reaction and a catalyst system comprising a cupric or manganous chelate of a keto alcohol compound.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: July 11, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4100204
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkylphenol or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 7.0-9.5 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous or manganous chelate of a hydroxy- or keto- acid compound.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: July 11, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4100203
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkylphenol or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 8.0-9.5 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous or manganous chelate of an oxime of a keto or aldehyde compound.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: July 11, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4100202
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkylphenol or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 8.5-9.5 during the oxidative coupling reaction and a catalyst system comprising a cupric chelate of a compound selected from the group consisting of quanidines, amides, salens, dihydrazides, triazenes, dihydroxy substituted aromatics, macrocylic polyamines and alpha, delta-polyketones.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: July 11, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4100205
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkylphenol or 1-naphtol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 7.5-10 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous, nickelous, ferric, manganous or chromic chelate of an aminoketone compund.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: July 11, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4098766
    Abstract: Tetravalent manganese precipitated on porous carbon is useful to catalyze oxidative coupling reactions of alkyl phenols.
    Type: Grant
    Filed: April 14, 1977
    Date of Patent: July 4, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4098830
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkylphenol, alkoxyphenyl, or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 7.0-9.5 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous, manganous, nickelous, chromic or ferric chelate of a dicarboxylic acid compound.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: July 4, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4097461
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacting an aqueous mixture of an alkyl phenol or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 5-10 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous, manganous or chromic chelate of a beta- or gamma- diketone or keto ester.The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: December 3, 1976
    Date of Patent: June 27, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4096190
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols are prepared by contacting an aqueous mixture of an alkyl phenol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 6-9.5 during the oxidative coupling reaction and a catalyst system comprising an ammonia complex of monovalent copper; divalent copper, cobalt, nickel or manganese; or trivalent chromium or iron. The mixture may optionally contain a surfactant.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: June 20, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4085124
    Abstract: Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols, alkoxyphenols or 1-naphthols are prepared by contacting an aqueous mixture of the phenol or naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 5-10 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous, manganous or ferric complex ofAn aliphatic hydroxy amine,A heterocyclic hydroxy amine,A heterocyclic polyamine or,An aliphatic diamineThe mixture may optionally contain a surfactant.
    Type: Grant
    Filed: November 24, 1975
    Date of Patent: April 18, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4070383
    Abstract: Self-condensation products obtained by the coupling of alkylphenols, alkoxyphenols or naphthols are prepared by contacting an aqueous mixture of the phenol or naphthol with oxygen or an oxygen-containing gas in the presence of a catalyst system comprisingA. a copper compound,B. an anionic surfactant, andC. an alkaline material.
    Type: Grant
    Filed: February 4, 1976
    Date of Patent: January 24, 1978
    Assignee: ICI Americas Inc.
    Inventor: Thomas F. Rutledge
  • Patent number: 4067890
    Abstract: Self-condensation products obtained by the oxidative coupling of certain alkylphenols, alkoxyphenols or naphthols are prepared by contacting an aqueous mixture of the phenol or naphthol with oxygen in the presence of a metal complex of an aminocarboxylic acid or an aminosulfonic acid.
    Type: Grant
    Filed: March 12, 1976
    Date of Patent: January 10, 1978
    Assignee: ICI America Inc.
    Inventor: Thomas F. Rutledge