Abstract: An emulsion includes a substantially continuous liquid medium, and a plurality of droplet structures dispersed within the substantially continuous liquid medium. Each droplet structure of the plurality of droplet structures includes an outer droplet of a first liquid having an outer surface; an inner droplet of a second liquid within the first droplet, the second liquid being immiscible in the first liquid, wherein the inner and outer droplets have a boundary surface region therebetween; an outer layer of block copolymers disposed on the outer surface of the outer droplet; and an inner layer of block copolymers disposed on the boundary surface region between the outer and the inner droplets.

Abstract: A method of separating a mixture of discrete structures dispersed in a fluid material includes identifying a target structure and a non-target structure; providing a custom-shaped particle having at least a portion of a surface that is substantially shape-complementary to a portion of a surface of the target structure; introducing the custom-shaped particle into the fluid material; exciting reconfigurations of the custom-shaped particle with respect to the target structure and the non-target structure; binding the custom-shaped particle to the target structure through an attractive interaction to form an aggregate; and isolating the aggregate containing the target structure and the custom-shaped particle from the non-target structure. The custom-shaped particle preferentially binds with the target structure without binding with the non-target structure.

Abstract: An emulsion includes a substantially continuous liquid medium, and a plurality of droplet structures dispersed within the substantially continuous liquid medium. Each droplet structure of the plurality of droplet structures includes an outer droplet of a first liquid having an outer surface; an inner droplet of a second liquid having an inner surface contained within the outer surface of the outer droplet of the first liquid, the second liquid being immiscible in the first liquid, wherein the inner and outer droplets have a boundary surface region therebetween; an outer layer of block copolymers disposed on the outer surface of the outer droplet; and an inner layer of block copolymers disposed on the inner surface of the inner droplet. The block copolymers include a hydrophilic polymer block and a hydrophobic polymer block that act in combination to stabilize the droplet structure, and the first liquid is immiscible in the substantially continuous liquid medium.

Abstract: A method of assembling composite structures from objects in fluid includes providing a plurality of objects, each having a preselected size, shape, and spatial distribution of surface structural features characterizing a surface roughness; dispersing the objects into the fluid; and introducing a depletion agent. The depletion agent includes a plurality of particles having a size distribution preselected causing an attractive force arising from a depletion attraction between at least a first object and second object of the plurality in at least one relative position and orientation based on the preselected spatial distribution of surface structural features on the first and second objects, and the depletion attraction between the first and second objects forms at least one rigid bond or slippery bond at or proximate to respective surface portions based on the preselected spatial distribution of surface structural features on the first and second objects to form a two-object composite structure.

Abstract: A system for producing emulsions includes a liquid supply system, an emulsification system in liquid connection with the liquid supply system to receive a first liquid and a second liquid from the liquid supply system while in operation to be used to produce an emulsion therefrom, and a surfactant recovery system connected to the emulsification system to receive the emulsion when produced from the first and second liquids. The second liquid is immiscible with the first liquid, and the surfactant recovery system recovers at least a portion of surfactant from the emulsion when the emulsion is received from the emulsification system.

Abstract: A method of producing a topical scrub includes providing a particle material suitable for producing a customized anisotropic particle; producing a plurality of customized anisotropic particles composed of the particle material, each customized anisotropic particle having a particle shape, a particle volume, and a particle composition; and dispersing the plurality of customized anisotropic particles in a fluid material to form a dispersion of customized anisotropic particles in the fluid material. At least a feature of the particle shape facilitates embedding at least a portion of the plurality of customized anisotropic particles into a topical surface by a scrubbing action.

Abstract: A method of producing an emulsion includes preparing a droplet solution comprising first and second molecular species, the droplet solution being in a fluid phase, wherein the first molecular species is soluble in the second molecular species; forming a plurality of droplets from the droplet solution in a bulk fluid to create a first emulsion, the plurality of droplets having a first ensemble average radius in the bulk fluid, wherein the first molecular species of the droplet solution is at least partially soluble in the bulk fluid and the droplet solution is at least partially immiscible in the bulk fluid; and allowing molecules of the first molecular species to migrate from the plurality of fluid droplets to the bulk fluid due to a higher concentration of the first molecular species in the droplet solution than the bulk fluid to result in the plurality of droplets having a second ensemble average radius that is smaller than the first ensemble average radius.

Abstract: A method of producing a particle includes fabricating a precursor particle structure that has a first sub-structure, a second sub-structure proximate the first sub-structure and an interconnecting sub-structure connected to the first and second sub-structures, the precursor particle structure being in a first configuration; and exposing the precursor particle structure to a stochastic excitation process to cause a deformation of the interconnecting sub-structure to reconfigure at least one of a position and an orientation of the first sub-structure relative to the second sub-structure from the first configuration to form the particle in a second configuration. The first sub-structure and the second sub-structure are substantially free of deformation during the exposing, and a maximal spatial dimension of the particle in the second configuration is less than about one millimeter.

Abstract: A method of assembling composite structures from objects in fluid includes providing a plurality of objects, each having a preselected size, shape, and spatial distribution of surface structural features characterizing a surface roughness; dispersing the objects into the fluid; and introducing a depletion agent. The depletion agent includes a plurality of particles having a size distribution preselected causing an attractive force arising from a depletion attraction between at least a first object and second object of the plurality in at least one relative position and orientation based on the preselected spatial distribution of surface structural features on the first and second objects, and the depletion attraction between the first and second objects forms at least one rigid bond or slippery bond at or proximate to respective surface portions based on the preselected spatial distribution of surface structural features on the first and second objects to form a two-object composite structure.

Abstract: A system for producing multi-component colloidal structures has a supply system; an assembly system that is in fluid connection with the supply system to receive a supply of colloidal structural components from the supply system; and an output system in fluid connection with the assembly system. The assembly system has an assembly chamber adapted to contain colloidal structural components during assembly of a multi-component colloidal structure and is structured and arranged to control positions and orientations of first and second c structural components in the assembly chamber to bring the first and second colloidal structural components together in predetermined relative positions and orientations for assembly into at least a portion of the multi-component colloidal structure.

Abstract: A protein-modified droplet includes a droplet having a liquid material, and a protein structure formed to at least partially enclose the droplet. The protein structure includes a plurality of protein molecules having an affinity to at least a region of the droplet during formation of the protein structure, and the droplet has a maximum dimension of at least about 1 nm and less than about 1000 nm. A composition includes a plurality of protein-modified droplets dispersed in an aqueous solution.

Abstract: A method for producing particles includes providing a first patterned surface having a first surface relief pattern adapted to impart structure to a plurality of particles while they are under production; providing a second patterned surface having a second surface relief pattern adapted to impart structure to a plurality of particles while they are under production; depositing a particle material in contact with at least one of the first patterned surface and the second patterned surface; aligning the first surface relief pattern on the first patterned surface with respect to the second surface relief pattern on the second patterned surface; contacting at least a portion of the first patterned surface with at least a portion of the second patterned surface; solidifying at least a portion of the particle material to form a plurality of particles; and separating at least a portion of the plurality of particles from at least one of the first patterned surface and the second patterned surface.

Abstract: A method for producing particles includes providing a relief template having a surface relief pattern adapted to impart structure to a plurality of particles while they are under production; depositing a radiation-sensitive material on the relief template; exposing portions of the radiation-sensitive material on the relief template using a beam of spatially patterned radiation; removing portions of the radiation-sensitive material after the exposing to reveal at least portions of surfaces of the plurality of particles; and separating at least a portion of the plurality of particles from the relief template. At least a portion of a structure of each of the plurality of particles is defined by a combination of the surface relief pattern and the spatially patterned radiation.

Abstract: A method of separating a mixture of discrete structures dispersed in a fluid material includes identifying a target structure and a non-target structure; providing a custom-shaped particle having at least a portion of a surface that is substantially shape-complementary to a portion of a surface of the target structure; introducing the custom-shaped particle into the fluid material; exciting reconfigurations of the custom-shaped particle with respect to the target structure and the non-target structure; binding the custom-shaped particle to the target structure through an attractive interaction to form an aggregate; and isolating the aggregate containing the target structure and the custom-shaped particle from the non-target structure. The custom-shaped particle preferentially binds with the target structure without binding with the non-target structure.

Abstract: A method of producing particles includes providing a substrate structure that comprises a solid substrate; forming a target structure on said substrate structure, said target structure comprising a radiation-reactive material; forming a spatially patterned beam of radiation using a patterned mask; exposing at least a portion of the target structure to the spatially patterned beam of radiation to which the radiation-reactive material reacts while leaving other portions of the target structure unexposed to the radiation; removing substantially all of one of the exposed or the unexposed patterned portions of the target structure to provide a plurality of non-contiguous structures that include at least a portion of the radiation-reactive material; and separating the plurality of non-contiguous structures comprising the radiation-reactive material from the substrate structure into a fluid material.

Abstract: A method of producing at least one of microscopic and submicroscopic particles includes providing a template that has a plurality of discrete surface portions, each discrete surface portion having a surface geometry selected to impart a desired geometrical property to a particle while being produced; depositing a constituent material of the at least one of microscopic and submicroscopic particles being produced onto the plurality of discrete surface portions of the template to form at least portions of the particles; separating the at least one of microscopic and submicroscopic particles comprising the constituent material from the template into a fluid material, the particles being separate from each other at respective discrete surface portions of the template; and processing the template for subsequent use in producing additional at least one of microscopic and submicroscopic particles.

Abstract: A method of producing an elastic material including providing a viscous material having an initial material composition thereof, the viscous material being a multiphase dispersion comprising a plurality of discrete elements of a first component dispersed within a continuous fluid phase of a second component; and applying stress to the plurality of discrete elements of the first component to break up the plurality of discrete elements into a second plurality of discrete elements having a greater number of discrete elements than the first plurality of discrete elements. The discrete elements of the second plurality of discrete elements have at least one of a composition or a surface layer that provides at least a repulsion between adjacent discrete elements to prevent the discrete elements from irreversibly coalescing or irreversibly re-uniting, the viscous material thus irreversibly becoming an elastic material having a same material composition as the initial material composition.

Abstract: Producing composite structures includes dispersing a first plurality of objects, a second plurality of objects, and a third plurality of objects in a fluid, the third and second plurality of objects having an average maximum dimension that is smaller than the first plurality of objects The first plurality of objects comprise a first, a second, a third and a forth object, each having mating surface regions The first and second objects' mating surfaces are complimentary and the third and forth objects' mating surfaces are complementary The first and second object aggregate together in response to the dispersing of the second plurality of objects in the fluid due to a depletion attraction between the first and the second object The third and forth object aggregate together in response to dispersing the third plurality of objects in the fluid due to a depletion attraction between the third and the fourth object

Abstract: An emulsion includes a substantially continuous liquid medium, and a plurality of droplet structures dispersed within the substantially continuous liquid medium. Each droplet structure of the plurality of droplet structures includes an outer droplet of a first liquid having an outer surface; an inner droplet of a second liquid having an inner surface contained within the outer surface of the outer droplet of the first liquid, the second liquid being immiscible in the first liquid, wherein the inner and outer droplets have a boundary surface region therebetween; an outer layer of block copolymers disposed on the outer surface of the outer droplet; and an inner layer of block copolymers disposed on the inner surface of the inner droplet. The block copolymers include a hydrophilic polymer block and a hydrophobic polymer block that act in combination to stabilize the droplet structure, and the first liquid is immiscible in the substantially continuous liquid medium.

Abstract: The thermal decomposition of Athabasca asphaltene at relatively low (<350° C.) temperatures is believed to proceed by elimination of groups situated on peripheral sites of the asphaltene. More severe degradation of the asphaltene structure does not occur until elevated (>350° C.) temperatures are attained.