Patents by Inventor Thomas G. Rukavina

Thomas G. Rukavina has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230120549
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Application
    Filed: August 11, 2022
    Publication date: April 20, 2023
    Inventors: Thomas G. Rukavina, Caroline S. Harris, Robert M. Hunia, Veronica L. Frain, Yan Wang
  • Patent number: 11591436
    Abstract: Articles are provided including at least one polyurethane prepared from: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.005 to about 0.35 equivalent of at least one polycaprolactone polyol; (c) about 0.01 to about 1.0 equivalent of at least one polyol selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,2-ethanediol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, dodecane diol, octadecanediol, cyclopentanediol, 1,4-cyclohexanediol, cyclohexanedimethanol, 1,4-benzenedimethanol, xylene glycol, hydroxybenzyl alcohol, dihydroxytoluene, bis(2-hydroxyethyl) terephthalate, 1,4-bis(hydroxyethyl)piperazine, N,N?,bis(2-hydroxyethyl)oxamide and mixtures thereof; and (d) about 0.01 to about 0.
    Type: Grant
    Filed: April 14, 2021
    Date of Patent: February 28, 2023
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Thomas G. Rukavina
  • Patent number: 11472912
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: December 24, 2019
    Date of Patent: October 18, 2022
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Thomas G. Rukavina, Caroline S. Harris, Robert M. Hunia, Veronica L. Frain, Yan Wang
  • Publication number: 20220119581
    Abstract: The present invention provides an aircraft window including a polyurethane including a reaction product of components including (a) about 1 equivalent of at least one polyisocyanate; and (b) about 1 equivalent of 1,4-cyclohexane dimethanol based upon the about 1 equivalent of the at least one polyisocyanate, and other aircraft window compositions.
    Type: Application
    Filed: December 30, 2021
    Publication date: April 21, 2022
    Inventor: Thomas G. Rukavina
  • Publication number: 20220112328
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer including a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.01 to about 0.5 equivalent of at least one polyol having at least 3 hydroxyl groups; and (b) about 0.1 to about 1.0 equivalent of at least one polyol having at least 3 hydroxyl groups; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Application
    Filed: September 10, 2021
    Publication date: April 14, 2022
    Inventor: Thomas G. Rukavina
  • Patent number: 11248083
    Abstract: The present invention provides an aircraft window including a polyurethane including a reaction product of components including (a) about 1 equivalent of at least one polyisocyanate; and (b) about 1 equivalent of 1,4-cyclohexane dimethanol based upon the about 1 equivalent of the at least one polyisocyanate, and other aircraft window compositions.
    Type: Grant
    Filed: September 23, 2019
    Date of Patent: February 15, 2022
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Thomas G. Rukavina
  • Patent number: 11149107
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer including a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.01 to about 0.5 equivalent of at least one polyol having at least 3 hydroxyl groups; and (b) about 0.1 to about 1.0 equivalent of at least one polyol having at least 3 hydroxyl groups; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: October 19, 2021
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Thomas G. Rukavina
  • Publication number: 20210253779
    Abstract: Articles are provided including at least one polyurethane prepared from: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.005 to about 0.35 equivalent of at least one polycaprolactone polyol; (c) about 0.01 to about 1.0 equivalent of at least one polyol selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,2-ethanediol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, dodecane diol, octadecanediol, cyclopentanediol, 1,4-cyclohexanediol, cyclohexanedimethanol, 1,4-benzenedimethanol, xylene glycol, hydroxybenzyl alcohol, dihydroxytoluene, bis(2-hydroxyethyl) terephthalate, 1,4-bis(hydroxyethyl)piperazine, N,N?,bis(2-hydroxyethyl)oxamide and mixtures thereof; and (d) about 0.01 to about 0.
    Type: Application
    Filed: April 14, 2021
    Publication date: August 19, 2021
    Inventor: Thomas G. Rukavina
  • Patent number: 11008418
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (1) a reaction product of (a) an isocyanate functional urethane prepolymer including a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.005 to about 0.35 equivalent of at least one polycaprolactone polyol; and (b) about 0.01 to about 0.5 equivalent of at least one polyol having 2 hydroxyl groups, based upon the about 1 equivalent of the at least one polyisocyanate; and (2) about 0.3 to about 1.0 equivalent of at least one polyol having at least 2 hydroxyl groups, based upon the about 1 equivalent of the at least one polyisocyanate, wherein the at least one polyol (b) can be the same or different from the at least one polyol (2); compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: May 18, 2021
    Assignee: PPG industries Ohio, Inc.
    Inventor: Thomas G. Rukavina
  • Publication number: 20200165375
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Application
    Filed: December 24, 2019
    Publication date: May 28, 2020
    Inventors: Thomas G. Rukavina, Caroline S. Harris, Robert M. Hunia, Veronica L. Frain, Yan Wang
  • Patent number: 10590230
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: March 6, 2018
    Date of Patent: March 17, 2020
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Thomas G. Rukavina, Robert M. Hunia, Caroline S. Harris, Veronica L. Frain
  • Publication number: 20200071451
    Abstract: The present invention provides an aircraft window including a polyurethane including a reaction product of components including (a) about 1 equivalent of at least one polyisocyanate; and (b) about 1 equivalent of 1,4-cyclohexane dimethanol based upon the about 1 equivalent of the at least one polyisocyanate, and other aircraft window compositions.
    Type: Application
    Filed: September 23, 2019
    Publication date: March 5, 2020
    Inventor: Thomas G. Rukavina
  • Patent number: 10533068
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: October 27, 2017
    Date of Patent: January 14, 2020
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Thomas G. Rukavina, Caroline Harris, Robert M. Hunia, Veronica L. Frain, Yan Wang
  • Publication number: 20180282470
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Application
    Filed: March 6, 2018
    Publication date: October 4, 2018
    Inventors: Thomas G. Rukavina, Robert M. Hunia, Caroline S. Harris, Veronica L. Frain
  • Patent number: 9994670
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) at least one isocyanate functional prepolymer including a reaction product of: (1) about 1 equivalent of at least one polyisocyanate; and (2) about 0.01 to about 0.5 equivalent of at least one polycarbonate polyol; and (b) about 0.01 to about 1 equivalent of at least one branched polyol having at least 3 hydroxyl groups; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: July 26, 2016
    Date of Patent: June 12, 2018
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Thomas G Rukavina
  • Patent number: 9951173
    Abstract: The present invention provides polyurethanes including a reaction product of components including (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: February 26, 2016
    Date of Patent: April 24, 2018
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Thomas G. Rukavina, Caroline S. Harris, Robert M. Hunia, Veronica L. Frain
  • Publication number: 20180051123
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Application
    Filed: October 27, 2017
    Publication date: February 22, 2018
    Inventors: Thomas G. Rukavina, Caroline Harris, Robert M. Hunia, Veronica L. Frain, Yan Wang
  • Patent number: 9822211
    Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
    Type: Grant
    Filed: August 21, 2014
    Date of Patent: November 21, 2017
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Thomas G. Rukavina, Caroline S. Harris, Robert M. Hunia, Veronica L. Frain, Yan Wang
  • Patent number: 9744747
    Abstract: The present invention discloses a method for forming a laminated window. The method includes: a) assembling a mold between two plies that make up a laminated window; b) filling the mold with a reaction mixture having: (1) at least one chain extender; (2) at least one polyether polyol having a molecular weight of approximately 1,000; and (3) at least one aliphatic polyisocyanate; and c) curing the reaction mixture.
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: August 29, 2017
    Assignee: Vitro, S.A.B. de C.V.
    Inventors: Thomas G. Rukavina, Gregory J. McCollum
  • Patent number: 9701807
    Abstract: The present invention is directed toward a polymer and a method for making a polymer that has nanostructures incorporated into the matrix of the polymer. The method of the invention involves the following steps: mixing a precursor solution for the polymer with a precursor for the nanostructures to form a mixture; forming nanostructures in the mixture from the precursor of the nanostructures; and forming a polymer from the precursor solution of the polymer so that the nanostructures are incorporated into the polymer matrix.
    Type: Grant
    Filed: December 7, 2015
    Date of Patent: July 11, 2017
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Songwei Lu, Thomas G. Rukavina, Mehran Arbab