Patents by Inventor Thomas Geelhaar

Thomas Geelhaar has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5232624
    Abstract: Chiral 1,2-difluorobenzene derivatives are suitable as components of chiral tilted smectic liquid-crystalline phases.
    Type: Grant
    Filed: May 15, 1989
    Date of Patent: August 3, 1993
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Volker Reiffenrath, Joachim Krause, Andreas Wachtler, Thomas Geelhaar, Ekkehard Bartmann, Reinhard Hittich
  • Patent number: 5230827
    Abstract: Derivatives of 2,3-Difluorobenzoic acid compounds of the formula I ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are each an alkyl group having 1 to 15 C atoms, in which, in addition, one or two non-adjacent CH.sub.2 groups may be replaced by --O--, --CO--, --CH.dbd.CH-- and/or --C.tbd.C--, andA.sup.1 and A.sup.2, independently of one another, are each 1,4-phenylene which is unsubstituted or substituted by one or two fluorine atoms, and in which, in addition, one or two CH groups may be replaced by N, or are trans1,4-cyclohexylene, or one of the two A.sup.1 and A.sup.2 groups is alternatively a single bond,are suitable as components of liquid-crystalline phases.
    Type: Grant
    Filed: May 12, 1989
    Date of Patent: July 27, 1993
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Volker Reiffenrath, Joachim Krause, Andreas Wachtler, Georg Weber, Thomas Geelhaar
  • Patent number: 5209866
    Abstract: Heterocyclic 1,2-difluorobenzene derivatives of the formula I ##STR1## in which R.sup.1 and R.sup.2, in each case independently of one another, are an alkyl groups (sic) having 1-15 C atoms in which, in addition, one or more CH.sub.2 groups may be replaced by a divalent radical selected from the group comprising --O--, --S--, --CO--, --O--CO--, --CO--O--, --CH.dbd.CH-- and --C.tbd.C--, where two heteroatoms are not linked directly to one another,A.sup.1 and A.sup.2, in each case independently of one another, are a 1,4-phenylene group which is unsubstituted or monosubstituted or polysubstituted by fluorine, and in which, in addition, one or two CH groups may be replaced by N, or are a 1,3,4-thiadiazole-2,5-diyl group or a trans-1,4-cyclohexylene group,m and n are each 0 or 2,o is 0 or 1, andp is 0, 1 or 2,where (o+p) is 1, 2 or 3 and, in the case where p=2, the A.sup.2 groups and n may be identical or different with the proviso that at least one of the groups A.sup.1 and A.sup.
    Type: Grant
    Filed: May 15, 1989
    Date of Patent: May 11, 1993
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Volker Reiffenrath, Joachim Krause, Andreas Wachtler, Thomas Geelhaar
  • Patent number: 5204476
    Abstract: The invention relates to fluorophenylpyridines of the formula I: ##STR1## where R.sup.1 and R.sup.2 are substituted and unsubstituted monovalent organic radicals.
    Type: Grant
    Filed: December 18, 1990
    Date of Patent: April 20, 1993
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Andreas Wachtler, Eike Poetsch, Thomas Geelhaar, Reinhard Hittich, Volker Reiffenrath, Hans-Michael Kompter
  • Patent number: 5198149
    Abstract: Chiral, tilted, smectic liquid-crystal phases containing at least two liquid-crystal components and at least one chiral doping agent, at least one liquid-crystal component being a compound having the structural unit 2,3-difluoro-1,4-phenylene, are distinguished by a very low viscosity and advantageous switching times.
    Type: Grant
    Filed: May 15, 1989
    Date of Patent: March 30, 1993
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Volker Reiffenrath, Joachim Krause, Andreas Wachtler, Thomas Geelhaar, David Coates, Ian Sage, Simon Greenfield
  • Patent number: 5196141
    Abstract: The invention relates to 5-oxy-2-phenylpyridines of the formula I ##STR1## in which m and n, independently of one another, are each from 1 to 18,Q.sup.1 is --O--, trans-1,4-cyclohexylene, 1,4-phenylene or a single bond, andQ.sup.2 is --CO--, ##STR2## or a single bond, with the provisos that in the case where Q.sup.1 =Q.sup.2 =a single bond, the sum of m+n.gtoreq.11, and in the case where Q.sup.2 =CO, the radical C.sub.n H.sub.2n+1 is straight-chain, and to ferroelectric liquid-crystalline media containing these compounds.
    Type: Grant
    Filed: October 22, 1990
    Date of Patent: March 23, 1993
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Andreas Wachtler, Volker Reiffenrath, Reinhard Hittich, Thomas Geelhaar, Eike Poetsch
  • Patent number: 5167859
    Abstract: 2,5-Disubstituted heterocycles of the formula I ##STR1## in which R.sup.1 and R.sup.2, each independently of one another, are alkyl, alkenyl or oxaalkyl having up to 12 C atoms,L.sup.1 and L.sup.2, each independently of one another are H or F,Y is --O--, --CO--O--, --O--CO-- or a single bond,m is 1 or 2,Z is H, F, OH or alkyl having up to 5 C atoms, andQ is --O--, --O--CO--, or if Z is fluorine or hydroxyl, is also be a single bondare suitable as components of ferroelectric mixtures.
    Type: Grant
    Filed: December 21, 1989
    Date of Patent: December 1, 1992
    Assignee: Merck Patent Gesellschaft Mit Beschraenkter Haftung
    Inventors: Andreas Wachtler, Thomas Geelhaar, Hans-Adolf Kurmeier, Detlef Pauluth
  • Patent number: 5143642
    Abstract: The invention relates to a liquid-crystalline medium for electrooptical display elements based on the ECB effect, containing two components A and B which themselves comprise one or more individual compounds, component A having clearly negative dielectric anistropy and giving the liquid-crystalline phase a dielectric anistrophy of .ltoreq.-0.3, and component B having pronounced nematogeneity and a viscosity of not more than 30 mPa.s at 20.degree. C.
    Type: Grant
    Filed: January 11, 1991
    Date of Patent: September 1, 1992
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Joachim Krause, Thomas Geelhaar, Reinhard Hittich, Ulrich Finkenzeller, Bernhard Rieger, Georg Weber
  • Patent number: 5116527
    Abstract: The invenion relates to a display element based on the electroclinic effect containing a liquid crystal medium being a mixture of at least two chiral components and at least one non-chiral component, characterized in that said medium has a pitch compensated cholesteric phase above the optically active smectic A phase.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: May 26, 1992
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: David Coates, Ian C. Sage, Thomas Geelhaar, Andreas Wachtler
  • Patent number: 5089168
    Abstract: Optically active nitrogen-containing heterocycles of the formula I according to claim 1 are suitable as components for ferroelectric liquid crystalline materials.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: February 18, 1992
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Joachim Krause, Rudolf Eidenschink, Klaus Bofinger, Reinhard Hopf, Volker Reiffenrath, Eike Poetsch, Bernhard Scheuble, Thomas Geelhaar
  • Patent number: 5064569
    Abstract: Optically active compounds of the formula I can be used as components of chiral titled smectic liquid crystal phases:R.sup.1 --C*HX--Q--A.sup.4 --Z.sup.1 --A.sup.2 --(Z.sup.2 --A.sup.3).sub.n --X'--Q'--C*HY'--R.sup.5 (I)whereinR.sup.1 --C*HX--Q-- and --X'--Q'--C*HY--R.sup.5 are identical optically active radicals selected from the group --O--C*HCH.sub.3 --COO--n--alkyl, --O--C*HCH.sub.3 --CH.sub.2 --O--n--alkyl, --OCO--C*HC1--CHCH.sub.3 --CH.sub.3, --OCO--C*HCl--C*HCH.sub.3 --C.sub.2 H.sub.5, --OCO--C*HCl--CH.sub.2 --CHCH.sub.3 --CH.sub.3, --OCO--C*HCl--C(CH.sub.3).sub.3, --COO--C*HCH.sub.3 -COO--n--alkyl, --O--CO--C*HCH.sub.3 --o--n--alkyl, --OCH.sub.2 --C*HCH.sub.3 --O--n--alkyl, --COO--C*HCH.sub.3 CH.sub.2 --O--n--allyl, --OC*HCH.sub.3 --CH.sub.2 --COO--n--alkyl, --COO--C*HCH.sub.3 --CH.sub.2 --COO--n--alkyl, --OCH.sub.2 --C*HCH.sub.3 --COO--n--alkyl or --COO--CH.sub.2 --C*HCH.sub.3 --COO--n--alkyl, alkyl is of 1--12 c atoms,and --A.sup.4 --Z.sup.1 --A.sup.2 --(Z.sup.2 --A.sup.3).sub.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: November 12, 1991
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Thomas Geelhaar, Andreas Wachtler, Bernhard Scheuble
  • Patent number: 5064566
    Abstract: Compounds of the formula IR.sup.1 -A.sup.1 -A.sup.2 -R.sup.2 IwhereinR.sup.1 and R.sup.2 are each alkyl with 1-15 C atoms, and wherein one or two non-adjacent CH.sub.2 groups can also be replaced by --O--, --S--, --CO--, --O--CO--, --CO--O--, --CO--S--, --S--CO--, --CHHalogen--, --CHCN-- and/or --CH.dbd.CH--,A.sup.1 is 1,4-phenylene, trans-1,4-cyclohexylene or a single bond andA.sup.2 is ##STR1## in which Z is --O--CO--, --CO--O--, --S--CO--, --CO--S--, CH.sub.2 O--, --OCH.sub.2 -- or --CH.sub.2 CH.sub.2 --, with the proviso that, if A.sup.1 is a single bond, A.sup.2 is ##STR2## are suitable as components of chirally tilted smectic liquid crystal phases.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: November 12, 1991
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Reinhard Hopf, Bernhard Scheuble, Reinhard Hittich, Joachim Krause, Volker Reiffenrath, Eike Poetsch, Thomas Geelhaar, Rudolf Eidenschink
  • Patent number: 4897216
    Abstract: 2,3-Difluorophenol derivatives of the formula ##STR1## wherein R.sup.1 and R.sup.2, in each case independently of one another, are an alkyl group having 1 to 15 C atoms in which, in addition, one or two nonadjacent CH.sub.2 groups may be replaced by --O--, --CO--, --CH.dbd.CH-- and/or --C.tbd.C--;A is 1,4-phenylene which is unsubstituted or substituted by one or two fluorines, or is trans-1,4-cyclohexylene or a single bond; andL.sup.1 and L.sup.2, in each case independently of one another, are H or F,are suitable as components of liquid-crystalline media.
    Type: Grant
    Filed: March 9, 1989
    Date of Patent: January 30, 1990
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Volker Reiffenrath, Joachim Krause, Andreas Wachtler, Georg Weber, Thomas Geelhaar
  • Patent number: 4886620
    Abstract: The invention relates to the use of compounds of the formula IR.sup.1 --Q.sup.1 --A--(A.sup.2).sub.q --R.sup.2 Iwherein ##STR1## and R.sup.1, R.sup.2, Q.sup.1, Q.sup.2 and q have the meaning specified in claim 1, as components of smectic liquid-crystalline phases, and also smectic liquid-crystalline phases, in particular chiral tilted smectic phases containing compounds of formula I.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: December 12, 1989
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Reinhard Hopf, Bernhard Scheuble, Andreas Wachtler, Reinhard Hittich, Rudolf Eidenschink, Thomas Geelhaar, Joachim Krause, Volker Reiffenrath
  • Patent number: 4871469
    Abstract: The invention relates to the use of trifluorotoluene derivatives of the formula I ##STR1## in which R.sup.1 is alkyl having 1 to 12 carbon atoms in which, in addition, one or more non-neighboring CH.sub.2 groups may be replaced by --O--, --CO--, --O--CO--, --CO--O--, --O--CO--O--, --CH-halogen, --CH--CN-and/or --CH=CH--,A.sup.1 and A.sup.2, in each case independently of one another, are 1,4-phenylene in which, in addition, one or more CH groups may be replaced by N, trans-1,4-cyclohexylene in which, in addition, one or two non-neighboring CH.sub.2 groups may be replaced by --O--and/or --S--, or 1,4-bicyclo(2,2,2)octylene, each of which is unsubstituted or monosubstituted or poly-substituted by halogen, nitrile and/or CH.sub.3,Z.sup.1 and Z.sup.2, in each case independently of one another, are --CO--O--, --O--CO--, --CH.sub.2 O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 -- or a single bond, andn is 0 or 1,as components of chiral tilted smectic phases.
    Type: Grant
    Filed: January 4, 1988
    Date of Patent: October 3, 1989
    Assignee: Bescrankter Haftung
    Inventors: Volker Reiffenrath, Joachim Krause, Thomas Geelhaar, Rudolf Eidenschink, Hans-Adolf Kurmeier, Eike Poetsch, Bernhard Scheuble, Georg Weber
  • Patent number: 4871472
    Abstract: Compounds of the formula I ##STR1## wherein R.sup.1 and R.sup.2 each independently of one another are R, OR, OCOR, COOR or OCOOR,is alkyl with 1 to 15 C atoms, wherein one or more CH.sub.2 groups which are not adjacent and are not linked by O can also be replaced by --O--, --CO--, --O--CO--, --CO--O--, --CH--halogen, --CHCN-- and/or --CH.dbd.CH--,A.sup.1, A.sup.2 and A.sup.3 each independently of one another are 1,4-phenylene or trans-1,4-cyclohexylene,m, n and o are each 0 or 1,m+n+o is 0, 1 or 2,Z.sup.1 and Z.sup.2 each independently of one another are --CH.sub.2 --O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 -- or a single bond andX is F, Cl, Br, I or CN,with the provisos given in claim 1, can be used as components of ferroelectric liquid crystal phases.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: October 3, 1989
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Joachim Krause, Volker Reiffenrath, Thomas Geelhaar
  • Patent number: 4834904
    Abstract: Optically active nitrogen-containing heterocycles of the formula I according to claim 1 are suitable as components for ferroelectric liquid crystalline materials.
    Type: Grant
    Filed: December 24, 1986
    Date of Patent: May 30, 1989
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Joachim Krause, Rudolf Eidenschink, Klaus Bofinger, Bernhard Scheuble, Thomas Geelhaar