Abstract: The present invention relates to a reaction mixture for manufacturing an inorganic-filler based closed-cell rigid polyurethane or polyisocyanurate (PU or PIR) containing foam having a calorific value below 6 MJ/kg, preferably below 4.5 MJ/kg, more preferably below 3 MJ/kg, measured according to EN ISO 1716, the reaction mixture comprising: At least one polyisocyanate-containing compound; At least one isocyanate-reactive compound; An inorganic filler composition; At least one physical blowing agent; characterised in that said inorganic filler composition has bulk density higher than 2 g/cm3, preferably higher than 2.1 g/cm3, more preferably higher than 2.2 g/cm3, even more preferably higher than 2.4 g/cm3.

Abstract: A reactive composition for making a PIR comprising foam at an isocyanate index of at least 120, said composition comprising at least an isocyanate composition comprising one or more isocyanate compounds, an isocyanate-reactive composition comprising one or more isocyanate-reactive compounds, at least one PIR promoting catalyst, at least one physical blowing agent with a lambda gas ?12 mW/m·K at 10° C., at least one CO2 scavenging compound selected from at least one epoxy compound, and optionally a catalyst promoting epoxy reaction with CO2 characterized in that the amount of isocyanate-reactive compounds in the reactive composition is at least 10 wt % calculated on the total weight of the reactive composition, or at least more than the amount of epoxy compounds and the molar amount of epoxy compounds in the reactive composition is at least 7.8 times higher than the molar amount of CO2 formed by the water present in the reactive composition after reaction with isocyanates.

Abstract: A reactive mixture comprising a Fire, Smoke and Toxicity retardant (FST) composition for making a polyisocyanurate and/or polyurethane (PIR/PUR) comprising material, said FST composition comprising: a) at least one compound having at least one ethylenically unsaturated moiety having a number average equivalent weight<160 g/mol, and b) optionally one or more radical initiator compound characterized in that the onset temperature for radical polymerization (Tonset) of the ethylenically unsaturated compound with or without the radical initiator is 2° C. up to 40° C. lower than the maximum reaction temperature achieved during the process for making the PIR/PUR material (reaction exotherm (Treaction)).

Abstract: A polyisocyanurate and/or polyurethane (PIR/PUR) comprising material having improved Flame, Smoke and/or Toxicity (FST) retardancy is disclosed and a method for forming said PIR/PUR comprising material. The PIR/PUR material is comprising at least 0.2 wt % of compounds having a number average equivalent weight <160 g/mol and at least one non-polymerized ethylenically unsaturated moiety based on the total weight of the PIR/PUR comprising material, and optionally 0.01 wt % up to 1 wt % of one or more radical initiator compounds based on the total weight of the PIR/PUR comprising material.

Abstract: Polyisocyanurate (PIR) and/or polyurethane (PUR) comprising insulation foams having significantly improved long term insulation values are disclosed as well as a processing method to fabricate said improved insulation foams and use of the improved insulation foams for thermal insulation.

Abstract: A (super)hydrophobic isocyanate based organic aerogel/xerogel/cryogel having a water contact angle of at least 90° comprising: a cross-linked porous network structure made of polyurethane and/or polyisocyanurate and/or polyurea, and hydrophobic compounds having before the gelling step at least one isocyanate-reactive group and no isocyanate groups Characterized in that said hydrophobic compounds are covalently bonded within the porous network of the aerogel/xerogel/cryogel and wherein said bondings are created during the gelling step of the formation of the isocyanate based organic aerogel/xerogel/cryogel cross-linked porous network structure.

Abstract: A reaction mixture and a process for making a polyisocyanurate comprising rigid foam having a density in the range 50-500 kg/m3 is disclosed, said process having a cream time >35 seconds and a snap cure behaviour.

Abstract: Polyisocyanurate (PIR) and/or polyurethane (PUR) comprising insulation foams having significantly improved long term insulation values are disclosed as well as a processing method to fabricate said improved insulation foams and use of the improved insulation foams for thermal insulation.

Abstract: A reactive composition is disclosed for making a polyisocyanurate-polyurethane comprising rigid foam (PIR-PUR), said reactive composition comprising a polyisocyanate composition, an isocyanate-reactive composition, at least one catalyst compound suitable for making the PIR-PUR comprising foam, at least one blowing agent; and optionally one or more surfactants, one or more flame retardants, one or more antioxidants, or combinations thereof characterized in that the reactive composition further comprises a reactive viscosity reducer selected from at least one acrylate and/or methacrylate compound having no isocyanate-reactive groups and having a viscosity at 25° C. below 100 mPa·s.

Abstract: Functionalized isocyanate based organic aerogel/xerogel/cryogel comprising: a cross-linked porous network structure made of polyurethane and/or polyisocyanurate and/or polyurea, comprising on their pore surface before functionalization reactive groups (B) and functionalization molecules having a solubility in water <10 g/L at 20° C. chemically attached to the pore surface of the cross-linked porous network structure wherein said molecules have at least one reactive group (A) being capable of binding to said pore surface (by reaction with groups (B)) and at least one functional group (C) providing the pore surface with the desired functionalization.

Abstract: A synthesis method for making an isocyanate based organic xerogel having a low density (i.e. <400 kg/m3) and a small pore size (<150 nm) in combination with a specific surface area >100 m2/g is disclosed. The synthesis method avoiding or reducing gel shrinkage during the solvent removal step is characterized by the step wherein the organic solvent used to synthesize the isocyanate based organic xerogel is replaced by water such that during the solvent removal step only water needs to be removed to dry the porous network and to obtain the isocyanate based organic xerogel.

Abstract: A reaction mixture and a process for making a polyisocyanurate comprising rigid foam having a density in the range 50-500 kg/m3 is disclosed, said process having a cream time >35 seconds and a snap cure behaviour.

Abstract: A (super)hydrophobic isocyanate based organic aerogel/xerogel/cryogel having a water contact angle of at least 90° comprising: a cross-linked porous network structure made of polyurethane and/or polyisocyanurate and/or polyurea, and hydrophobic compounds having before the gelling step at least one isocyanate-reactive group and no isocyanate groups Characterized in that said hydrophobic compounds are covalently bonded within the porous network of the aerogel/xerogel/cryogel and wherein said bondings are created during the gelling step of the formation of the isocyanate based organic aerogel/xerogel/cryogel cross-linked porous network structure.

Abstract: A synthesis method for making an isocyanate based organic xerogel having a low density (i.e. <400 kg/m3) and a small pore size (<150 nm) in combination with a specific surface area >100 m2/g is disclosed. The synthesis method avoiding or reducing gel shrinkage during the solvent removal step is characterized by the step wherein the organic solvent used to synthesize the isocyanate based organic xerogel is replaced by water such that during the solvent removal step only water needs to be removed to dry the porous network and to obtain the isocyanate based organic xerogel.

Abstract: A reinforced organic natural fiber composite material having a lambda value in the range 15-35 mW/m·K is disclosed which comprises 25-85% by weight hydrophobic nanoporous particles calculated on the total weight of the composite material, at least 10% by weight organic natural fibers having isocyanate reactive groups calculated on the total weight of the composite material and 1-15% by weight binder selected from a polyurea/polyurethane comprising binder made from emulsifiable polyisocyanate, water and surfactants.

Abstract: Functionalized isocyanate based organic aerogel/xerogel/cryogel comprising: a cross-linked porous network structure made of polyurethane and/or polyisocyanurate and/or polyurea, comprising on their pore surface before functionalization reactive groups (B) and functionalization molecules having a solubility in water <10 g/L at 20° C. chemically attached to the pore surface of the cross-linked porous network structure wherein said molecules have at least one reactive group (A) being capable of binding to said pore surface (by reaction with groups (B)) and at least one functional group (C) providing the pore surface with the desired functionalization.

Abstract: A reinforced organic natural fiber composite material having a lambda value in the range 15-35 mW/m·K is disclosed which comprises 25-85% by weight hydrophobic nanoporous particles calculated on the total weight of the composite material, at least 10% by weight organic natural fibers having isocyanate reactive groups calculated on the total weight of the composite material and 1-15% by weight binder selected from a polyurea/polyurethane comprising binder made from emulsifiable polyisocyanate, water and surfactants.

Abstract: Crystalline foam and process for making it by first creating a crystalline arrangement of gas bubbles in curable composition and allowing this composition to cure subsequently.

Abstract: Process for making a flexible polyurethane foam by reacting a polyisocyanate and a polyol composition in the presence of water, a reactive amine catalyst and a specific metal salt. The foams have a low level of volatile organic compounds (VOCs) and a desirable combination of mechanical and durability properties.

Abstract: Process for making a flexible polyurethane foam by reacting a polyisocyanate and a polyol composition in the presence of water, a reactive amine catalyst and a specific metal salt.