Abstract: A tool and a method for forming a tool are disclosed. The tool has a base layer additively formed from a polymer material in a desired tool shape. In addition, a sealant layer is formed over an outer surface the base layer. The sealant is a low-modulus material such as a silicone rubber or an elastomer. In one embodiment, the sealant is made electrically conductive by the addition of a filler to the low-modulus material. The filler material may be one of carbon black, carbon fibers, graphene, carbon nanotubes, and metallic whiskers, for example. In another embodiment, the sealant is not electrically conductive and an electrically conductive layer is formed over the sealant layer. Finally, a metallic coating, preferably multilayer, is formed over the sealant layer by electroplating or electrodeposition.

Abstract: A fiber-modified interlayer includes a nonwoven fabric layer formed of continuous fibers, and discontinuous fibers attached to the nonwoven fabric, the fiber-modified interlayer is attached to at least one reinforcing layer of structural tows to form an interlayer-toughened reinforcing fabric, at least one layer of the interlayer-toughened reinforcing fabric is infused with a matrix material and cured to form a composite structure.

Abstract: The present disclosure provides a barrier-coating structure that includes a polymer-matrix composite having a first surface and a second surface. The barrier-coating structure includes a flexible layer having a first surface and a second surface and a sol-gel layer having a first surface and a second surface. The first surface of the flexible layer contacts the second surface of the flexible layer. The barrier-coating structure includes a barrier layer having a first surface and a second surface. The sol-gel and/or the barrier layer may comprise one or more reactive substituents. The first surface of the barrier layer may be a laser-ablated surface.

Abstract: A method of imparting electrical conductivity on an interlayer material is disclosed. In one non-limiting example the method includes forming the interlayer material from at least one layer of fabric of thermoplastic fibers. The method further includes, treating the surface of the interlayer material using an atmospheric-pressure plasma such that the surface of the interlayer material undergoes a surface activation. Additionally, the method includes depositing a layer of conductive material on the surface of the interlayer material such that the conductive material increases a conductivity of the interlayer material.

Abstract: A tool including a tool body, the tool body including a substrate having a tool-side surface, an intermediate layer positioned over the tool-side surface, and an outer layer positioned over the intermediate layer, the outer layer including a metallic material.

Abstract: A tool and a method for forming a tool are disclosed. The tool has a base layer additively formed from a polymer material in a desired tool shape. In addition, a sealant layer is formed over an outer surface the base layer. The sealant is a low-modulus material such as a silicone rubber or an elastomer. In one embodiment, the sealant is made electrically conductive by the addition of a filler to the low-modulus material. The filler material may be one of carbon black, carbon fibers, graphene, carbon nanotubes, and metallic whiskers, for example. In another embodiment, the sealant is not electrically conductive and an electrically conductive layer is formed over the sealant layer. Finally, a metallic coating, preferably multilayer, is formed over the sealant layer by electroplating or electrodeposition.

Abstract: A method for manufacturing a composite may include: selecting an interlayer material having a first distortional-deformation capability; selecting a matrix material having a second distortional-deformation capability, which is less than the first distortional-deformation capability; disposing at least one reinforcing layer, formed of reinforcing fibers of a reinforcing material, and at least one interlayer, formed of a nonwoven fabric of the interlayer material, in an alternating configuration; and infusing the at least one reinforcing layer and the at least one interlayer with the matrix material such that the matrix material flows though the at least one reinforcing layer and the at least one interlayer. Selection of the interlayer material having the first distortional-deformation capability and the matrix material having the second distortional-deformation capability is configured to increase tensile strength of the composite.

Abstract: A tool including a tool body, the tool body including a substrate having a tool-side surface, an intermediate layer positioned over the tool-side surface, and an outer layer positioned over the intermediate layer, the outer layer including a metallic material.

Abstract: A method for using a tow incorporating a large number of fibers to form a composite part that has the quality of parts made with tows incorporating a small number of fibers is described. The method includes spreading the tows incorporating a large number of fibers to form a relatively wide, flat, and continuous, unidirectional fabric, holding the fabric under tension to maintain the orientation and flatness, subjecting the flattened fabric to melt-bonding while held under tension to maintain the flattened configuration, and slicing the melt-bonded, unidirectional fabric into a plurality of narrow fiber tows and subsequently using these to produce braided, woven, and other fabric forms.

Abstract: Polyimides containing a backbone with at least one nanoparticle component and made from oligomers having endcaps that are difunctional or a mix of di- and monofunctionality are provided. The endcaps may be nadic or phenylethynyl. The backbone may be wholly inorganic or made from a mixture of inorganic and organic groups. The oligomers may be created in-situ using standard polymerization of monomeric reactants chemistry using a solvent or may be provided as a pre-imidized compound that may be either a solid or liquid. It is believed that the nanoparticle component of the polymer backbone provides superior thermo-oxidative stability verses unmodified organic backbones. It is further believed that providing difunctional or a mixture of di- and monofunctional endcaps allows for increased crosslinking to provide improved strength and stiffness verses wholly monofunctional endcapped oligomers for polyimides. The nanoparticle is part of the backbone of the polymer and not solely a pendant group.

Abstract: A system and method for forming an item from a material, which may include elongated fibers and/or stretched broken fibers. The material is placed on a first clamping portion, which is placed on a fixture. A second clamping portion is placed against the material and the first clamping portion and secured together, forming a clamping assembly. The clamping assembly is removed from the fixture and placed on a first die portion, having a first profile. A second die portion is also provided, having a second profile. In forming the item, at least one of the first die portion and the second die portion are moved toward each other such that a second surface of the first die portion and a first surface of the second die portion contact and form the material into the item generally replicating the first profile and the second profile.

Abstract: A system and method for forming an item from a material, which may include elongated fibers and/or stretched broken fibers. The material is placed on a first clamping portion, which is placed on a fixture. A second clamping portion is placed against the material and the first clamping portion and secured together, forming a clamping assembly. The clamping assembly is removed from the fixture and placed on a first die portion, having a first profile. A second die portion is also provided, having a second profile. In forming the item, at least one of the first die portion and the second die portion are moved toward each other such that a second surface of the first die portion and a first surface of the second die portion contact and form the material into the item generally replicating the first profile and the second profile.

Abstract: Polyimides containing a backbone with at least one nanoparticle component and made from oligomers having endcaps that are difunctional or a mix of di- and monofunctionality are provided. The endcaps may be nadic or phenylethynyl. The backbone may be wholly inorganic or made from a mixture of inorganic and organic groups. The oligomers may be created in-situ using standard polymerization of monomeric reactants chemistry using a solvent or may be provided as a pre-imidized compound that may be either a solid or liquid. It is believed that the nanoparticle component of the polymer backbone provides superior thermo-oxidative stability verses unmodified organic backbones. It is further believed that providing difunctional or a mixture of di- and monofunctional endcaps allows for increased crosslinking to provide improved strength and stiffness verses wholly monofunctional endcapped oligomers for polyimides. The nanoparticle is part of the backbone of the polymer and not solely a pendant group.

Abstract: A tool including a tool body, the tool body including a substrate having a tool-side surface, an intermediate layer positioned over the tool-side surface, and an outer layer positioned over the intermediate layer, the outer layer including a metallic material.

Abstract: Polyimides containing a backbone with at least one nanoparticle component and made from oligomers having endcaps that are difunctional or a mix of di- and monofunctionality are provided. The endcaps may be nadic or phenylethynyl. The backbone may be wholly inorganic or made from a mixture of inorganic and organic groups. The oligomers may be created in-situ using standard polymerization of monomeric reactants chemistry using a solvent or may be provided as a pre-imidized compound that may be either a solid or liquid. It is believed that the nanoparticle component of the polymer backbone provides superior thermo-oxidative stability verses unmodified organic backbones. It is further believed that providing difunctional or a mixture of di- and monofunctional endcaps allows for increased crosslinking to provide improved strength and stiffness verses wholly monofunctional endcapped oligomers for polyimides. The nanoparticle is part of the backbone of the polymer and not solely a pendant group.

Abstract: Polyimides containing a backbone with at least one nanoparticle component and made from oligomers having endcaps that are difunctional or a mix of di- and monofunctionality are provided. The endcaps may be nadic or phenylethynyl. The backbone may be wholly inorganic or made from a mixture of inorganic and organic groups. The oligomers may be created in-situ using standard polymerization of monomeric reactants chemistry using a solvent or may be provided as a pre-imidized compound that may be either a solid or liquid. It is believed that the nanoparticle component of the polymer backbone provides superior thermo-oxidative stability verses unmodified organic backbones. It is further believed that providing difunctional or a mixture of di- and monofunctional endcaps allows for increased crosslinking to provide improved strength and stiffness verses wholly monofunctional endcapped oligomers for polyimides. The nanoparticle is part of the backbone of the polymer and not solely a pendant group.

Abstract: Polyimides containing a backbone with at least one nanoparticle component and made from oligomers having endcaps that are difunctional or a mix of di- and monofunctionality are provided. The endcaps may be nadic or phenylethynyl. The backbone may be wholly inorganic or made from a mixture of inorganic and organic groups. The oligomers may be created in-situ using standard polymerization of monomeric reactants chemistry using a solvent or may be provided as a pre-imidized compound that may be either a solid or liquid. It is believed that the nanoparticle component of the polymer backbone provides superior thermo-oxidative stability verses unmodified organic backbones. It is further believed that providing difunctional or a mixture of di- and monofunctional endcaps allows for increased crosslinking to provide improved strength and stiffness verses wholly monofunctional endcapped oligomers for polyimides. The nanoparticle is part of the backbone of the polymer and not solely a pendant group.

Abstract: Polyimides containing a backbone with at least one nanoparticle component and made from oligomers having endcaps that are difunctional or a mix of di- and monofunctionality are provided. The endcaps may be nadic or phenylethynyl. The backbone may be wholly inorganic or made from a mixture of inorganic and organic groups. The oligomers may be created in-situ using standard polymerization of monomeric reactants chemistry using a solvent or may be provided as a pre-imidized compound that may be either a solid or liquid. It is believed that the nanoparticle component of the polymer backbone provides superior thermo-oxidative stability verses unmodified organic backbones. It is further believed that providing difunctional or a mixture of di- and monofunctional endcaps allows for increased crosslinking to provide improved strength and stiffness verses wholly monofunctional endcapped oligomers for polyimides. The nanoparticle is part of the backbone of the polymer and not solely a pendant group.

Abstract: A method of manufacturing a composite structure is provided. The method includes positioning a polymer-nanoparticle-enhanced interlayer adjacent to a first fiber layer. The polymer-nanoparticle-enhanced interlayer comprises at least one polymer and derivatized nanoparticles included in the molecular backbone of the at least one polymer, wherein the nanoparticles are derivatized to include functional groups. The method further includes positioning a second fiber layer adjacent to the polymer-nanoparticle-enhanced interlayer attached to the first fiber layer. The first fiber layer and the second fiber layer are infused with resin. The resin is cured to harden the composite structure.

Abstract: The disclosure provides for a system and method for dense barrier coatings for oxidation protection. In an embodiment of the disclosure, there is provided a dense barrier-coating system for use with a dry polymer-matrix composite (PMC) substrate having a first coefficient of thermal expansion. The system comprises a flexible sublayer free of water, wherein a first surface of the flexible sublayer is bonded to a first surface of the PMC. The system further comprises an oxygen-impervious, dense barrier-coating layer, wherein a first surface of the oxygen-impervious, dense barrier-coating layer is bonded to a second surface of the flexible sublayer, and further wherein the oxygen-impervious, dense barrier-coating layer is selected from the group consisting of metallic materials and ceramic materials each having a respective second coefficient of thermal expansion. The flexibility of the flexible sublayer protects the respective bonds when the first and second coefficients of thermal expansion are unequal.