Abstract: A process for preparing fluorochemical compounds, e.g., perfluoroalkanes, perfluoroethers, and perfluoroalkyl tertiary amines, comprises(a) forming a mixture comprising at least one fluorinatable, non-functional organic starting compound, e.g., propane, and at least one other compound which is present in an amount sufficient to enable the formation of a fluorochemical phase and which is selected from the group consisting of(i) perfluorochemical compounds, e.g., perfluorohexane, which boil at a higher temperature than either the fluorinatable, non-functional organic starting compound or the fluorochemical compound resulting from the subsequent fluorination of the fluorinatable, non-functional organic starting compound; and(ii) precursor compounds, e.g., hexane, which can be fluorinated in situ to produce such perfluorochemical compounds; and(b) subjecting the mixture to electrochemical fluorination in the presence of anhydrous hydrogen fluoride.

Abstract: An intelligent control system for directing a process for curing parts made of fiber-reinforced composite material in an autoclave. The system uses data gathered during the curing processing to calculate repetitively the temperature of the autoclave required to establish and maintain a predetermined cure temperature. The system accounts for heat generated by the exothermal reaction of the resin during polymerization. The control recalculates an optimal autoclave temperature at periodic intervals during the cure cycle on the basis of temperature data from the part being cured and temperature within the autoclave. The optimal autoclave temperature is determined from calculated values representing resin heat, maximum offset, lag time and degree of cure of the resin.